Ionic liquids-based nanoemulsion for assisted by ultrasound liquid–liquid microextraction of UV-filters in water samples

Autores
Fernández, Cintia Jimena; Gomez, Natalia Andrea; Oresti, Gerardo Martin; Domini, Claudia Elizabeth; Grunhut, Marcos
Año de publicación
2024
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Organic UV filters can contaminate various bodies of water such as streams, rivers, and seas, and as such, they have been identified as emerging contaminants of relevance in aquatic ecosystems. Therefore, the detection and determination of these compounds at low concentrations from an environmentally friendly perspective are necessary. In this work, an ionic liquids based nanoemulsion for the ultrasound assisted liquid–liquid microextraction (ILs-NE/US-LLME) of benzophenone-3, octocrylene, octisalate and octinoxate in different water bodies was reached. The material was based on a mixture of the ionic liquids 1,3-didecyl-2-methylimidazolium chloride and 1-butyl-3-methylimidazolium hexafluorophosphate, and the surfactant Triton X-100. The microextraction process was assisted by ultrasound and was performed using 475 µL of extractant solvent and 10.0 mL of sample, and an optimal preconcentration factor of 100 was achieved. The detection was performed by HPLC-UV in less than 5 min for all analytes. Low detection limits (lower than 2.0 µg L− 1 ) and an optimal precision (RSD lower than 6.7 %) were obtained for the four UV filters. Different water samples (pool, stream, river, sea and a simulated sample) were analyzed and satisfactory recovery values were obtained in all cases (82–119 %). The method was fast (15 min− 1 ) and it presented an optimal value of greenness (0.50) according to the AGREE metric. The extractant material was easily synthesized using a minimum amount of materials. The chromatographic procedure for separation and detection of the analytes was simple and fast. Moreover, the method was more environmentally friendly compared to previous work reported in the literatur
Fil: Fernández, Cintia Jimena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Gomez, Natalia Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Oresti, Gerardo Martin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Investigaciones Bioquímicas de Bahía Blanca. Universidad Nacional del Sur. Instituto de Investigaciones Bioquímicas de Bahía Blanca; Argentina. Universidad Nacional del Sur. Departamento de Biología, Bioquímica y Farmacia; Argentina
Fil: Domini, Claudia Elizabeth. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Grunhut, Marcos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Materia
Ionic liquids
Nanoemulsions
Ultrasound
UV filters
Liquid–liquid microextraction
Green analytical chemistry
Nivel de accesibilidad
acceso embargado
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/241604
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Ionic liquids-based nanoemulsion for assisted by ultrasound liquid–liquid microextraction of UV-filters in water samplesFernández, Cintia JimenaGomez, Natalia AndreaOresti, Gerardo MartinDomini, Claudia ElizabethGrunhut, MarcosIonic liquidsNanoemulsionsUltrasoundUV filtersLiquid–liquid microextractionGreen analytical chemistryhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Organic UV filters can contaminate various bodies of water such as streams, rivers, and seas, and as such, they have been identified as emerging contaminants of relevance in aquatic ecosystems. Therefore, the detection and determination of these compounds at low concentrations from an environmentally friendly perspective are necessary. In this work, an ionic liquids based nanoemulsion for the ultrasound assisted liquid–liquid microextraction (ILs-NE/US-LLME) of benzophenone-3, octocrylene, octisalate and octinoxate in different water bodies was reached. The material was based on a mixture of the ionic liquids 1,3-didecyl-2-methylimidazolium chloride and 1-butyl-3-methylimidazolium hexafluorophosphate, and the surfactant Triton X-100. The microextraction process was assisted by ultrasound and was performed using 475 µL of extractant solvent and 10.0 mL of sample, and an optimal preconcentration factor of 100 was achieved. The detection was performed by HPLC-UV in less than 5 min for all analytes. Low detection limits (lower than 2.0 µg L− 1 ) and an optimal precision (RSD lower than 6.7 %) were obtained for the four UV filters. Different water samples (pool, stream, river, sea and a simulated sample) were analyzed and satisfactory recovery values were obtained in all cases (82–119 %). The method was fast (15 min− 1 ) and it presented an optimal value of greenness (0.50) according to the AGREE metric. The extractant material was easily synthesized using a minimum amount of materials. The chromatographic procedure for separation and detection of the analytes was simple and fast. Moreover, the method was more environmentally friendly compared to previous work reported in the literaturFil: Fernández, Cintia Jimena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Gomez, Natalia Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Oresti, Gerardo Martin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Investigaciones Bioquímicas de Bahía Blanca. Universidad Nacional del Sur. Instituto de Investigaciones Bioquímicas de Bahía Blanca; Argentina. Universidad Nacional del Sur. Departamento de Biología, Bioquímica y Farmacia; ArgentinaFil: Domini, Claudia Elizabeth. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Grunhut, Marcos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaElsevier Science2024-06-18info:eu-repo/date/embargoEnd/2024-09-30info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/241604Fernández, Cintia Jimena; Gomez, Natalia Andrea; Oresti, Gerardo Martin; Domini, Claudia Elizabeth; Grunhut, Marcos; Ionic liquids-based nanoemulsion for assisted by ultrasound liquid–liquid microextraction of UV-filters in water samples; Elsevier Science; Microchemical Journal; 204; 18-6-2024; 1-80026-265X1095-9149CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0026265X24011196info:eu-repo/semantics/altIdentifier/doi/10.1016/j.microc.2024.111007info:eu-repo/semantics/embargoedAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:53:44Zoai:ri.conicet.gov.ar:11336/241604instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:53:44.467CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Ionic liquids-based nanoemulsion for assisted by ultrasound liquid–liquid microextraction of UV-filters in water samples
title Ionic liquids-based nanoemulsion for assisted by ultrasound liquid–liquid microextraction of UV-filters in water samples
spellingShingle Ionic liquids-based nanoemulsion for assisted by ultrasound liquid–liquid microextraction of UV-filters in water samples
Fernández, Cintia Jimena
Ionic liquids
Nanoemulsions
Ultrasound
UV filters
Liquid–liquid microextraction
Green analytical chemistry
title_short Ionic liquids-based nanoemulsion for assisted by ultrasound liquid–liquid microextraction of UV-filters in water samples
title_full Ionic liquids-based nanoemulsion for assisted by ultrasound liquid–liquid microextraction of UV-filters in water samples
title_fullStr Ionic liquids-based nanoemulsion for assisted by ultrasound liquid–liquid microextraction of UV-filters in water samples
title_full_unstemmed Ionic liquids-based nanoemulsion for assisted by ultrasound liquid–liquid microextraction of UV-filters in water samples
title_sort Ionic liquids-based nanoemulsion for assisted by ultrasound liquid–liquid microextraction of UV-filters in water samples
dc.creator.none.fl_str_mv Fernández, Cintia Jimena
Gomez, Natalia Andrea
Oresti, Gerardo Martin
Domini, Claudia Elizabeth
Grunhut, Marcos
author Fernández, Cintia Jimena
author_facet Fernández, Cintia Jimena
Gomez, Natalia Andrea
Oresti, Gerardo Martin
Domini, Claudia Elizabeth
Grunhut, Marcos
author_role author
author2 Gomez, Natalia Andrea
Oresti, Gerardo Martin
Domini, Claudia Elizabeth
Grunhut, Marcos
author2_role author
author
author
author
dc.subject.none.fl_str_mv Ionic liquids
Nanoemulsions
Ultrasound
UV filters
Liquid–liquid microextraction
Green analytical chemistry
topic Ionic liquids
Nanoemulsions
Ultrasound
UV filters
Liquid–liquid microextraction
Green analytical chemistry
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Organic UV filters can contaminate various bodies of water such as streams, rivers, and seas, and as such, they have been identified as emerging contaminants of relevance in aquatic ecosystems. Therefore, the detection and determination of these compounds at low concentrations from an environmentally friendly perspective are necessary. In this work, an ionic liquids based nanoemulsion for the ultrasound assisted liquid–liquid microextraction (ILs-NE/US-LLME) of benzophenone-3, octocrylene, octisalate and octinoxate in different water bodies was reached. The material was based on a mixture of the ionic liquids 1,3-didecyl-2-methylimidazolium chloride and 1-butyl-3-methylimidazolium hexafluorophosphate, and the surfactant Triton X-100. The microextraction process was assisted by ultrasound and was performed using 475 µL of extractant solvent and 10.0 mL of sample, and an optimal preconcentration factor of 100 was achieved. The detection was performed by HPLC-UV in less than 5 min for all analytes. Low detection limits (lower than 2.0 µg L− 1 ) and an optimal precision (RSD lower than 6.7 %) were obtained for the four UV filters. Different water samples (pool, stream, river, sea and a simulated sample) were analyzed and satisfactory recovery values were obtained in all cases (82–119 %). The method was fast (15 min− 1 ) and it presented an optimal value of greenness (0.50) according to the AGREE metric. The extractant material was easily synthesized using a minimum amount of materials. The chromatographic procedure for separation and detection of the analytes was simple and fast. Moreover, the method was more environmentally friendly compared to previous work reported in the literatur
Fil: Fernández, Cintia Jimena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Gomez, Natalia Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Oresti, Gerardo Martin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Investigaciones Bioquímicas de Bahía Blanca. Universidad Nacional del Sur. Instituto de Investigaciones Bioquímicas de Bahía Blanca; Argentina. Universidad Nacional del Sur. Departamento de Biología, Bioquímica y Farmacia; Argentina
Fil: Domini, Claudia Elizabeth. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Grunhut, Marcos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
description Organic UV filters can contaminate various bodies of water such as streams, rivers, and seas, and as such, they have been identified as emerging contaminants of relevance in aquatic ecosystems. Therefore, the detection and determination of these compounds at low concentrations from an environmentally friendly perspective are necessary. In this work, an ionic liquids based nanoemulsion for the ultrasound assisted liquid–liquid microextraction (ILs-NE/US-LLME) of benzophenone-3, octocrylene, octisalate and octinoxate in different water bodies was reached. The material was based on a mixture of the ionic liquids 1,3-didecyl-2-methylimidazolium chloride and 1-butyl-3-methylimidazolium hexafluorophosphate, and the surfactant Triton X-100. The microextraction process was assisted by ultrasound and was performed using 475 µL of extractant solvent and 10.0 mL of sample, and an optimal preconcentration factor of 100 was achieved. The detection was performed by HPLC-UV in less than 5 min for all analytes. Low detection limits (lower than 2.0 µg L− 1 ) and an optimal precision (RSD lower than 6.7 %) were obtained for the four UV filters. Different water samples (pool, stream, river, sea and a simulated sample) were analyzed and satisfactory recovery values were obtained in all cases (82–119 %). The method was fast (15 min− 1 ) and it presented an optimal value of greenness (0.50) according to the AGREE metric. The extractant material was easily synthesized using a minimum amount of materials. The chromatographic procedure for separation and detection of the analytes was simple and fast. Moreover, the method was more environmentally friendly compared to previous work reported in the literatur
publishDate 2024
dc.date.none.fl_str_mv 2024-06-18
info:eu-repo/date/embargoEnd/2024-09-30
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/241604
Fernández, Cintia Jimena; Gomez, Natalia Andrea; Oresti, Gerardo Martin; Domini, Claudia Elizabeth; Grunhut, Marcos; Ionic liquids-based nanoemulsion for assisted by ultrasound liquid–liquid microextraction of UV-filters in water samples; Elsevier Science; Microchemical Journal; 204; 18-6-2024; 1-8
0026-265X
1095-9149
CONICET Digital
CONICET
url http://hdl.handle.net/11336/241604
identifier_str_mv Fernández, Cintia Jimena; Gomez, Natalia Andrea; Oresti, Gerardo Martin; Domini, Claudia Elizabeth; Grunhut, Marcos; Ionic liquids-based nanoemulsion for assisted by ultrasound liquid–liquid microextraction of UV-filters in water samples; Elsevier Science; Microchemical Journal; 204; 18-6-2024; 1-8
0026-265X
1095-9149
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0026265X24011196
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.microc.2024.111007
dc.rights.none.fl_str_mv info:eu-repo/semantics/embargoedAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv embargoedAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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