Dispersive liquid–liquid microextraction and preconcentration of thallium species in water samples by two ionic liquids applied as ion-pairing reagent and extractant phase

Autores
Escudero, Leticia Belén; Berton, Paula; Martinis, Estefanía Mabel; Olsina, Roberto Antonio; Wuilloud, Rodolfo German
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In the present work, a simple and highly sensitive analytical methodology for determination of Tl+ and Tl3+ species, based on the use of modern and non-volatile solvents, such as ionic liquids (ILs), was developed. Initially, Tl+ was complexed by iodide ion at pH 1 in diluted sulfuric acid solution. Then, tetradecyl(trihexyl)phosphonium chloride ionic liquid (CYPHOS® IL 101) was used as ion-pairing reagent and a dispersive liquid?liquid microextraction (DLLME) procedure was developed by dispersing 60 mg of 1-hexyl-3-methylimidazolium hexafluorophosphate [C6mim][PF6] with 500 L of ethanol in the aqueous solution. After the microextraction procedure was finished, the final IL phase was solubilized in methanol and directly injected into the graphite furnace of an electrothermal atomic absorption spectrometer (ETAAS). An extraction efficiency of 77% and a sensitivity enhancement factor of 100 were obtained with only 5.00 mL of sample. The limit of detection (LOD) was 3.3 ng L-1 Tl while the relative standard deviation (RSD) was 5.3% (at 0.4 µg L-1 Tl and n = 10), calculated from the peak height of absorbance signals. The method was finally applied to determine Tl species in tap and river water samples after separation of Tl3+ species. To the best of our knowledge, this work reports the first application of ILs for Tl extraction and separation in the analytical field.
Fil: Escudero, Leticia Belén. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Regional de Investigaciones Científicas y Tecnológicas. Laboratorio de Investigaciones y Servicios Ambientales Mendoza; Argentina
Fil: Berton, Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Regional de Investigaciones Científicas y Tecnológicas. Laboratorio de Investigaciones y Servicios Ambientales Mendoza; Argentina
Fil: Martinis, Estefanía Mabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Regional de Investigaciones Científicas y Tecnológicas. Laboratorio de Investigaciones y Servicios Ambientales Mendoza; Argentina
Fil: Olsina, Roberto Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
Fil: Wuilloud, Rodolfo German. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Interdisciplinario de Ciencias Básicas. - Universidad Nacional de Cuyo. Instituto Interdisciplinario de Ciencias Básicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Regional de Investigaciones Científicas y Tecnológicas. Laboratorio de Investigaciones y Servicios Ambientales Mendoza; Argentina
Materia
Thallium
Ionic liquid
Speciation
Microextraction
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/244754
Acceder
id CONICETDig_f1fb5bfce377e4ff580db4852ac73945
oai_identifier_str oai:ri.conicet.gov.ar:11336/244754
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Dispersive liquid–liquid microextraction and preconcentration of thallium species in water samples by two ionic liquids applied as ion-pairing reagent and extractant phaseEscudero, Leticia BelénBerton, PaulaMartinis, Estefanía MabelOlsina, Roberto AntonioWuilloud, Rodolfo GermanThalliumIonic liquidSpeciationMicroextractionhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1In the present work, a simple and highly sensitive analytical methodology for determination of Tl+ and Tl3+ species, based on the use of modern and non-volatile solvents, such as ionic liquids (ILs), was developed. Initially, Tl+ was complexed by iodide ion at pH 1 in diluted sulfuric acid solution. Then, tetradecyl(trihexyl)phosphonium chloride ionic liquid (CYPHOS® IL 101) was used as ion-pairing reagent and a dispersive liquid?liquid microextraction (DLLME) procedure was developed by dispersing 60 mg of 1-hexyl-3-methylimidazolium hexafluorophosphate [C6mim][PF6] with 500 L of ethanol in the aqueous solution. After the microextraction procedure was finished, the final IL phase was solubilized in methanol and directly injected into the graphite furnace of an electrothermal atomic absorption spectrometer (ETAAS). An extraction efficiency of 77% and a sensitivity enhancement factor of 100 were obtained with only 5.00 mL of sample. The limit of detection (LOD) was 3.3 ng L-1 Tl while the relative standard deviation (RSD) was 5.3% (at 0.4 µg L-1 Tl and n = 10), calculated from the peak height of absorbance signals. The method was finally applied to determine Tl species in tap and river water samples after separation of Tl3+ species. To the best of our knowledge, this work reports the first application of ILs for Tl extraction and separation in the analytical field.Fil: Escudero, Leticia Belén. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Regional de Investigaciones Científicas y Tecnológicas. Laboratorio de Investigaciones y Servicios Ambientales Mendoza; ArgentinaFil: Berton, Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Regional de Investigaciones Científicas y Tecnológicas. Laboratorio de Investigaciones y Servicios Ambientales Mendoza; ArgentinaFil: Martinis, Estefanía Mabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Regional de Investigaciones Científicas y Tecnológicas. Laboratorio de Investigaciones y Servicios Ambientales Mendoza; ArgentinaFil: Olsina, Roberto Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; ArgentinaFil: Wuilloud, Rodolfo German. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Interdisciplinario de Ciencias Básicas. - Universidad Nacional de Cuyo. Instituto Interdisciplinario de Ciencias Básicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Regional de Investigaciones Científicas y Tecnológicas. Laboratorio de Investigaciones y Servicios Ambientales Mendoza; ArgentinaElsevier Science2012-01-15info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/244754Escudero, Leticia Belén; Berton, Paula; Martinis, Estefanía Mabel; Olsina, Roberto Antonio; Wuilloud, Rodolfo German; Dispersive liquid–liquid microextraction and preconcentration of thallium species in water samples by two ionic liquids applied as ion-pairing reagent and extractant phase; Elsevier Science; Talanta; 88; 15-1-2012; 277-2830039-9140CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0039914011009465info:eu-repo/semantics/altIdentifier/doi/10.1016/j.talanta.2011.09.068info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:58:40Zoai:ri.conicet.gov.ar:11336/244754instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:58:41.034CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Dispersive liquid–liquid microextraction and preconcentration of thallium species in water samples by two ionic liquids applied as ion-pairing reagent and extractant phase
title Dispersive liquid–liquid microextraction and preconcentration of thallium species in water samples by two ionic liquids applied as ion-pairing reagent and extractant phase
spellingShingle Dispersive liquid–liquid microextraction and preconcentration of thallium species in water samples by two ionic liquids applied as ion-pairing reagent and extractant phase
Escudero, Leticia Belén
Thallium
Ionic liquid
Speciation
Microextraction
title_short Dispersive liquid–liquid microextraction and preconcentration of thallium species in water samples by two ionic liquids applied as ion-pairing reagent and extractant phase
title_full Dispersive liquid–liquid microextraction and preconcentration of thallium species in water samples by two ionic liquids applied as ion-pairing reagent and extractant phase
title_fullStr Dispersive liquid–liquid microextraction and preconcentration of thallium species in water samples by two ionic liquids applied as ion-pairing reagent and extractant phase
title_full_unstemmed Dispersive liquid–liquid microextraction and preconcentration of thallium species in water samples by two ionic liquids applied as ion-pairing reagent and extractant phase
title_sort Dispersive liquid–liquid microextraction and preconcentration of thallium species in water samples by two ionic liquids applied as ion-pairing reagent and extractant phase
dc.creator.none.fl_str_mv Escudero, Leticia Belén
Berton, Paula
Martinis, Estefanía Mabel
Olsina, Roberto Antonio
Wuilloud, Rodolfo German
author Escudero, Leticia Belén
author_facet Escudero, Leticia Belén
Berton, Paula
Martinis, Estefanía Mabel
Olsina, Roberto Antonio
Wuilloud, Rodolfo German
author_role author
author2 Berton, Paula
Martinis, Estefanía Mabel
Olsina, Roberto Antonio
Wuilloud, Rodolfo German
author2_role author
author
author
author
dc.subject.none.fl_str_mv Thallium
Ionic liquid
Speciation
Microextraction
topic Thallium
Ionic liquid
Speciation
Microextraction
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv In the present work, a simple and highly sensitive analytical methodology for determination of Tl+ and Tl3+ species, based on the use of modern and non-volatile solvents, such as ionic liquids (ILs), was developed. Initially, Tl+ was complexed by iodide ion at pH 1 in diluted sulfuric acid solution. Then, tetradecyl(trihexyl)phosphonium chloride ionic liquid (CYPHOS® IL 101) was used as ion-pairing reagent and a dispersive liquid?liquid microextraction (DLLME) procedure was developed by dispersing 60 mg of 1-hexyl-3-methylimidazolium hexafluorophosphate [C6mim][PF6] with 500 L of ethanol in the aqueous solution. After the microextraction procedure was finished, the final IL phase was solubilized in methanol and directly injected into the graphite furnace of an electrothermal atomic absorption spectrometer (ETAAS). An extraction efficiency of 77% and a sensitivity enhancement factor of 100 were obtained with only 5.00 mL of sample. The limit of detection (LOD) was 3.3 ng L-1 Tl while the relative standard deviation (RSD) was 5.3% (at 0.4 µg L-1 Tl and n = 10), calculated from the peak height of absorbance signals. The method was finally applied to determine Tl species in tap and river water samples after separation of Tl3+ species. To the best of our knowledge, this work reports the first application of ILs for Tl extraction and separation in the analytical field.
Fil: Escudero, Leticia Belén. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Regional de Investigaciones Científicas y Tecnológicas. Laboratorio de Investigaciones y Servicios Ambientales Mendoza; Argentina
Fil: Berton, Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Regional de Investigaciones Científicas y Tecnológicas. Laboratorio de Investigaciones y Servicios Ambientales Mendoza; Argentina
Fil: Martinis, Estefanía Mabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Regional de Investigaciones Científicas y Tecnológicas. Laboratorio de Investigaciones y Servicios Ambientales Mendoza; Argentina
Fil: Olsina, Roberto Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
Fil: Wuilloud, Rodolfo German. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Interdisciplinario de Ciencias Básicas. - Universidad Nacional de Cuyo. Instituto Interdisciplinario de Ciencias Básicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Regional de Investigaciones Científicas y Tecnológicas. Laboratorio de Investigaciones y Servicios Ambientales Mendoza; Argentina
description In the present work, a simple and highly sensitive analytical methodology for determination of Tl+ and Tl3+ species, based on the use of modern and non-volatile solvents, such as ionic liquids (ILs), was developed. Initially, Tl+ was complexed by iodide ion at pH 1 in diluted sulfuric acid solution. Then, tetradecyl(trihexyl)phosphonium chloride ionic liquid (CYPHOS® IL 101) was used as ion-pairing reagent and a dispersive liquid?liquid microextraction (DLLME) procedure was developed by dispersing 60 mg of 1-hexyl-3-methylimidazolium hexafluorophosphate [C6mim][PF6] with 500 L of ethanol in the aqueous solution. After the microextraction procedure was finished, the final IL phase was solubilized in methanol and directly injected into the graphite furnace of an electrothermal atomic absorption spectrometer (ETAAS). An extraction efficiency of 77% and a sensitivity enhancement factor of 100 were obtained with only 5.00 mL of sample. The limit of detection (LOD) was 3.3 ng L-1 Tl while the relative standard deviation (RSD) was 5.3% (at 0.4 µg L-1 Tl and n = 10), calculated from the peak height of absorbance signals. The method was finally applied to determine Tl species in tap and river water samples after separation of Tl3+ species. To the best of our knowledge, this work reports the first application of ILs for Tl extraction and separation in the analytical field.
publishDate 2012
dc.date.none.fl_str_mv 2012-01-15
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/244754
Escudero, Leticia Belén; Berton, Paula; Martinis, Estefanía Mabel; Olsina, Roberto Antonio; Wuilloud, Rodolfo German; Dispersive liquid–liquid microextraction and preconcentration of thallium species in water samples by two ionic liquids applied as ion-pairing reagent and extractant phase; Elsevier Science; Talanta; 88; 15-1-2012; 277-283
0039-9140
CONICET Digital
CONICET
url http://hdl.handle.net/11336/244754
identifier_str_mv Escudero, Leticia Belén; Berton, Paula; Martinis, Estefanía Mabel; Olsina, Roberto Antonio; Wuilloud, Rodolfo German; Dispersive liquid–liquid microextraction and preconcentration of thallium species in water samples by two ionic liquids applied as ion-pairing reagent and extractant phase; Elsevier Science; Talanta; 88; 15-1-2012; 277-283
0039-9140
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0039914011009465
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.talanta.2011.09.068
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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