Structural and topologic aspects of carbonium ions (C=1-4)

Autores
Okulik, Nora Beatriz; Jubert, Alicia Haydee; Castro, Eduardo Alberto
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Since the original Olah's discovery a large number of carbocations have been prepared and their properties studied in great detail. Stable carbocations could be prepared through the use of extremely acidic compounds. Thus, pentacoordinated carbonium ions have been obtained from methane higher alkanes and various cycloalkanes. However, the characterization of these protonated species using spectroscopic techniques is a difficult task to accomplish. This fact reveals the importance of using theoretical tools to complement experimental efforts to study suitably these chemical ions. In this review, we present an exhaustive study on structural investigations and topologic characterizations using atoms-in-molecules method of carbonium ions (C=1-4) in order to get a suitable improvement of our understanding of the chemical bonding in these species.
Fil: Okulik, Nora Beatriz. Universidad Nacional del Chaco Austral. Departamento de Ciencias Básicas y Aplicadas. Laboratorio de Ingeniería de las Reacciones Químicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste; Argentina
Fil: Jubert, Alicia Haydee. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Castro, Eduardo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Materia
Carbocations
Three-Centre Bonds
C1-C4 Alkanes
Activation
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/80096
Acceder
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network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling Structural and topologic aspects of carbonium ions (C=1-4)Okulik, Nora BeatrizJubert, Alicia HaydeeCastro, Eduardo AlbertoCarbocationsThree-Centre BondsC1-C4 AlkanesActivationhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Since the original Olah's discovery a large number of carbocations have been prepared and their properties studied in great detail. Stable carbocations could be prepared through the use of extremely acidic compounds. Thus, pentacoordinated carbonium ions have been obtained from methane higher alkanes and various cycloalkanes. However, the characterization of these protonated species using spectroscopic techniques is a difficult task to accomplish. This fact reveals the importance of using theoretical tools to complement experimental efforts to study suitably these chemical ions. In this review, we present an exhaustive study on structural investigations and topologic characterizations using atoms-in-molecules method of carbonium ions (C=1-4) in order to get a suitable improvement of our understanding of the chemical bonding in these species.Fil: Okulik, Nora Beatriz. Universidad Nacional del Chaco Austral. Departamento de Ciencias Básicas y Aplicadas. Laboratorio de Ingeniería de las Reacciones Químicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste; ArgentinaFil: Jubert, Alicia Haydee. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Castro, Eduardo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaResearch Trends2011-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/80096Okulik, Nora Beatriz; Jubert, Alicia Haydee; Castro, Eduardo Alberto; Structural and topologic aspects of carbonium ions (C=1-4); Research Trends; Trends in Organic Chemistry; 15; 6-2011; 51-720972-4362CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.researchtrends.net/tia/abstract.asp?in=0&vn=15&tid=14&aid=3320&pub=2011&type=3info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:35:27Zoai:ri.conicet.gov.ar:11336/80096instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:35:27.407CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Structural and topologic aspects of carbonium ions (C=1-4)
title Structural and topologic aspects of carbonium ions (C=1-4)
spellingShingle Structural and topologic aspects of carbonium ions (C=1-4)
Okulik, Nora Beatriz
Carbocations
Three-Centre Bonds
C1-C4 Alkanes
Activation
title_short Structural and topologic aspects of carbonium ions (C=1-4)
title_full Structural and topologic aspects of carbonium ions (C=1-4)
title_fullStr Structural and topologic aspects of carbonium ions (C=1-4)
title_full_unstemmed Structural and topologic aspects of carbonium ions (C=1-4)
title_sort Structural and topologic aspects of carbonium ions (C=1-4)
dc.creator.none.fl_str_mv Okulik, Nora Beatriz
Jubert, Alicia Haydee
Castro, Eduardo Alberto
author Okulik, Nora Beatriz
author_facet Okulik, Nora Beatriz
Jubert, Alicia Haydee
Castro, Eduardo Alberto
author_role author
author2 Jubert, Alicia Haydee
Castro, Eduardo Alberto
author2_role author
author
dc.subject.none.fl_str_mv Carbocations
Three-Centre Bonds
C1-C4 Alkanes
Activation
topic Carbocations
Three-Centre Bonds
C1-C4 Alkanes
Activation
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Since the original Olah's discovery a large number of carbocations have been prepared and their properties studied in great detail. Stable carbocations could be prepared through the use of extremely acidic compounds. Thus, pentacoordinated carbonium ions have been obtained from methane higher alkanes and various cycloalkanes. However, the characterization of these protonated species using spectroscopic techniques is a difficult task to accomplish. This fact reveals the importance of using theoretical tools to complement experimental efforts to study suitably these chemical ions. In this review, we present an exhaustive study on structural investigations and topologic characterizations using atoms-in-molecules method of carbonium ions (C=1-4) in order to get a suitable improvement of our understanding of the chemical bonding in these species.
Fil: Okulik, Nora Beatriz. Universidad Nacional del Chaco Austral. Departamento de Ciencias Básicas y Aplicadas. Laboratorio de Ingeniería de las Reacciones Químicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste; Argentina
Fil: Jubert, Alicia Haydee. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Castro, Eduardo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
description Since the original Olah's discovery a large number of carbocations have been prepared and their properties studied in great detail. Stable carbocations could be prepared through the use of extremely acidic compounds. Thus, pentacoordinated carbonium ions have been obtained from methane higher alkanes and various cycloalkanes. However, the characterization of these protonated species using spectroscopic techniques is a difficult task to accomplish. This fact reveals the importance of using theoretical tools to complement experimental efforts to study suitably these chemical ions. In this review, we present an exhaustive study on structural investigations and topologic characterizations using atoms-in-molecules method of carbonium ions (C=1-4) in order to get a suitable improvement of our understanding of the chemical bonding in these species.
publishDate 2011
dc.date.none.fl_str_mv 2011-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/80096
Okulik, Nora Beatriz; Jubert, Alicia Haydee; Castro, Eduardo Alberto; Structural and topologic aspects of carbonium ions (C=1-4); Research Trends; Trends in Organic Chemistry; 15; 6-2011; 51-72
0972-4362
CONICET Digital
CONICET
url http://hdl.handle.net/11336/80096
identifier_str_mv Okulik, Nora Beatriz; Jubert, Alicia Haydee; Castro, Eduardo Alberto; Structural and topologic aspects of carbonium ions (C=1-4); Research Trends; Trends in Organic Chemistry; 15; 6-2011; 51-72
0972-4362
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.researchtrends.net/tia/abstract.asp?in=0&vn=15&tid=14&aid=3320&pub=2011&type=3
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Research Trends
publisher.none.fl_str_mv Research Trends
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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