Effect of water vapor over Pd-Co/SZ catalyst for the NO selective reduction by methane

Autores
Quincoces, Claudia Edith; Guerrero, S.; Araya, P.; Gónzalez, María Gloria
Año de publicación
2005
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The selective catalytic reduction (SCR) of NO by CH4 in the presence of excess O2 has been studied on Pd-Co, Pd and Co catalysts supported on sulfated zirconia (SZ) and activated in reaction mixture at 700 °C. After the addition of Co on Pd/SZ, an promoting effect on the catalytic activity was achieved, especially on 0.2%Pd-2%Co/SZ, which showed the maximum NO conversion higher 60% at 500 °C and 31,000 h-1. The bimetallic catalyst presented practical activity in the presence of water vapor. Stable NOx conversion was obtained for over 50 h in the presence of 6% water vapor. In order to correlate the catalysts composition with their activity, they were characterized by X-ray diffraction (XRD), diffuse reflectance spectroscopy (DRS) and temperature programmed reduction (TPR) techniques.
Fil: Quincoces, Claudia Edith. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Guerrero, S.. Universidad de Chile; Chile
Fil: Araya, P.. Universidad de Chile; Chile
Fil: Gónzalez, María Gloria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Materia
Methane
No Reduction
Sulfated Zirconia
Water Tolerance
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/55386
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Effect of water vapor over Pd-Co/SZ catalyst for the NO selective reduction by methaneQuincoces, Claudia EdithGuerrero, S.Araya, P.Gónzalez, María GloriaMethaneNo ReductionSulfated ZirconiaWater Tolerancehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The selective catalytic reduction (SCR) of NO by CH4 in the presence of excess O2 has been studied on Pd-Co, Pd and Co catalysts supported on sulfated zirconia (SZ) and activated in reaction mixture at 700 °C. After the addition of Co on Pd/SZ, an promoting effect on the catalytic activity was achieved, especially on 0.2%Pd-2%Co/SZ, which showed the maximum NO conversion higher 60% at 500 °C and 31,000 h-1. The bimetallic catalyst presented practical activity in the presence of water vapor. Stable NOx conversion was obtained for over 50 h in the presence of 6% water vapor. In order to correlate the catalysts composition with their activity, they were characterized by X-ray diffraction (XRD), diffuse reflectance spectroscopy (DRS) and temperature programmed reduction (TPR) techniques.Fil: Quincoces, Claudia Edith. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Guerrero, S.. Universidad de Chile; ChileFil: Araya, P.. Universidad de Chile; ChileFil: Gónzalez, María Gloria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaElsevier Science2005-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/55386Quincoces, Claudia Edith; Guerrero, S.; Araya, P.; Gónzalez, María Gloria; Effect of water vapor over Pd-Co/SZ catalyst for the NO selective reduction by methane; Elsevier Science; Catalysis Communications; 6; 1; 1-2005; 75-801566-7367CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.catcom.2004.11.002info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1566736704002213info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:06:01Zoai:ri.conicet.gov.ar:11336/55386instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:06:01.912CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Effect of water vapor over Pd-Co/SZ catalyst for the NO selective reduction by methane
title Effect of water vapor over Pd-Co/SZ catalyst for the NO selective reduction by methane
spellingShingle Effect of water vapor over Pd-Co/SZ catalyst for the NO selective reduction by methane
Quincoces, Claudia Edith
Methane
No Reduction
Sulfated Zirconia
Water Tolerance
title_short Effect of water vapor over Pd-Co/SZ catalyst for the NO selective reduction by methane
title_full Effect of water vapor over Pd-Co/SZ catalyst for the NO selective reduction by methane
title_fullStr Effect of water vapor over Pd-Co/SZ catalyst for the NO selective reduction by methane
title_full_unstemmed Effect of water vapor over Pd-Co/SZ catalyst for the NO selective reduction by methane
title_sort Effect of water vapor over Pd-Co/SZ catalyst for the NO selective reduction by methane
dc.creator.none.fl_str_mv Quincoces, Claudia Edith
Guerrero, S.
Araya, P.
Gónzalez, María Gloria
author Quincoces, Claudia Edith
author_facet Quincoces, Claudia Edith
Guerrero, S.
Araya, P.
Gónzalez, María Gloria
author_role author
author2 Guerrero, S.
Araya, P.
Gónzalez, María Gloria
author2_role author
author
author
dc.subject.none.fl_str_mv Methane
No Reduction
Sulfated Zirconia
Water Tolerance
topic Methane
No Reduction
Sulfated Zirconia
Water Tolerance
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The selective catalytic reduction (SCR) of NO by CH4 in the presence of excess O2 has been studied on Pd-Co, Pd and Co catalysts supported on sulfated zirconia (SZ) and activated in reaction mixture at 700 °C. After the addition of Co on Pd/SZ, an promoting effect on the catalytic activity was achieved, especially on 0.2%Pd-2%Co/SZ, which showed the maximum NO conversion higher 60% at 500 °C and 31,000 h-1. The bimetallic catalyst presented practical activity in the presence of water vapor. Stable NOx conversion was obtained for over 50 h in the presence of 6% water vapor. In order to correlate the catalysts composition with their activity, they were characterized by X-ray diffraction (XRD), diffuse reflectance spectroscopy (DRS) and temperature programmed reduction (TPR) techniques.
Fil: Quincoces, Claudia Edith. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Guerrero, S.. Universidad de Chile; Chile
Fil: Araya, P.. Universidad de Chile; Chile
Fil: Gónzalez, María Gloria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
description The selective catalytic reduction (SCR) of NO by CH4 in the presence of excess O2 has been studied on Pd-Co, Pd and Co catalysts supported on sulfated zirconia (SZ) and activated in reaction mixture at 700 °C. After the addition of Co on Pd/SZ, an promoting effect on the catalytic activity was achieved, especially on 0.2%Pd-2%Co/SZ, which showed the maximum NO conversion higher 60% at 500 °C and 31,000 h-1. The bimetallic catalyst presented practical activity in the presence of water vapor. Stable NOx conversion was obtained for over 50 h in the presence of 6% water vapor. In order to correlate the catalysts composition with their activity, they were characterized by X-ray diffraction (XRD), diffuse reflectance spectroscopy (DRS) and temperature programmed reduction (TPR) techniques.
publishDate 2005
dc.date.none.fl_str_mv 2005-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/55386
Quincoces, Claudia Edith; Guerrero, S.; Araya, P.; Gónzalez, María Gloria; Effect of water vapor over Pd-Co/SZ catalyst for the NO selective reduction by methane; Elsevier Science; Catalysis Communications; 6; 1; 1-2005; 75-80
1566-7367
CONICET Digital
CONICET
url http://hdl.handle.net/11336/55386
identifier_str_mv Quincoces, Claudia Edith; Guerrero, S.; Araya, P.; Gónzalez, María Gloria; Effect of water vapor over Pd-Co/SZ catalyst for the NO selective reduction by methane; Elsevier Science; Catalysis Communications; 6; 1; 1-2005; 75-80
1566-7367
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.catcom.2004.11.002
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1566736704002213
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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