On the role of Pd β-hydride in the reduction of nitrate over Pd based catalyst
- Autores
- Mendez, Claudio Matias; Olivero, Hernan; Damiani, Daniel Eduardo; Volpe, María Alicia
- Año de publicación
- 2008
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Two monometallic palladium catalysts supported on γ-Al2O3 were synthesized using different precursors, Pd(AcAc)2 and Pd(NO3)2, while Pd-Cu/γ Al2O3 catalysts were prepared from those parent catalysts. The samples were tested for the elimination of nitrate and nitrite from aqueous solutions using hydrogen as a reductant in a standard batch reactor. Besides, the reduction of nitrate was carried out in a series of two reactors by an electrochemical cell mechanism. In this case, nitrate was reduced to nitrite by electrons supplied from the first reactor. The following reduction of nitrite was performed over the monometallic catalyst. Both the conversion and the selectivity to N2 were higher than in the standard batch reactor. Monometallic samples prepared from Pd(AcAc)2 showed an extremely high selectivity to the desired product. The catalysts were characterized by transmission electron microscopy (TEM), temperature programmed reduction (TPR) and H2 chemisorption. Differences in particle size and β-hydride formation were observed for the different samples. The possible role of Pd β-hydride in the formation of overhydrogenated products is discussed. © 2008 Elsevier B.V. All rights reserved.
Fil: Mendez, Claudio Matias. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Olivero, Hernan. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Volpe, María Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina - Materia
-
Β-Hydride
Nitrate Reduction
Nitrite Reduction
Palladium-Copper Catalyst
Supported Palladium - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/62495
Ver los metadatos del registro completo
id |
CONICETDig_fbceb488dfbf791a72e099b3490e0296 |
---|---|
oai_identifier_str |
oai:ri.conicet.gov.ar:11336/62495 |
network_acronym_str |
CONICETDig |
repository_id_str |
3498 |
network_name_str |
CONICET Digital (CONICET) |
spelling |
On the role of Pd β-hydride in the reduction of nitrate over Pd based catalystMendez, Claudio MatiasOlivero, HernanDamiani, Daniel EduardoVolpe, María AliciaΒ-HydrideNitrate ReductionNitrite ReductionPalladium-Copper CatalystSupported Palladiumhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Two monometallic palladium catalysts supported on γ-Al2O3 were synthesized using different precursors, Pd(AcAc)2 and Pd(NO3)2, while Pd-Cu/γ Al2O3 catalysts were prepared from those parent catalysts. The samples were tested for the elimination of nitrate and nitrite from aqueous solutions using hydrogen as a reductant in a standard batch reactor. Besides, the reduction of nitrate was carried out in a series of two reactors by an electrochemical cell mechanism. In this case, nitrate was reduced to nitrite by electrons supplied from the first reactor. The following reduction of nitrite was performed over the monometallic catalyst. Both the conversion and the selectivity to N2 were higher than in the standard batch reactor. Monometallic samples prepared from Pd(AcAc)2 showed an extremely high selectivity to the desired product. The catalysts were characterized by transmission electron microscopy (TEM), temperature programmed reduction (TPR) and H2 chemisorption. Differences in particle size and β-hydride formation were observed for the different samples. The possible role of Pd β-hydride in the formation of overhydrogenated products is discussed. © 2008 Elsevier B.V. All rights reserved.Fil: Mendez, Claudio Matias. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Olivero, Hernan. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Volpe, María Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaElsevier Science2008-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/62495Mendez, Claudio Matias; Olivero, Hernan; Damiani, Daniel Eduardo; Volpe, María Alicia; On the role of Pd β-hydride in the reduction of nitrate over Pd based catalyst; Elsevier Science; Applied Catalysis B: Environmental; 84; 1-2; 10-2008; 156-1610926-3373CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926337308001161info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcatb.2008.03.019info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:55:31Zoai:ri.conicet.gov.ar:11336/62495instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:55:31.507CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
On the role of Pd β-hydride in the reduction of nitrate over Pd based catalyst |
title |
On the role of Pd β-hydride in the reduction of nitrate over Pd based catalyst |
spellingShingle |
On the role of Pd β-hydride in the reduction of nitrate over Pd based catalyst Mendez, Claudio Matias Β-Hydride Nitrate Reduction Nitrite Reduction Palladium-Copper Catalyst Supported Palladium |
title_short |
On the role of Pd β-hydride in the reduction of nitrate over Pd based catalyst |
title_full |
On the role of Pd β-hydride in the reduction of nitrate over Pd based catalyst |
title_fullStr |
On the role of Pd β-hydride in the reduction of nitrate over Pd based catalyst |
title_full_unstemmed |
On the role of Pd β-hydride in the reduction of nitrate over Pd based catalyst |
title_sort |
On the role of Pd β-hydride in the reduction of nitrate over Pd based catalyst |
dc.creator.none.fl_str_mv |
Mendez, Claudio Matias Olivero, Hernan Damiani, Daniel Eduardo Volpe, María Alicia |
author |
Mendez, Claudio Matias |
author_facet |
Mendez, Claudio Matias Olivero, Hernan Damiani, Daniel Eduardo Volpe, María Alicia |
author_role |
author |
author2 |
Olivero, Hernan Damiani, Daniel Eduardo Volpe, María Alicia |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Β-Hydride Nitrate Reduction Nitrite Reduction Palladium-Copper Catalyst Supported Palladium |
topic |
Β-Hydride Nitrate Reduction Nitrite Reduction Palladium-Copper Catalyst Supported Palladium |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
Two monometallic palladium catalysts supported on γ-Al2O3 were synthesized using different precursors, Pd(AcAc)2 and Pd(NO3)2, while Pd-Cu/γ Al2O3 catalysts were prepared from those parent catalysts. The samples were tested for the elimination of nitrate and nitrite from aqueous solutions using hydrogen as a reductant in a standard batch reactor. Besides, the reduction of nitrate was carried out in a series of two reactors by an electrochemical cell mechanism. In this case, nitrate was reduced to nitrite by electrons supplied from the first reactor. The following reduction of nitrite was performed over the monometallic catalyst. Both the conversion and the selectivity to N2 were higher than in the standard batch reactor. Monometallic samples prepared from Pd(AcAc)2 showed an extremely high selectivity to the desired product. The catalysts were characterized by transmission electron microscopy (TEM), temperature programmed reduction (TPR) and H2 chemisorption. Differences in particle size and β-hydride formation were observed for the different samples. The possible role of Pd β-hydride in the formation of overhydrogenated products is discussed. © 2008 Elsevier B.V. All rights reserved. Fil: Mendez, Claudio Matias. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina Fil: Olivero, Hernan. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina Fil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina Fil: Volpe, María Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina |
description |
Two monometallic palladium catalysts supported on γ-Al2O3 were synthesized using different precursors, Pd(AcAc)2 and Pd(NO3)2, while Pd-Cu/γ Al2O3 catalysts were prepared from those parent catalysts. The samples were tested for the elimination of nitrate and nitrite from aqueous solutions using hydrogen as a reductant in a standard batch reactor. Besides, the reduction of nitrate was carried out in a series of two reactors by an electrochemical cell mechanism. In this case, nitrate was reduced to nitrite by electrons supplied from the first reactor. The following reduction of nitrite was performed over the monometallic catalyst. Both the conversion and the selectivity to N2 were higher than in the standard batch reactor. Monometallic samples prepared from Pd(AcAc)2 showed an extremely high selectivity to the desired product. The catalysts were characterized by transmission electron microscopy (TEM), temperature programmed reduction (TPR) and H2 chemisorption. Differences in particle size and β-hydride formation were observed for the different samples. The possible role of Pd β-hydride in the formation of overhydrogenated products is discussed. © 2008 Elsevier B.V. All rights reserved. |
publishDate |
2008 |
dc.date.none.fl_str_mv |
2008-10 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/62495 Mendez, Claudio Matias; Olivero, Hernan; Damiani, Daniel Eduardo; Volpe, María Alicia; On the role of Pd β-hydride in the reduction of nitrate over Pd based catalyst; Elsevier Science; Applied Catalysis B: Environmental; 84; 1-2; 10-2008; 156-161 0926-3373 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/62495 |
identifier_str_mv |
Mendez, Claudio Matias; Olivero, Hernan; Damiani, Daniel Eduardo; Volpe, María Alicia; On the role of Pd β-hydride in the reduction of nitrate over Pd based catalyst; Elsevier Science; Applied Catalysis B: Environmental; 84; 1-2; 10-2008; 156-161 0926-3373 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0926337308001161 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcatb.2008.03.019 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1842269348962500608 |
score |
13.13397 |