On the role of Pd β-hydride in the reduction of nitrate over Pd based catalyst

Autores
Mendez, Claudio Matias; Olivero, Hernan; Damiani, Daniel Eduardo; Volpe, María Alicia
Año de publicación
2008
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Two monometallic palladium catalysts supported on γ-Al2O3 were synthesized using different precursors, Pd(AcAc)2 and Pd(NO3)2, while Pd-Cu/γ Al2O3 catalysts were prepared from those parent catalysts. The samples were tested for the elimination of nitrate and nitrite from aqueous solutions using hydrogen as a reductant in a standard batch reactor. Besides, the reduction of nitrate was carried out in a series of two reactors by an electrochemical cell mechanism. In this case, nitrate was reduced to nitrite by electrons supplied from the first reactor. The following reduction of nitrite was performed over the monometallic catalyst. Both the conversion and the selectivity to N2 were higher than in the standard batch reactor. Monometallic samples prepared from Pd(AcAc)2 showed an extremely high selectivity to the desired product. The catalysts were characterized by transmission electron microscopy (TEM), temperature programmed reduction (TPR) and H2 chemisorption. Differences in particle size and β-hydride formation were observed for the different samples. The possible role of Pd β-hydride in the formation of overhydrogenated products is discussed. © 2008 Elsevier B.V. All rights reserved.
Fil: Mendez, Claudio Matias. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Olivero, Hernan. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Volpe, María Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Materia
Β-Hydride
Nitrate Reduction
Nitrite Reduction
Palladium-Copper Catalyst
Supported Palladium
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/62495
Acceder
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network_name_str CONICET Digital (CONICET)
spelling On the role of Pd β-hydride in the reduction of nitrate over Pd based catalystMendez, Claudio MatiasOlivero, HernanDamiani, Daniel EduardoVolpe, María AliciaΒ-HydrideNitrate ReductionNitrite ReductionPalladium-Copper CatalystSupported Palladiumhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Two monometallic palladium catalysts supported on γ-Al2O3 were synthesized using different precursors, Pd(AcAc)2 and Pd(NO3)2, while Pd-Cu/γ Al2O3 catalysts were prepared from those parent catalysts. The samples were tested for the elimination of nitrate and nitrite from aqueous solutions using hydrogen as a reductant in a standard batch reactor. Besides, the reduction of nitrate was carried out in a series of two reactors by an electrochemical cell mechanism. In this case, nitrate was reduced to nitrite by electrons supplied from the first reactor. The following reduction of nitrite was performed over the monometallic catalyst. Both the conversion and the selectivity to N2 were higher than in the standard batch reactor. Monometallic samples prepared from Pd(AcAc)2 showed an extremely high selectivity to the desired product. The catalysts were characterized by transmission electron microscopy (TEM), temperature programmed reduction (TPR) and H2 chemisorption. Differences in particle size and β-hydride formation were observed for the different samples. The possible role of Pd β-hydride in the formation of overhydrogenated products is discussed. © 2008 Elsevier B.V. All rights reserved.Fil: Mendez, Claudio Matias. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Olivero, Hernan. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Volpe, María Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaElsevier Science2008-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/62495Mendez, Claudio Matias; Olivero, Hernan; Damiani, Daniel Eduardo; Volpe, María Alicia; On the role of Pd β-hydride in the reduction of nitrate over Pd based catalyst; Elsevier Science; Applied Catalysis B: Environmental; 84; 1-2; 10-2008; 156-1610926-3373CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926337308001161info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcatb.2008.03.019info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:58:13Zoai:ri.conicet.gov.ar:11336/62495instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:58:14.243CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv On the role of Pd β-hydride in the reduction of nitrate over Pd based catalyst
title On the role of Pd β-hydride in the reduction of nitrate over Pd based catalyst
spellingShingle On the role of Pd β-hydride in the reduction of nitrate over Pd based catalyst
Mendez, Claudio Matias
Β-Hydride
Nitrate Reduction
Nitrite Reduction
Palladium-Copper Catalyst
Supported Palladium
title_short On the role of Pd β-hydride in the reduction of nitrate over Pd based catalyst
title_full On the role of Pd β-hydride in the reduction of nitrate over Pd based catalyst
title_fullStr On the role of Pd β-hydride in the reduction of nitrate over Pd based catalyst
title_full_unstemmed On the role of Pd β-hydride in the reduction of nitrate over Pd based catalyst
title_sort On the role of Pd β-hydride in the reduction of nitrate over Pd based catalyst
dc.creator.none.fl_str_mv Mendez, Claudio Matias
Olivero, Hernan
Damiani, Daniel Eduardo
Volpe, María Alicia
author Mendez, Claudio Matias
author_facet Mendez, Claudio Matias
Olivero, Hernan
Damiani, Daniel Eduardo
Volpe, María Alicia
author_role author
author2 Olivero, Hernan
Damiani, Daniel Eduardo
Volpe, María Alicia
author2_role author
author
author
dc.subject.none.fl_str_mv Β-Hydride
Nitrate Reduction
Nitrite Reduction
Palladium-Copper Catalyst
Supported Palladium
topic Β-Hydride
Nitrate Reduction
Nitrite Reduction
Palladium-Copper Catalyst
Supported Palladium
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Two monometallic palladium catalysts supported on γ-Al2O3 were synthesized using different precursors, Pd(AcAc)2 and Pd(NO3)2, while Pd-Cu/γ Al2O3 catalysts were prepared from those parent catalysts. The samples were tested for the elimination of nitrate and nitrite from aqueous solutions using hydrogen as a reductant in a standard batch reactor. Besides, the reduction of nitrate was carried out in a series of two reactors by an electrochemical cell mechanism. In this case, nitrate was reduced to nitrite by electrons supplied from the first reactor. The following reduction of nitrite was performed over the monometallic catalyst. Both the conversion and the selectivity to N2 were higher than in the standard batch reactor. Monometallic samples prepared from Pd(AcAc)2 showed an extremely high selectivity to the desired product. The catalysts were characterized by transmission electron microscopy (TEM), temperature programmed reduction (TPR) and H2 chemisorption. Differences in particle size and β-hydride formation were observed for the different samples. The possible role of Pd β-hydride in the formation of overhydrogenated products is discussed. © 2008 Elsevier B.V. All rights reserved.
Fil: Mendez, Claudio Matias. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Olivero, Hernan. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Volpe, María Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
description Two monometallic palladium catalysts supported on γ-Al2O3 were synthesized using different precursors, Pd(AcAc)2 and Pd(NO3)2, while Pd-Cu/γ Al2O3 catalysts were prepared from those parent catalysts. The samples were tested for the elimination of nitrate and nitrite from aqueous solutions using hydrogen as a reductant in a standard batch reactor. Besides, the reduction of nitrate was carried out in a series of two reactors by an electrochemical cell mechanism. In this case, nitrate was reduced to nitrite by electrons supplied from the first reactor. The following reduction of nitrite was performed over the monometallic catalyst. Both the conversion and the selectivity to N2 were higher than in the standard batch reactor. Monometallic samples prepared from Pd(AcAc)2 showed an extremely high selectivity to the desired product. The catalysts were characterized by transmission electron microscopy (TEM), temperature programmed reduction (TPR) and H2 chemisorption. Differences in particle size and β-hydride formation were observed for the different samples. The possible role of Pd β-hydride in the formation of overhydrogenated products is discussed. © 2008 Elsevier B.V. All rights reserved.
publishDate 2008
dc.date.none.fl_str_mv 2008-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/62495
Mendez, Claudio Matias; Olivero, Hernan; Damiani, Daniel Eduardo; Volpe, María Alicia; On the role of Pd β-hydride in the reduction of nitrate over Pd based catalyst; Elsevier Science; Applied Catalysis B: Environmental; 84; 1-2; 10-2008; 156-161
0926-3373
CONICET Digital
CONICET
url http://hdl.handle.net/11336/62495
identifier_str_mv Mendez, Claudio Matias; Olivero, Hernan; Damiani, Daniel Eduardo; Volpe, María Alicia; On the role of Pd β-hydride in the reduction of nitrate over Pd based catalyst; Elsevier Science; Applied Catalysis B: Environmental; 84; 1-2; 10-2008; 156-161
0926-3373
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926337308001161
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcatb.2008.03.019
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.069144

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