Structural and Mechanical Evolution of Mesoporous Films With Thermal Treatment: The Case of Brij 58 Templated Titania

Autores
Lionello, Diego Fernando; Steinberg, Paula Yael; Zalduendo, María Mercedes; Soler Illia, Galo Juan de Avila Arturo; Angelome, Paula Cecilia; Fuertes, María Cecilia
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Mesoporous titania thin films (MTTFs) with well ordered cubic array of mesopores were synthesized on glass and silicon substrates using Brij 58 as a template. The effect of the thermal treatment and the substrate on the structural parameters (thickness, porosity, pore order, and crystallinity) and the mechanical properties of MTTFs were determined by electron microscopy, X-ray diffraction, Raman spectroscopy, 2D-small angle X-ray scattering, ellipsometric porosimetry, and nanoindentation. Clear differences in the mesostructural order evolution and crystallization behavior were observed as a function of the substrate and the thermal treatment. In particular, the anatase crystallization process occurs at lower temperatures for samples prepared on silicon when compared with samples prepared on glass, due to the balance between nanocrystals formation, mass diffusion, and Na+ migration from the substrate. As a consequence of such phenomena, the MTTFs mechanical properties are also dependent on the substrate. For samples prepared on glass the 325–350 °C range is the optimal annealing temperature to maximize the mechanical properties (E value of 45 GPa), while higher temperatures can be used for the Si supported oxides, to reach E values of 60 GPa. The obtained anatase crystal dimensions (below 4–5 nm) are restricted by the wall thickness, indicating the chosen thermal treatment prevents the mesoporous structure from collapsing even when the oxide presents thin walls and small pores, preserving high porosity and high porous ordering. As a consequence, the presented Brij 58 templated MTTFs exhibits smaller crystalline domains than analogous materials with thicker walls. Such properties could be exploited for applications in photocatalysis and titania-based solar cells.
Fil: Lionello, Diego Fernando. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Universidad Nacional de San Martín. Instituto Sabato; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Steinberg, Paula Yael. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Zalduendo, María Mercedes. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Soler Illia, Galo Juan de Avila Arturo. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Angelome, Paula Cecilia. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Fuertes, María Cecilia. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Universidad Nacional de San Martín. Instituto Sabato; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Materia
MESOPOROUS MATERIALS
MECHANICAL PROPERTIES
NANOINDENTATION
Nivel de accesibilidad
acceso embargado
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/41124
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oai_identifier_str oai:ri.conicet.gov.ar:11336/41124
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Structural and Mechanical Evolution of Mesoporous Films With Thermal Treatment: The Case of Brij 58 Templated TitaniaLionello, Diego FernandoSteinberg, Paula YaelZalduendo, María MercedesSoler Illia, Galo Juan de Avila ArturoAngelome, Paula CeciliaFuertes, María CeciliaMESOPOROUS MATERIALSMECHANICAL PROPERTIESNANOINDENTATIONhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2Mesoporous titania thin films (MTTFs) with well ordered cubic array of mesopores were synthesized on glass and silicon substrates using Brij 58 as a template. The effect of the thermal treatment and the substrate on the structural parameters (thickness, porosity, pore order, and crystallinity) and the mechanical properties of MTTFs were determined by electron microscopy, X-ray diffraction, Raman spectroscopy, 2D-small angle X-ray scattering, ellipsometric porosimetry, and nanoindentation. Clear differences in the mesostructural order evolution and crystallization behavior were observed as a function of the substrate and the thermal treatment. In particular, the anatase crystallization process occurs at lower temperatures for samples prepared on silicon when compared with samples prepared on glass, due to the balance between nanocrystals formation, mass diffusion, and Na+ migration from the substrate. As a consequence of such phenomena, the MTTFs mechanical properties are also dependent on the substrate. For samples prepared on glass the 325–350 °C range is the optimal annealing temperature to maximize the mechanical properties (E value of 45 GPa), while higher temperatures can be used for the Si supported oxides, to reach E values of 60 GPa. The obtained anatase crystal dimensions (below 4–5 nm) are restricted by the wall thickness, indicating the chosen thermal treatment prevents the mesoporous structure from collapsing even when the oxide presents thin walls and small pores, preserving high porosity and high porous ordering. As a consequence, the presented Brij 58 templated MTTFs exhibits smaller crystalline domains than analogous materials with thicker walls. Such properties could be exploited for applications in photocatalysis and titania-based solar cells.Fil: Lionello, Diego Fernando. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Universidad Nacional de San Martín. Instituto Sabato; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Steinberg, Paula Yael. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Zalduendo, María Mercedes. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Soler Illia, Galo Juan de Avila Arturo. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Angelome, Paula Cecilia. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Fuertes, María Cecilia. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Universidad Nacional de San Martín. Instituto Sabato; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaAmerican Chemical Society2017-09info:eu-repo/date/embargoEnd/2018-10-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/41124Lionello, Diego Fernando; Steinberg, Paula Yael; Zalduendo, María Mercedes; Soler Illia, Galo Juan de Avila Arturo; Angelome, Paula Cecilia; et al.; Structural and Mechanical Evolution of Mesoporous Films With Thermal Treatment: The Case of Brij 58 Templated Titania; American Chemical Society; Journal of Physical Chemistry C; 121; 40; 9-2017; 22576-225861932-7447CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/acs.jpcc.7b09054info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acs.jpcc.7b09054info:eu-repo/semantics/embargoedAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:09:04Zoai:ri.conicet.gov.ar:11336/41124instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:09:04.618CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Structural and Mechanical Evolution of Mesoporous Films With Thermal Treatment: The Case of Brij 58 Templated Titania
title Structural and Mechanical Evolution of Mesoporous Films With Thermal Treatment: The Case of Brij 58 Templated Titania
spellingShingle Structural and Mechanical Evolution of Mesoporous Films With Thermal Treatment: The Case of Brij 58 Templated Titania
Lionello, Diego Fernando
MESOPOROUS MATERIALS
MECHANICAL PROPERTIES
NANOINDENTATION
title_short Structural and Mechanical Evolution of Mesoporous Films With Thermal Treatment: The Case of Brij 58 Templated Titania
title_full Structural and Mechanical Evolution of Mesoporous Films With Thermal Treatment: The Case of Brij 58 Templated Titania
title_fullStr Structural and Mechanical Evolution of Mesoporous Films With Thermal Treatment: The Case of Brij 58 Templated Titania
title_full_unstemmed Structural and Mechanical Evolution of Mesoporous Films With Thermal Treatment: The Case of Brij 58 Templated Titania
title_sort Structural and Mechanical Evolution of Mesoporous Films With Thermal Treatment: The Case of Brij 58 Templated Titania
dc.creator.none.fl_str_mv Lionello, Diego Fernando
Steinberg, Paula Yael
Zalduendo, María Mercedes
Soler Illia, Galo Juan de Avila Arturo
Angelome, Paula Cecilia
Fuertes, María Cecilia
author Lionello, Diego Fernando
author_facet Lionello, Diego Fernando
Steinberg, Paula Yael
Zalduendo, María Mercedes
Soler Illia, Galo Juan de Avila Arturo
Angelome, Paula Cecilia
Fuertes, María Cecilia
author_role author
author2 Steinberg, Paula Yael
Zalduendo, María Mercedes
Soler Illia, Galo Juan de Avila Arturo
Angelome, Paula Cecilia
Fuertes, María Cecilia
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv MESOPOROUS MATERIALS
MECHANICAL PROPERTIES
NANOINDENTATION
topic MESOPOROUS MATERIALS
MECHANICAL PROPERTIES
NANOINDENTATION
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Mesoporous titania thin films (MTTFs) with well ordered cubic array of mesopores were synthesized on glass and silicon substrates using Brij 58 as a template. The effect of the thermal treatment and the substrate on the structural parameters (thickness, porosity, pore order, and crystallinity) and the mechanical properties of MTTFs were determined by electron microscopy, X-ray diffraction, Raman spectroscopy, 2D-small angle X-ray scattering, ellipsometric porosimetry, and nanoindentation. Clear differences in the mesostructural order evolution and crystallization behavior were observed as a function of the substrate and the thermal treatment. In particular, the anatase crystallization process occurs at lower temperatures for samples prepared on silicon when compared with samples prepared on glass, due to the balance between nanocrystals formation, mass diffusion, and Na+ migration from the substrate. As a consequence of such phenomena, the MTTFs mechanical properties are also dependent on the substrate. For samples prepared on glass the 325–350 °C range is the optimal annealing temperature to maximize the mechanical properties (E value of 45 GPa), while higher temperatures can be used for the Si supported oxides, to reach E values of 60 GPa. The obtained anatase crystal dimensions (below 4–5 nm) are restricted by the wall thickness, indicating the chosen thermal treatment prevents the mesoporous structure from collapsing even when the oxide presents thin walls and small pores, preserving high porosity and high porous ordering. As a consequence, the presented Brij 58 templated MTTFs exhibits smaller crystalline domains than analogous materials with thicker walls. Such properties could be exploited for applications in photocatalysis and titania-based solar cells.
Fil: Lionello, Diego Fernando. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Universidad Nacional de San Martín. Instituto Sabato; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Steinberg, Paula Yael. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Zalduendo, María Mercedes. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Soler Illia, Galo Juan de Avila Arturo. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Angelome, Paula Cecilia. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Fuertes, María Cecilia. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Universidad Nacional de San Martín. Instituto Sabato; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
description Mesoporous titania thin films (MTTFs) with well ordered cubic array of mesopores were synthesized on glass and silicon substrates using Brij 58 as a template. The effect of the thermal treatment and the substrate on the structural parameters (thickness, porosity, pore order, and crystallinity) and the mechanical properties of MTTFs were determined by electron microscopy, X-ray diffraction, Raman spectroscopy, 2D-small angle X-ray scattering, ellipsometric porosimetry, and nanoindentation. Clear differences in the mesostructural order evolution and crystallization behavior were observed as a function of the substrate and the thermal treatment. In particular, the anatase crystallization process occurs at lower temperatures for samples prepared on silicon when compared with samples prepared on glass, due to the balance between nanocrystals formation, mass diffusion, and Na+ migration from the substrate. As a consequence of such phenomena, the MTTFs mechanical properties are also dependent on the substrate. For samples prepared on glass the 325–350 °C range is the optimal annealing temperature to maximize the mechanical properties (E value of 45 GPa), while higher temperatures can be used for the Si supported oxides, to reach E values of 60 GPa. The obtained anatase crystal dimensions (below 4–5 nm) are restricted by the wall thickness, indicating the chosen thermal treatment prevents the mesoporous structure from collapsing even when the oxide presents thin walls and small pores, preserving high porosity and high porous ordering. As a consequence, the presented Brij 58 templated MTTFs exhibits smaller crystalline domains than analogous materials with thicker walls. Such properties could be exploited for applications in photocatalysis and titania-based solar cells.
publishDate 2017
dc.date.none.fl_str_mv 2017-09
info:eu-repo/date/embargoEnd/2018-10-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/41124
Lionello, Diego Fernando; Steinberg, Paula Yael; Zalduendo, María Mercedes; Soler Illia, Galo Juan de Avila Arturo; Angelome, Paula Cecilia; et al.; Structural and Mechanical Evolution of Mesoporous Films With Thermal Treatment: The Case of Brij 58 Templated Titania; American Chemical Society; Journal of Physical Chemistry C; 121; 40; 9-2017; 22576-22586
1932-7447
CONICET Digital
CONICET
url http://hdl.handle.net/11336/41124
identifier_str_mv Lionello, Diego Fernando; Steinberg, Paula Yael; Zalduendo, María Mercedes; Soler Illia, Galo Juan de Avila Arturo; Angelome, Paula Cecilia; et al.; Structural and Mechanical Evolution of Mesoporous Films With Thermal Treatment: The Case of Brij 58 Templated Titania; American Chemical Society; Journal of Physical Chemistry C; 121; 40; 9-2017; 22576-22586
1932-7447
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.jpcc.7b09054
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acs.jpcc.7b09054
dc.rights.none.fl_str_mv info:eu-repo/semantics/embargoedAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv embargoedAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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