Selective gas phase hydrogenation of maleic anhydride over Ni-supported catalysts: Effect of support on the catalytic performance

Autores
Regenhardt, Silvina Andrea; Meyer, Camilo Ignacio; Garetto, Teresita Francisca; Marchi, Alberto Julio
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The gas phase hydrogenation of maleic anhydride to obtain γ-butyrolactone was studied using Ni supported on SiO2, SiO2–Al2O3 and zeolite H-BEA as catalysts. The samples were prepared by incipient wetness impregnation and characterized by N2 adsorption at −196 °C (Sg), X-ray diffraction (XRD), temperature programmed reduction (TPR), temperature programmed desorption of NH3 (TPD-NH3) and chemisorption of H2. The reaction was carried out at 170 °C and 220 °C in a fixed bed reactor operating at atmospheric pressure. From the characterization results, it was determined that the degree of Ni2+–support interaction varies according to the following pattern: Ni/HBEA > Ni/SiO2–Al2O3 > Ni/SiO2. All catalysts were very active in the hydrogenation of maleic anhydride to succinic anhydride. However, hydrogenolytic activity and stability of nickel-based catalyst varies with the degree of interaction Ni2+–support. Ni/H-BEA, in which Ni2+–support interaction is the highest, was active in the hydrogenolysis of succinic anhydride to γ-butyrolactone but it was not stable. By contrast, Ni/SiO2–Al2O3 and Ni/SiO2, with medium or low degree of Ni2+–support interaction, were more stable than Ni/H-BEA. In addition, Ni/SiO2–Al2O3, with a medium degree of Ni2+–support interaction, was the most stable and selective to γ-butyrolactone, especially when the reaction was carried out at 220 °C.
Fil: Regenhardt, Silvina Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Meyer, Camilo Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Garetto, Teresita Francisca. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Marchi, Alberto Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Materia
Hydrogenation
Hydrogenolysis
Ni-Based Catalysts
Gamma-Butyrolactone
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/52373
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/52373
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Selective gas phase hydrogenation of maleic anhydride over Ni-supported catalysts: Effect of support on the catalytic performanceRegenhardt, Silvina AndreaMeyer, Camilo IgnacioGaretto, Teresita FranciscaMarchi, Alberto JulioHydrogenationHydrogenolysisNi-Based CatalystsGamma-Butyrolactonehttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The gas phase hydrogenation of maleic anhydride to obtain γ-butyrolactone was studied using Ni supported on SiO2, SiO2–Al2O3 and zeolite H-BEA as catalysts. The samples were prepared by incipient wetness impregnation and characterized by N2 adsorption at −196 °C (Sg), X-ray diffraction (XRD), temperature programmed reduction (TPR), temperature programmed desorption of NH3 (TPD-NH3) and chemisorption of H2. The reaction was carried out at 170 °C and 220 °C in a fixed bed reactor operating at atmospheric pressure. From the characterization results, it was determined that the degree of Ni2+–support interaction varies according to the following pattern: Ni/HBEA > Ni/SiO2–Al2O3 > Ni/SiO2. All catalysts were very active in the hydrogenation of maleic anhydride to succinic anhydride. However, hydrogenolytic activity and stability of nickel-based catalyst varies with the degree of interaction Ni2+–support. Ni/H-BEA, in which Ni2+–support interaction is the highest, was active in the hydrogenolysis of succinic anhydride to γ-butyrolactone but it was not stable. By contrast, Ni/SiO2–Al2O3 and Ni/SiO2, with medium or low degree of Ni2+–support interaction, were more stable than Ni/H-BEA. In addition, Ni/SiO2–Al2O3, with a medium degree of Ni2+–support interaction, was the most stable and selective to γ-butyrolactone, especially when the reaction was carried out at 220 °C.Fil: Regenhardt, Silvina Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Meyer, Camilo Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Garetto, Teresita Francisca. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Marchi, Alberto Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaElsevier Science2012-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/52373Regenhardt, Silvina Andrea; Meyer, Camilo Ignacio; Garetto, Teresita Francisca; Marchi, Alberto Julio; Selective gas phase hydrogenation of maleic anhydride over Ni-supported catalysts: Effect of support on the catalytic performance; Elsevier Science; Applied Catalysis A: General; 449; 10-2012; 81-870926-860XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/www.sciencedirect.com/science/article/pii/S0926860X12006163info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2012.09.023info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:55:25Zoai:ri.conicet.gov.ar:11336/52373instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:55:25.863CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Selective gas phase hydrogenation of maleic anhydride over Ni-supported catalysts: Effect of support on the catalytic performance
title Selective gas phase hydrogenation of maleic anhydride over Ni-supported catalysts: Effect of support on the catalytic performance
spellingShingle Selective gas phase hydrogenation of maleic anhydride over Ni-supported catalysts: Effect of support on the catalytic performance
Regenhardt, Silvina Andrea
Hydrogenation
Hydrogenolysis
Ni-Based Catalysts
Gamma-Butyrolactone
title_short Selective gas phase hydrogenation of maleic anhydride over Ni-supported catalysts: Effect of support on the catalytic performance
title_full Selective gas phase hydrogenation of maleic anhydride over Ni-supported catalysts: Effect of support on the catalytic performance
title_fullStr Selective gas phase hydrogenation of maleic anhydride over Ni-supported catalysts: Effect of support on the catalytic performance
title_full_unstemmed Selective gas phase hydrogenation of maleic anhydride over Ni-supported catalysts: Effect of support on the catalytic performance
title_sort Selective gas phase hydrogenation of maleic anhydride over Ni-supported catalysts: Effect of support on the catalytic performance
dc.creator.none.fl_str_mv Regenhardt, Silvina Andrea
Meyer, Camilo Ignacio
Garetto, Teresita Francisca
Marchi, Alberto Julio
author Regenhardt, Silvina Andrea
author_facet Regenhardt, Silvina Andrea
Meyer, Camilo Ignacio
Garetto, Teresita Francisca
Marchi, Alberto Julio
author_role author
author2 Meyer, Camilo Ignacio
Garetto, Teresita Francisca
Marchi, Alberto Julio
author2_role author
author
author
dc.subject.none.fl_str_mv Hydrogenation
Hydrogenolysis
Ni-Based Catalysts
Gamma-Butyrolactone
topic Hydrogenation
Hydrogenolysis
Ni-Based Catalysts
Gamma-Butyrolactone
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The gas phase hydrogenation of maleic anhydride to obtain γ-butyrolactone was studied using Ni supported on SiO2, SiO2–Al2O3 and zeolite H-BEA as catalysts. The samples were prepared by incipient wetness impregnation and characterized by N2 adsorption at −196 °C (Sg), X-ray diffraction (XRD), temperature programmed reduction (TPR), temperature programmed desorption of NH3 (TPD-NH3) and chemisorption of H2. The reaction was carried out at 170 °C and 220 °C in a fixed bed reactor operating at atmospheric pressure. From the characterization results, it was determined that the degree of Ni2+–support interaction varies according to the following pattern: Ni/HBEA > Ni/SiO2–Al2O3 > Ni/SiO2. All catalysts were very active in the hydrogenation of maleic anhydride to succinic anhydride. However, hydrogenolytic activity and stability of nickel-based catalyst varies with the degree of interaction Ni2+–support. Ni/H-BEA, in which Ni2+–support interaction is the highest, was active in the hydrogenolysis of succinic anhydride to γ-butyrolactone but it was not stable. By contrast, Ni/SiO2–Al2O3 and Ni/SiO2, with medium or low degree of Ni2+–support interaction, were more stable than Ni/H-BEA. In addition, Ni/SiO2–Al2O3, with a medium degree of Ni2+–support interaction, was the most stable and selective to γ-butyrolactone, especially when the reaction was carried out at 220 °C.
Fil: Regenhardt, Silvina Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Meyer, Camilo Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Garetto, Teresita Francisca. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Marchi, Alberto Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
description The gas phase hydrogenation of maleic anhydride to obtain γ-butyrolactone was studied using Ni supported on SiO2, SiO2–Al2O3 and zeolite H-BEA as catalysts. The samples were prepared by incipient wetness impregnation and characterized by N2 adsorption at −196 °C (Sg), X-ray diffraction (XRD), temperature programmed reduction (TPR), temperature programmed desorption of NH3 (TPD-NH3) and chemisorption of H2. The reaction was carried out at 170 °C and 220 °C in a fixed bed reactor operating at atmospheric pressure. From the characterization results, it was determined that the degree of Ni2+–support interaction varies according to the following pattern: Ni/HBEA > Ni/SiO2–Al2O3 > Ni/SiO2. All catalysts were very active in the hydrogenation of maleic anhydride to succinic anhydride. However, hydrogenolytic activity and stability of nickel-based catalyst varies with the degree of interaction Ni2+–support. Ni/H-BEA, in which Ni2+–support interaction is the highest, was active in the hydrogenolysis of succinic anhydride to γ-butyrolactone but it was not stable. By contrast, Ni/SiO2–Al2O3 and Ni/SiO2, with medium or low degree of Ni2+–support interaction, were more stable than Ni/H-BEA. In addition, Ni/SiO2–Al2O3, with a medium degree of Ni2+–support interaction, was the most stable and selective to γ-butyrolactone, especially when the reaction was carried out at 220 °C.
publishDate 2012
dc.date.none.fl_str_mv 2012-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/52373
Regenhardt, Silvina Andrea; Meyer, Camilo Ignacio; Garetto, Teresita Francisca; Marchi, Alberto Julio; Selective gas phase hydrogenation of maleic anhydride over Ni-supported catalysts: Effect of support on the catalytic performance; Elsevier Science; Applied Catalysis A: General; 449; 10-2012; 81-87
0926-860X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/52373
identifier_str_mv Regenhardt, Silvina Andrea; Meyer, Camilo Ignacio; Garetto, Teresita Francisca; Marchi, Alberto Julio; Selective gas phase hydrogenation of maleic anhydride over Ni-supported catalysts: Effect of support on the catalytic performance; Elsevier Science; Applied Catalysis A: General; 449; 10-2012; 81-87
0926-860X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/www.sciencedirect.com/science/article/pii/S0926860X12006163
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2012.09.023
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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