Engineering multilayer chemical networks

Autores
Martinez Amezaga, Maitena; Orrillo, Alfredo Gastón; Furlan, Ricardo Luis Eugenio
Año de publicación
2019
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Dynamic multilevel systems emerged in the last few years as new platforms to study thermodynamic systems. In this work, unprecedented fully communicated three-level systems are studied. First, different conditions were screened to selectively activate thiol/dithioacetal, thiol/thioester, and thiol/disulfide exchanges, individually or in pairs. Some of those conditions were applied, sequentially, to build multilayer dynamic systems wherein information, in the form of relative amounts of building blocks, can be directionally transmitted between different exchange pools. As far as we know, this is the first report of one synthetic dynamic chemical system where relationships between layers can be changed through network operations.
Fil: Martinez Amezaga, Maitena. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Departamento de Química Orgánica. Área Farmacognosia; Argentina
Fil: Orrillo, Alfredo Gastón. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Departamento de Química Orgánica. Área Farmacognosia; Argentina
Fil: Furlan, Ricardo Luis Eugenio. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Departamento de Química Orgánica. Área Farmacognosia; Argentina
Materia
REDES MULTICAPA
SISTEMAS QUÍMICOS MULTINIVEL
REACCIONES REVERSIBLES
DYNAMIC COVALENT CHEMISTRY
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/152792
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Engineering multilayer chemical networksMartinez Amezaga, MaitenaOrrillo, Alfredo GastónFurlan, Ricardo Luis EugenioREDES MULTICAPASISTEMAS QUÍMICOS MULTINIVELREACCIONES REVERSIBLESDYNAMIC COVALENT CHEMISTRYhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Dynamic multilevel systems emerged in the last few years as new platforms to study thermodynamic systems. In this work, unprecedented fully communicated three-level systems are studied. First, different conditions were screened to selectively activate thiol/dithioacetal, thiol/thioester, and thiol/disulfide exchanges, individually or in pairs. Some of those conditions were applied, sequentially, to build multilayer dynamic systems wherein information, in the form of relative amounts of building blocks, can be directionally transmitted between different exchange pools. As far as we know, this is the first report of one synthetic dynamic chemical system where relationships between layers can be changed through network operations.Fil: Martinez Amezaga, Maitena. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Departamento de Química Orgánica. Área Farmacognosia; ArgentinaFil: Orrillo, Alfredo Gastón. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Departamento de Química Orgánica. Área Farmacognosia; ArgentinaFil: Furlan, Ricardo Luis Eugenio. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Departamento de Química Orgánica. Área Farmacognosia; ArgentinaRoyal Society of Chemistry2019-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/152792Martinez Amezaga, Maitena; Orrillo, Alfredo Gastón; Furlan, Ricardo Luis Eugenio; Engineering multilayer chemical networks; Royal Society of Chemistry; Chemical Science; 36; 9-2019; 1-102041-65202041-6539CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://xlink.rsc.org/?DOI=C9SC02166Cinfo:eu-repo/semantics/altIdentifier/doi/10.1039/C9SC02166Cinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:53:31Zoai:ri.conicet.gov.ar:11336/152792instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:53:31.561CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Engineering multilayer chemical networks
title Engineering multilayer chemical networks
spellingShingle Engineering multilayer chemical networks
Martinez Amezaga, Maitena
REDES MULTICAPA
SISTEMAS QUÍMICOS MULTINIVEL
REACCIONES REVERSIBLES
DYNAMIC COVALENT CHEMISTRY
title_short Engineering multilayer chemical networks
title_full Engineering multilayer chemical networks
title_fullStr Engineering multilayer chemical networks
title_full_unstemmed Engineering multilayer chemical networks
title_sort Engineering multilayer chemical networks
dc.creator.none.fl_str_mv Martinez Amezaga, Maitena
Orrillo, Alfredo Gastón
Furlan, Ricardo Luis Eugenio
author Martinez Amezaga, Maitena
author_facet Martinez Amezaga, Maitena
Orrillo, Alfredo Gastón
Furlan, Ricardo Luis Eugenio
author_role author
author2 Orrillo, Alfredo Gastón
Furlan, Ricardo Luis Eugenio
author2_role author
author
dc.subject.none.fl_str_mv REDES MULTICAPA
SISTEMAS QUÍMICOS MULTINIVEL
REACCIONES REVERSIBLES
DYNAMIC COVALENT CHEMISTRY
topic REDES MULTICAPA
SISTEMAS QUÍMICOS MULTINIVEL
REACCIONES REVERSIBLES
DYNAMIC COVALENT CHEMISTRY
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Dynamic multilevel systems emerged in the last few years as new platforms to study thermodynamic systems. In this work, unprecedented fully communicated three-level systems are studied. First, different conditions were screened to selectively activate thiol/dithioacetal, thiol/thioester, and thiol/disulfide exchanges, individually or in pairs. Some of those conditions were applied, sequentially, to build multilayer dynamic systems wherein information, in the form of relative amounts of building blocks, can be directionally transmitted between different exchange pools. As far as we know, this is the first report of one synthetic dynamic chemical system where relationships between layers can be changed through network operations.
Fil: Martinez Amezaga, Maitena. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Departamento de Química Orgánica. Área Farmacognosia; Argentina
Fil: Orrillo, Alfredo Gastón. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Departamento de Química Orgánica. Área Farmacognosia; Argentina
Fil: Furlan, Ricardo Luis Eugenio. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Departamento de Química Orgánica. Área Farmacognosia; Argentina
description Dynamic multilevel systems emerged in the last few years as new platforms to study thermodynamic systems. In this work, unprecedented fully communicated three-level systems are studied. First, different conditions were screened to selectively activate thiol/dithioacetal, thiol/thioester, and thiol/disulfide exchanges, individually or in pairs. Some of those conditions were applied, sequentially, to build multilayer dynamic systems wherein information, in the form of relative amounts of building blocks, can be directionally transmitted between different exchange pools. As far as we know, this is the first report of one synthetic dynamic chemical system where relationships between layers can be changed through network operations.
publishDate 2019
dc.date.none.fl_str_mv 2019-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/152792
Martinez Amezaga, Maitena; Orrillo, Alfredo Gastón; Furlan, Ricardo Luis Eugenio; Engineering multilayer chemical networks; Royal Society of Chemistry; Chemical Science; 36; 9-2019; 1-10
2041-6520
2041-6539
CONICET Digital
CONICET
url http://hdl.handle.net/11336/152792
identifier_str_mv Martinez Amezaga, Maitena; Orrillo, Alfredo Gastón; Furlan, Ricardo Luis Eugenio; Engineering multilayer chemical networks; Royal Society of Chemistry; Chemical Science; 36; 9-2019; 1-10
2041-6520
2041-6539
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://xlink.rsc.org/?DOI=C9SC02166C
info:eu-repo/semantics/altIdentifier/doi/10.1039/C9SC02166C
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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