Heterogeneous esterification of oil with high amount of free fatty acids

Autores
Marchetti, Jorge Mario; Miguel, Victor Ubaldo; Errazu, Alberto Felipe
Año de publicación
2007
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Frying oils have become the newest raw material for the transesterification reaction for the production of biodiesel. However, these compounds usually come with a certain amount of free fatty acids. These impurities can be transformed into esters and the production of biodiesel could be increased. The use of basic resins to perform the esterification reaction into biodiesel is studied in this work. The effect of the most relevant variables of the process such as reaction temperature, molar ratio between alcohol and oil, amount of catalyst and amount of free fatty acids fed with the oil have been analyzed. For this purpose, an ideal frying oil using oleic acid and soybean oil was made. The alcohol used was ethanol. The esterification of free fatty acid using this heterogeneous catalyst appears as a great alternative to purify frying oil; in this case, the final conversion achieved was around 80%.
Fil: Marchetti, Jorge Mario. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Miguel, Victor Ubaldo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Errazu, Alberto Felipe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Materia
Esterification
Free Fatty Acids
Heterogeneous Catalyst
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/38733
Acceder
id CONICETDig_82aca043e26d2b58c03c0ea92d4adee7
oai_identifier_str oai:ri.conicet.gov.ar:11336/38733
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Heterogeneous esterification of oil with high amount of free fatty acidsMarchetti, Jorge MarioMiguel, Victor UbaldoErrazu, Alberto FelipeEsterificationFree Fatty AcidsHeterogeneous Catalysthttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Frying oils have become the newest raw material for the transesterification reaction for the production of biodiesel. However, these compounds usually come with a certain amount of free fatty acids. These impurities can be transformed into esters and the production of biodiesel could be increased. The use of basic resins to perform the esterification reaction into biodiesel is studied in this work. The effect of the most relevant variables of the process such as reaction temperature, molar ratio between alcohol and oil, amount of catalyst and amount of free fatty acids fed with the oil have been analyzed. For this purpose, an ideal frying oil using oleic acid and soybean oil was made. The alcohol used was ethanol. The esterification of free fatty acid using this heterogeneous catalyst appears as a great alternative to purify frying oil; in this case, the final conversion achieved was around 80%.Fil: Marchetti, Jorge Mario. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Miguel, Victor Ubaldo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Errazu, Alberto Felipe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaElsevier2007-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/38733Marchetti, Jorge Mario; Miguel, Victor Ubaldo; Errazu, Alberto Felipe; Heterogeneous esterification of oil with high amount of free fatty acids; Elsevier; Fuel; 86; 5-6; 3-2007; 906-9100016-2361CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.fuel.2006.09.006info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0016236106003516info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:19:17Zoai:ri.conicet.gov.ar:11336/38733instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:19:17.979CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Heterogeneous esterification of oil with high amount of free fatty acids
title Heterogeneous esterification of oil with high amount of free fatty acids
spellingShingle Heterogeneous esterification of oil with high amount of free fatty acids
Marchetti, Jorge Mario
Esterification
Free Fatty Acids
Heterogeneous Catalyst
title_short Heterogeneous esterification of oil with high amount of free fatty acids
title_full Heterogeneous esterification of oil with high amount of free fatty acids
title_fullStr Heterogeneous esterification of oil with high amount of free fatty acids
title_full_unstemmed Heterogeneous esterification of oil with high amount of free fatty acids
title_sort Heterogeneous esterification of oil with high amount of free fatty acids
dc.creator.none.fl_str_mv Marchetti, Jorge Mario
Miguel, Victor Ubaldo
Errazu, Alberto Felipe
author Marchetti, Jorge Mario
author_facet Marchetti, Jorge Mario
Miguel, Victor Ubaldo
Errazu, Alberto Felipe
author_role author
author2 Miguel, Victor Ubaldo
Errazu, Alberto Felipe
author2_role author
author
dc.subject.none.fl_str_mv Esterification
Free Fatty Acids
Heterogeneous Catalyst
topic Esterification
Free Fatty Acids
Heterogeneous Catalyst
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Frying oils have become the newest raw material for the transesterification reaction for the production of biodiesel. However, these compounds usually come with a certain amount of free fatty acids. These impurities can be transformed into esters and the production of biodiesel could be increased. The use of basic resins to perform the esterification reaction into biodiesel is studied in this work. The effect of the most relevant variables of the process such as reaction temperature, molar ratio between alcohol and oil, amount of catalyst and amount of free fatty acids fed with the oil have been analyzed. For this purpose, an ideal frying oil using oleic acid and soybean oil was made. The alcohol used was ethanol. The esterification of free fatty acid using this heterogeneous catalyst appears as a great alternative to purify frying oil; in this case, the final conversion achieved was around 80%.
Fil: Marchetti, Jorge Mario. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Miguel, Victor Ubaldo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Errazu, Alberto Felipe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
description Frying oils have become the newest raw material for the transesterification reaction for the production of biodiesel. However, these compounds usually come with a certain amount of free fatty acids. These impurities can be transformed into esters and the production of biodiesel could be increased. The use of basic resins to perform the esterification reaction into biodiesel is studied in this work. The effect of the most relevant variables of the process such as reaction temperature, molar ratio between alcohol and oil, amount of catalyst and amount of free fatty acids fed with the oil have been analyzed. For this purpose, an ideal frying oil using oleic acid and soybean oil was made. The alcohol used was ethanol. The esterification of free fatty acid using this heterogeneous catalyst appears as a great alternative to purify frying oil; in this case, the final conversion achieved was around 80%.
publishDate 2007
dc.date.none.fl_str_mv 2007-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/38733
Marchetti, Jorge Mario; Miguel, Victor Ubaldo; Errazu, Alberto Felipe; Heterogeneous esterification of oil with high amount of free fatty acids; Elsevier; Fuel; 86; 5-6; 3-2007; 906-910
0016-2361
CONICET Digital
CONICET
url http://hdl.handle.net/11336/38733
identifier_str_mv Marchetti, Jorge Mario; Miguel, Victor Ubaldo; Errazu, Alberto Felipe; Heterogeneous esterification of oil with high amount of free fatty acids; Elsevier; Fuel; 86; 5-6; 3-2007; 906-910
0016-2361
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.fuel.2006.09.006
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0016236106003516
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846781668238557184
score 12.982451

Publicaciones similares