Glass transition of LiCl aqueous solutions confined in mesoporous silica

Autores
Longinotti, María Paula; Fuentes Landete, Violeta; Loerting, Thomas; Corti, Horacio Roberto
Año de publicación
2019
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The thermal transitions of confined LiCl aqueous solutions were studied by differential scanning calorimetry for solutions with salt concentrations with eutectic (R = 7) and subeutectic (R > 7) compositions (R = moles of water/moles of LiCl). The confinement media consist of mesoporous silica with pore diameters between 2 nm and 58 nm, with a small negative surface charge density. The vitrification of confined LiCl aqueous solutions was observed in all samples, expanding the vitrification region up to R = 15, and probably beyond for cooling rates of ≈1000 K/min. Ice crystallization was observed in some samples, except for those confined in the narrower pores. The onset and endpoint glass transition temperatures for the confined eutectic samples increase by 2 K and 5 K, respectively, for the smallest pore diameters (2 nm), which is equivalent to the effect of applying a pressure of up to 100 MPa to the bulk sample. This behavior is opposite of that reported for aqueous subeutectic NaCl solutions confined in silica glasses of similar sizes. We speculate that this is due to the fact that the mechanism of double confinement of the NaCl solution, between the pore wall and the precipitated ice, is not operative for LiCl solutions. Instead, the Li+ ions might force the hydration water in to a high-density state.
Fil: Longinotti, María Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Fuentes Landete, Violeta. Universidad de Innsbruck; Austria
Fil: Loerting, Thomas. Universidad de Innsbruck; Austria
Fil: Corti, Horacio Roberto. Comisión Nacional de Energía Atómica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Materia
glass transition
LiCl
confinement
aqueous solutions
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/121411
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Glass transition of LiCl aqueous solutions confined in mesoporous silicaLonginotti, María PaulaFuentes Landete, VioletaLoerting, ThomasCorti, Horacio Robertoglass transitionLiClconfinementaqueous solutionshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The thermal transitions of confined LiCl aqueous solutions were studied by differential scanning calorimetry for solutions with salt concentrations with eutectic (R = 7) and subeutectic (R > 7) compositions (R = moles of water/moles of LiCl). The confinement media consist of mesoporous silica with pore diameters between 2 nm and 58 nm, with a small negative surface charge density. The vitrification of confined LiCl aqueous solutions was observed in all samples, expanding the vitrification region up to R = 15, and probably beyond for cooling rates of ≈1000 K/min. Ice crystallization was observed in some samples, except for those confined in the narrower pores. The onset and endpoint glass transition temperatures for the confined eutectic samples increase by 2 K and 5 K, respectively, for the smallest pore diameters (2 nm), which is equivalent to the effect of applying a pressure of up to 100 MPa to the bulk sample. This behavior is opposite of that reported for aqueous subeutectic NaCl solutions confined in silica glasses of similar sizes. We speculate that this is due to the fact that the mechanism of double confinement of the NaCl solution, between the pore wall and the precipitated ice, is not operative for LiCl solutions. Instead, the Li+ ions might force the hydration water in to a high-density state.Fil: Longinotti, María Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Fuentes Landete, Violeta. Universidad de Innsbruck; AustriaFil: Loerting, Thomas. Universidad de Innsbruck; AustriaFil: Corti, Horacio Roberto. Comisión Nacional de Energía Atómica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaAmerican Institute of Physics2019-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/121411Longinotti, María Paula; Fuentes Landete, Violeta; Loerting, Thomas; Corti, Horacio Roberto; Glass transition of LiCl aqueous solutions confined in mesoporous silica; American Institute of Physics; Journal of Chemical Physics; 151; 6; 8-2019; 1-120021-9606CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1063/1.5102142info:eu-repo/semantics/altIdentifier/url/https://aip.scitation.org/doi/10.1063/1.5102142info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:50:55Zoai:ri.conicet.gov.ar:11336/121411instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:50:55.934CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Glass transition of LiCl aqueous solutions confined in mesoporous silica
title Glass transition of LiCl aqueous solutions confined in mesoporous silica
spellingShingle Glass transition of LiCl aqueous solutions confined in mesoporous silica
Longinotti, María Paula
glass transition
LiCl
confinement
aqueous solutions
title_short Glass transition of LiCl aqueous solutions confined in mesoporous silica
title_full Glass transition of LiCl aqueous solutions confined in mesoporous silica
title_fullStr Glass transition of LiCl aqueous solutions confined in mesoporous silica
title_full_unstemmed Glass transition of LiCl aqueous solutions confined in mesoporous silica
title_sort Glass transition of LiCl aqueous solutions confined in mesoporous silica
dc.creator.none.fl_str_mv Longinotti, María Paula
Fuentes Landete, Violeta
Loerting, Thomas
Corti, Horacio Roberto
author Longinotti, María Paula
author_facet Longinotti, María Paula
Fuentes Landete, Violeta
Loerting, Thomas
Corti, Horacio Roberto
author_role author
author2 Fuentes Landete, Violeta
Loerting, Thomas
Corti, Horacio Roberto
author2_role author
author
author
dc.subject.none.fl_str_mv glass transition
LiCl
confinement
aqueous solutions
topic glass transition
LiCl
confinement
aqueous solutions
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The thermal transitions of confined LiCl aqueous solutions were studied by differential scanning calorimetry for solutions with salt concentrations with eutectic (R = 7) and subeutectic (R > 7) compositions (R = moles of water/moles of LiCl). The confinement media consist of mesoporous silica with pore diameters between 2 nm and 58 nm, with a small negative surface charge density. The vitrification of confined LiCl aqueous solutions was observed in all samples, expanding the vitrification region up to R = 15, and probably beyond for cooling rates of ≈1000 K/min. Ice crystallization was observed in some samples, except for those confined in the narrower pores. The onset and endpoint glass transition temperatures for the confined eutectic samples increase by 2 K and 5 K, respectively, for the smallest pore diameters (2 nm), which is equivalent to the effect of applying a pressure of up to 100 MPa to the bulk sample. This behavior is opposite of that reported for aqueous subeutectic NaCl solutions confined in silica glasses of similar sizes. We speculate that this is due to the fact that the mechanism of double confinement of the NaCl solution, between the pore wall and the precipitated ice, is not operative for LiCl solutions. Instead, the Li+ ions might force the hydration water in to a high-density state.
Fil: Longinotti, María Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Fuentes Landete, Violeta. Universidad de Innsbruck; Austria
Fil: Loerting, Thomas. Universidad de Innsbruck; Austria
Fil: Corti, Horacio Roberto. Comisión Nacional de Energía Atómica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
description The thermal transitions of confined LiCl aqueous solutions were studied by differential scanning calorimetry for solutions with salt concentrations with eutectic (R = 7) and subeutectic (R > 7) compositions (R = moles of water/moles of LiCl). The confinement media consist of mesoporous silica with pore diameters between 2 nm and 58 nm, with a small negative surface charge density. The vitrification of confined LiCl aqueous solutions was observed in all samples, expanding the vitrification region up to R = 15, and probably beyond for cooling rates of ≈1000 K/min. Ice crystallization was observed in some samples, except for those confined in the narrower pores. The onset and endpoint glass transition temperatures for the confined eutectic samples increase by 2 K and 5 K, respectively, for the smallest pore diameters (2 nm), which is equivalent to the effect of applying a pressure of up to 100 MPa to the bulk sample. This behavior is opposite of that reported for aqueous subeutectic NaCl solutions confined in silica glasses of similar sizes. We speculate that this is due to the fact that the mechanism of double confinement of the NaCl solution, between the pore wall and the precipitated ice, is not operative for LiCl solutions. Instead, the Li+ ions might force the hydration water in to a high-density state.
publishDate 2019
dc.date.none.fl_str_mv 2019-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/121411
Longinotti, María Paula; Fuentes Landete, Violeta; Loerting, Thomas; Corti, Horacio Roberto; Glass transition of LiCl aqueous solutions confined in mesoporous silica; American Institute of Physics; Journal of Chemical Physics; 151; 6; 8-2019; 1-12
0021-9606
CONICET Digital
CONICET
url http://hdl.handle.net/11336/121411
identifier_str_mv Longinotti, María Paula; Fuentes Landete, Violeta; Loerting, Thomas; Corti, Horacio Roberto; Glass transition of LiCl aqueous solutions confined in mesoporous silica; American Institute of Physics; Journal of Chemical Physics; 151; 6; 8-2019; 1-12
0021-9606
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1063/1.5102142
info:eu-repo/semantics/altIdentifier/url/https://aip.scitation.org/doi/10.1063/1.5102142
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Institute of Physics
publisher.none.fl_str_mv American Institute of Physics
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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