Dispersive liquid–liquid microextraction and preconcentration of thallium species in water samples by two ionic liquids applied as ion-pairing reagent and extractant phase
- Autores
- Escudero, Leticia Belén; Berton, Paula; Martinis, Estefanía Mabel; Olsina, Roberto Antonio; Wuilloud, Rodolfo German
- Año de publicación
- 2012
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- In the present work, a simple and highly sensitive analytical methodology for determination of Tl+ and Tl3+ species, based on the use of modern and non-volatile solvents, such as ionic liquids (ILs), was developed. Initially, Tl+ was complexed by iodide ion at pH 1 in diluted sulfuric acid solution. Then, tetradecyl(trihexyl)phosphonium chloride ionic liquid (CYPHOS® IL 101) was used as ion-pairing reagent and a dispersive liquid?liquid microextraction (DLLME) procedure was developed by dispersing 60 mg of 1-hexyl-3-methylimidazolium hexafluorophosphate [C6mim][PF6] with 500 L of ethanol in the aqueous solution. After the microextraction procedure was finished, the final IL phase was solubilized in methanol and directly injected into the graphite furnace of an electrothermal atomic absorption spectrometer (ETAAS). An extraction efficiency of 77% and a sensitivity enhancement factor of 100 were obtained with only 5.00 mL of sample. The limit of detection (LOD) was 3.3 ng L-1 Tl while the relative standard deviation (RSD) was 5.3% (at 0.4 µg L-1 Tl and n = 10), calculated from the peak height of absorbance signals. The method was finally applied to determine Tl species in tap and river water samples after separation of Tl3+ species. To the best of our knowledge, this work reports the first application of ILs for Tl extraction and separation in the analytical field.
Fil: Escudero, Leticia Belén. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Regional de Investigaciones Científicas y Tecnológicas. Laboratorio de Investigaciones y Servicios Ambientales Mendoza; Argentina
Fil: Berton, Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Regional de Investigaciones Científicas y Tecnológicas. Laboratorio de Investigaciones y Servicios Ambientales Mendoza; Argentina
Fil: Martinis, Estefanía Mabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Regional de Investigaciones Científicas y Tecnológicas. Laboratorio de Investigaciones y Servicios Ambientales Mendoza; Argentina
Fil: Olsina, Roberto Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
Fil: Wuilloud, Rodolfo German. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Interdisciplinario de Ciencias Básicas. - Universidad Nacional de Cuyo. Instituto Interdisciplinario de Ciencias Básicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Regional de Investigaciones Científicas y Tecnológicas. Laboratorio de Investigaciones y Servicios Ambientales Mendoza; Argentina - Materia
-
Thallium
Ionic liquid
Speciation
Microextraction - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/244754
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Dispersive liquid–liquid microextraction and preconcentration of thallium species in water samples by two ionic liquids applied as ion-pairing reagent and extractant phaseEscudero, Leticia BelénBerton, PaulaMartinis, Estefanía MabelOlsina, Roberto AntonioWuilloud, Rodolfo GermanThalliumIonic liquidSpeciationMicroextractionhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1In the present work, a simple and highly sensitive analytical methodology for determination of Tl+ and Tl3+ species, based on the use of modern and non-volatile solvents, such as ionic liquids (ILs), was developed. Initially, Tl+ was complexed by iodide ion at pH 1 in diluted sulfuric acid solution. Then, tetradecyl(trihexyl)phosphonium chloride ionic liquid (CYPHOS® IL 101) was used as ion-pairing reagent and a dispersive liquid?liquid microextraction (DLLME) procedure was developed by dispersing 60 mg of 1-hexyl-3-methylimidazolium hexafluorophosphate [C6mim][PF6] with 500 L of ethanol in the aqueous solution. After the microextraction procedure was finished, the final IL phase was solubilized in methanol and directly injected into the graphite furnace of an electrothermal atomic absorption spectrometer (ETAAS). An extraction efficiency of 77% and a sensitivity enhancement factor of 100 were obtained with only 5.00 mL of sample. The limit of detection (LOD) was 3.3 ng L-1 Tl while the relative standard deviation (RSD) was 5.3% (at 0.4 µg L-1 Tl and n = 10), calculated from the peak height of absorbance signals. The method was finally applied to determine Tl species in tap and river water samples after separation of Tl3+ species. To the best of our knowledge, this work reports the first application of ILs for Tl extraction and separation in the analytical field.Fil: Escudero, Leticia Belén. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Regional de Investigaciones Científicas y Tecnológicas. Laboratorio de Investigaciones y Servicios Ambientales Mendoza; ArgentinaFil: Berton, Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Regional de Investigaciones Científicas y Tecnológicas. Laboratorio de Investigaciones y Servicios Ambientales Mendoza; ArgentinaFil: Martinis, Estefanía Mabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Regional de Investigaciones Científicas y Tecnológicas. Laboratorio de Investigaciones y Servicios Ambientales Mendoza; ArgentinaFil: Olsina, Roberto Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; ArgentinaFil: Wuilloud, Rodolfo German. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Interdisciplinario de Ciencias Básicas. - Universidad Nacional de Cuyo. Instituto Interdisciplinario de Ciencias Básicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Regional de Investigaciones Científicas y Tecnológicas. Laboratorio de Investigaciones y Servicios Ambientales Mendoza; ArgentinaElsevier Science2012-01-15info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/244754Escudero, Leticia Belén; Berton, Paula; Martinis, Estefanía Mabel; Olsina, Roberto Antonio; Wuilloud, Rodolfo German; Dispersive liquid–liquid microextraction and preconcentration of thallium species in water samples by two ionic liquids applied as ion-pairing reagent and extractant phase; Elsevier Science; Talanta; 88; 15-1-2012; 277-2830039-9140CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0039914011009465info:eu-repo/semantics/altIdentifier/doi/10.1016/j.talanta.2011.09.068info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:55:40Zoai:ri.conicet.gov.ar:11336/244754instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:55:40.766CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Dispersive liquid–liquid microextraction and preconcentration of thallium species in water samples by two ionic liquids applied as ion-pairing reagent and extractant phase |
title |
Dispersive liquid–liquid microextraction and preconcentration of thallium species in water samples by two ionic liquids applied as ion-pairing reagent and extractant phase |
spellingShingle |
Dispersive liquid–liquid microextraction and preconcentration of thallium species in water samples by two ionic liquids applied as ion-pairing reagent and extractant phase Escudero, Leticia Belén Thallium Ionic liquid Speciation Microextraction |
title_short |
Dispersive liquid–liquid microextraction and preconcentration of thallium species in water samples by two ionic liquids applied as ion-pairing reagent and extractant phase |
title_full |
Dispersive liquid–liquid microextraction and preconcentration of thallium species in water samples by two ionic liquids applied as ion-pairing reagent and extractant phase |
title_fullStr |
Dispersive liquid–liquid microextraction and preconcentration of thallium species in water samples by two ionic liquids applied as ion-pairing reagent and extractant phase |
title_full_unstemmed |
Dispersive liquid–liquid microextraction and preconcentration of thallium species in water samples by two ionic liquids applied as ion-pairing reagent and extractant phase |
title_sort |
Dispersive liquid–liquid microextraction and preconcentration of thallium species in water samples by two ionic liquids applied as ion-pairing reagent and extractant phase |
dc.creator.none.fl_str_mv |
Escudero, Leticia Belén Berton, Paula Martinis, Estefanía Mabel Olsina, Roberto Antonio Wuilloud, Rodolfo German |
author |
Escudero, Leticia Belén |
author_facet |
Escudero, Leticia Belén Berton, Paula Martinis, Estefanía Mabel Olsina, Roberto Antonio Wuilloud, Rodolfo German |
author_role |
author |
author2 |
Berton, Paula Martinis, Estefanía Mabel Olsina, Roberto Antonio Wuilloud, Rodolfo German |
author2_role |
author author author author |
dc.subject.none.fl_str_mv |
Thallium Ionic liquid Speciation Microextraction |
topic |
Thallium Ionic liquid Speciation Microextraction |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
In the present work, a simple and highly sensitive analytical methodology for determination of Tl+ and Tl3+ species, based on the use of modern and non-volatile solvents, such as ionic liquids (ILs), was developed. Initially, Tl+ was complexed by iodide ion at pH 1 in diluted sulfuric acid solution. Then, tetradecyl(trihexyl)phosphonium chloride ionic liquid (CYPHOS® IL 101) was used as ion-pairing reagent and a dispersive liquid?liquid microextraction (DLLME) procedure was developed by dispersing 60 mg of 1-hexyl-3-methylimidazolium hexafluorophosphate [C6mim][PF6] with 500 L of ethanol in the aqueous solution. After the microextraction procedure was finished, the final IL phase was solubilized in methanol and directly injected into the graphite furnace of an electrothermal atomic absorption spectrometer (ETAAS). An extraction efficiency of 77% and a sensitivity enhancement factor of 100 were obtained with only 5.00 mL of sample. The limit of detection (LOD) was 3.3 ng L-1 Tl while the relative standard deviation (RSD) was 5.3% (at 0.4 µg L-1 Tl and n = 10), calculated from the peak height of absorbance signals. The method was finally applied to determine Tl species in tap and river water samples after separation of Tl3+ species. To the best of our knowledge, this work reports the first application of ILs for Tl extraction and separation in the analytical field. Fil: Escudero, Leticia Belén. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Regional de Investigaciones Científicas y Tecnológicas. Laboratorio de Investigaciones y Servicios Ambientales Mendoza; Argentina Fil: Berton, Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Regional de Investigaciones Científicas y Tecnológicas. Laboratorio de Investigaciones y Servicios Ambientales Mendoza; Argentina Fil: Martinis, Estefanía Mabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Regional de Investigaciones Científicas y Tecnológicas. Laboratorio de Investigaciones y Servicios Ambientales Mendoza; Argentina Fil: Olsina, Roberto Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina Fil: Wuilloud, Rodolfo German. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Interdisciplinario de Ciencias Básicas. - Universidad Nacional de Cuyo. Instituto Interdisciplinario de Ciencias Básicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Regional de Investigaciones Científicas y Tecnológicas. Laboratorio de Investigaciones y Servicios Ambientales Mendoza; Argentina |
description |
In the present work, a simple and highly sensitive analytical methodology for determination of Tl+ and Tl3+ species, based on the use of modern and non-volatile solvents, such as ionic liquids (ILs), was developed. Initially, Tl+ was complexed by iodide ion at pH 1 in diluted sulfuric acid solution. Then, tetradecyl(trihexyl)phosphonium chloride ionic liquid (CYPHOS® IL 101) was used as ion-pairing reagent and a dispersive liquid?liquid microextraction (DLLME) procedure was developed by dispersing 60 mg of 1-hexyl-3-methylimidazolium hexafluorophosphate [C6mim][PF6] with 500 L of ethanol in the aqueous solution. After the microextraction procedure was finished, the final IL phase was solubilized in methanol and directly injected into the graphite furnace of an electrothermal atomic absorption spectrometer (ETAAS). An extraction efficiency of 77% and a sensitivity enhancement factor of 100 were obtained with only 5.00 mL of sample. The limit of detection (LOD) was 3.3 ng L-1 Tl while the relative standard deviation (RSD) was 5.3% (at 0.4 µg L-1 Tl and n = 10), calculated from the peak height of absorbance signals. The method was finally applied to determine Tl species in tap and river water samples after separation of Tl3+ species. To the best of our knowledge, this work reports the first application of ILs for Tl extraction and separation in the analytical field. |
publishDate |
2012 |
dc.date.none.fl_str_mv |
2012-01-15 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/244754 Escudero, Leticia Belén; Berton, Paula; Martinis, Estefanía Mabel; Olsina, Roberto Antonio; Wuilloud, Rodolfo German; Dispersive liquid–liquid microextraction and preconcentration of thallium species in water samples by two ionic liquids applied as ion-pairing reagent and extractant phase; Elsevier Science; Talanta; 88; 15-1-2012; 277-283 0039-9140 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/244754 |
identifier_str_mv |
Escudero, Leticia Belén; Berton, Paula; Martinis, Estefanía Mabel; Olsina, Roberto Antonio; Wuilloud, Rodolfo German; Dispersive liquid–liquid microextraction and preconcentration of thallium species in water samples by two ionic liquids applied as ion-pairing reagent and extractant phase; Elsevier Science; Talanta; 88; 15-1-2012; 277-283 0039-9140 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0039914011009465 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.talanta.2011.09.068 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1842269359765979136 |
score |
13.13397 |