Highly selective conversion of maleic anhydride to gamma-butyrolactone over Ni-supported catalysts prepared by precipitation-deposition method

Autores
Bertone, Matías Ezequiel; Meyer, Camilo Ignacio; Regenhardt, Silvina Andrea; Sebastian, Victor; Garetto, Teresita Francisca; Marchi, Alberto Julio
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The gas-phase hydrogenation of maleic anhydride over Ni catalysts supported on SiO2 and SiO2-Al2O3, prepared by incipient wetness impregnation (I) and constant-pH precipitationdeposition (PD), was studied. The samples were characterized by N2 adsorption at -196 ºC, Xray diffraction, temperature-programmed reduction, H2 chemisorption, X-ray photoelectron spectroscopy and transmission electron microscopy. The catalytic tests were carried out at atmospheric pressure, between 170 and 220ºC and using a space-time of 12 g·h·mol-1. From the characterization results, it was determined that the interaction between Ni2+ species and the support strongly depends on the preparation method. The trend found for the Ni2+ -support interaction was Ni/SiO2-PD >Ni/SiO2-Al2O3-PD > Ni/SiO2-I. After reduction in H2 flow, metalNi particles were one order of magnitude smaller in catalysts prepared by precipitationdeposition than those prepared by impregnation. All catalysts were active for the hydrogenation of maleic anhydride (MA) into succinic anhydride (SA) and subsequent hydrogenolysis to GAMMA-butyrolactone (GBL) and propionic acid (PA). Regardless of small amounts of CH4, no other products were detected at the reactor outlet. However, the activity and selectivity to GBL depends on the metal particle size, Ni-support interaction and the presence of Lewis acid site on SiO2-Al2O3 surface. It was found that the small metallic particles obtained by precipitationdeposition method are more active and selective to GBL than the large particles formed using the impregnation method. The highest GBL yield (83%) was reached at 220 ºC with Ni/SiO2- Al2O3-PD, which is attributed to selective hydrogenolysis of SA adsorbed on Lewis acid sites by spillover of hydrogen chemisorbed on neighboring metal nickel nanoparticles.
Fil: Bertone, Matías Ezequiel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Meyer, Camilo Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Regenhardt, Silvina Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Sebastian, Victor. Universidad de Zaragoza; España
Fil: Garetto, Teresita Francisca. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Marchi, Alberto Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Materia
NI CATALYSTS
PRECIPITATION-DEPOSITION
G-BUTYROLACTONE
MALEIC ANHYDRIDE
HYDROGENATION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/113876
Acceder
id CONICETDig_64f3c740640a750966cf14673db34827
oai_identifier_str oai:ri.conicet.gov.ar:11336/113876
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Highly selective conversion of maleic anhydride to gamma-butyrolactone over Ni-supported catalysts prepared by precipitation-deposition methodBertone, Matías EzequielMeyer, Camilo IgnacioRegenhardt, Silvina AndreaSebastian, VictorGaretto, Teresita FranciscaMarchi, Alberto JulioNI CATALYSTSPRECIPITATION-DEPOSITIONG-BUTYROLACTONEMALEIC ANHYDRIDEHYDROGENATIONhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2https://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The gas-phase hydrogenation of maleic anhydride over Ni catalysts supported on SiO2 and SiO2-Al2O3, prepared by incipient wetness impregnation (I) and constant-pH precipitationdeposition (PD), was studied. The samples were characterized by N2 adsorption at -196 ºC, Xray diffraction, temperature-programmed reduction, H2 chemisorption, X-ray photoelectron spectroscopy and transmission electron microscopy. The catalytic tests were carried out at atmospheric pressure, between 170 and 220ºC and using a space-time of 12 g·h·mol-1. From the characterization results, it was determined that the interaction between Ni2+ species and the support strongly depends on the preparation method. The trend found for the Ni2+ -support interaction was Ni/SiO2-PD >Ni/SiO2-Al2O3-PD > Ni/SiO2-I. After reduction in H2 flow, metalNi particles were one order of magnitude smaller in catalysts prepared by precipitationdeposition than those prepared by impregnation. All catalysts were active for the hydrogenation of maleic anhydride (MA) into succinic anhydride (SA) and subsequent hydrogenolysis to GAMMA-butyrolactone (GBL) and propionic acid (PA). Regardless of small amounts of CH4, no other products were detected at the reactor outlet. However, the activity and selectivity to GBL depends on the metal particle size, Ni-support interaction and the presence of Lewis acid site on SiO2-Al2O3 surface. It was found that the small metallic particles obtained by precipitationdeposition method are more active and selective to GBL than the large particles formed using the impregnation method. The highest GBL yield (83%) was reached at 220 ºC with Ni/SiO2- Al2O3-PD, which is attributed to selective hydrogenolysis of SA adsorbed on Lewis acid sites by spillover of hydrogen chemisorbed on neighboring metal nickel nanoparticles.Fil: Bertone, Matías Ezequiel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Meyer, Camilo Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Regenhardt, Silvina Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Sebastian, Victor. Universidad de Zaragoza; EspañaFil: Garetto, Teresita Francisca. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Marchi, Alberto Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaElsevier Science2015-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/113876Bertone, Matías Ezequiel; Meyer, Camilo Ignacio; Regenhardt, Silvina Andrea; Sebastian, Victor; Garetto, Teresita Francisca; et al.; Highly selective conversion of maleic anhydride to gamma-butyrolactone over Ni-supported catalysts prepared by precipitation-deposition method; Elsevier Science; Applied Catalysis A: General; 503; 7-2015; 135-1460926-860XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2015.07.013info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:09:55Zoai:ri.conicet.gov.ar:11336/113876instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:09:56.255CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Highly selective conversion of maleic anhydride to gamma-butyrolactone over Ni-supported catalysts prepared by precipitation-deposition method
title Highly selective conversion of maleic anhydride to gamma-butyrolactone over Ni-supported catalysts prepared by precipitation-deposition method
spellingShingle Highly selective conversion of maleic anhydride to gamma-butyrolactone over Ni-supported catalysts prepared by precipitation-deposition method
Bertone, Matías Ezequiel
NI CATALYSTS
PRECIPITATION-DEPOSITION
G-BUTYROLACTONE
MALEIC ANHYDRIDE
HYDROGENATION
title_short Highly selective conversion of maleic anhydride to gamma-butyrolactone over Ni-supported catalysts prepared by precipitation-deposition method
title_full Highly selective conversion of maleic anhydride to gamma-butyrolactone over Ni-supported catalysts prepared by precipitation-deposition method
title_fullStr Highly selective conversion of maleic anhydride to gamma-butyrolactone over Ni-supported catalysts prepared by precipitation-deposition method
title_full_unstemmed Highly selective conversion of maleic anhydride to gamma-butyrolactone over Ni-supported catalysts prepared by precipitation-deposition method
title_sort Highly selective conversion of maleic anhydride to gamma-butyrolactone over Ni-supported catalysts prepared by precipitation-deposition method
dc.creator.none.fl_str_mv Bertone, Matías Ezequiel
Meyer, Camilo Ignacio
Regenhardt, Silvina Andrea
Sebastian, Victor
Garetto, Teresita Francisca
Marchi, Alberto Julio
author Bertone, Matías Ezequiel
author_facet Bertone, Matías Ezequiel
Meyer, Camilo Ignacio
Regenhardt, Silvina Andrea
Sebastian, Victor
Garetto, Teresita Francisca
Marchi, Alberto Julio
author_role author
author2 Meyer, Camilo Ignacio
Regenhardt, Silvina Andrea
Sebastian, Victor
Garetto, Teresita Francisca
Marchi, Alberto Julio
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv NI CATALYSTS
PRECIPITATION-DEPOSITION
G-BUTYROLACTONE
MALEIC ANHYDRIDE
HYDROGENATION
topic NI CATALYSTS
PRECIPITATION-DEPOSITION
G-BUTYROLACTONE
MALEIC ANHYDRIDE
HYDROGENATION
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The gas-phase hydrogenation of maleic anhydride over Ni catalysts supported on SiO2 and SiO2-Al2O3, prepared by incipient wetness impregnation (I) and constant-pH precipitationdeposition (PD), was studied. The samples were characterized by N2 adsorption at -196 ºC, Xray diffraction, temperature-programmed reduction, H2 chemisorption, X-ray photoelectron spectroscopy and transmission electron microscopy. The catalytic tests were carried out at atmospheric pressure, between 170 and 220ºC and using a space-time of 12 g·h·mol-1. From the characterization results, it was determined that the interaction between Ni2+ species and the support strongly depends on the preparation method. The trend found for the Ni2+ -support interaction was Ni/SiO2-PD >Ni/SiO2-Al2O3-PD > Ni/SiO2-I. After reduction in H2 flow, metalNi particles were one order of magnitude smaller in catalysts prepared by precipitationdeposition than those prepared by impregnation. All catalysts were active for the hydrogenation of maleic anhydride (MA) into succinic anhydride (SA) and subsequent hydrogenolysis to GAMMA-butyrolactone (GBL) and propionic acid (PA). Regardless of small amounts of CH4, no other products were detected at the reactor outlet. However, the activity and selectivity to GBL depends on the metal particle size, Ni-support interaction and the presence of Lewis acid site on SiO2-Al2O3 surface. It was found that the small metallic particles obtained by precipitationdeposition method are more active and selective to GBL than the large particles formed using the impregnation method. The highest GBL yield (83%) was reached at 220 ºC with Ni/SiO2- Al2O3-PD, which is attributed to selective hydrogenolysis of SA adsorbed on Lewis acid sites by spillover of hydrogen chemisorbed on neighboring metal nickel nanoparticles.
Fil: Bertone, Matías Ezequiel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Meyer, Camilo Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Regenhardt, Silvina Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Sebastian, Victor. Universidad de Zaragoza; España
Fil: Garetto, Teresita Francisca. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Marchi, Alberto Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
description The gas-phase hydrogenation of maleic anhydride over Ni catalysts supported on SiO2 and SiO2-Al2O3, prepared by incipient wetness impregnation (I) and constant-pH precipitationdeposition (PD), was studied. The samples were characterized by N2 adsorption at -196 ºC, Xray diffraction, temperature-programmed reduction, H2 chemisorption, X-ray photoelectron spectroscopy and transmission electron microscopy. The catalytic tests were carried out at atmospheric pressure, between 170 and 220ºC and using a space-time of 12 g·h·mol-1. From the characterization results, it was determined that the interaction between Ni2+ species and the support strongly depends on the preparation method. The trend found for the Ni2+ -support interaction was Ni/SiO2-PD >Ni/SiO2-Al2O3-PD > Ni/SiO2-I. After reduction in H2 flow, metalNi particles were one order of magnitude smaller in catalysts prepared by precipitationdeposition than those prepared by impregnation. All catalysts were active for the hydrogenation of maleic anhydride (MA) into succinic anhydride (SA) and subsequent hydrogenolysis to GAMMA-butyrolactone (GBL) and propionic acid (PA). Regardless of small amounts of CH4, no other products were detected at the reactor outlet. However, the activity and selectivity to GBL depends on the metal particle size, Ni-support interaction and the presence of Lewis acid site on SiO2-Al2O3 surface. It was found that the small metallic particles obtained by precipitationdeposition method are more active and selective to GBL than the large particles formed using the impregnation method. The highest GBL yield (83%) was reached at 220 ºC with Ni/SiO2- Al2O3-PD, which is attributed to selective hydrogenolysis of SA adsorbed on Lewis acid sites by spillover of hydrogen chemisorbed on neighboring metal nickel nanoparticles.
publishDate 2015
dc.date.none.fl_str_mv 2015-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/113876
Bertone, Matías Ezequiel; Meyer, Camilo Ignacio; Regenhardt, Silvina Andrea; Sebastian, Victor; Garetto, Teresita Francisca; et al.; Highly selective conversion of maleic anhydride to gamma-butyrolactone over Ni-supported catalysts prepared by precipitation-deposition method; Elsevier Science; Applied Catalysis A: General; 503; 7-2015; 135-146
0926-860X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/113876
identifier_str_mv Bertone, Matías Ezequiel; Meyer, Camilo Ignacio; Regenhardt, Silvina Andrea; Sebastian, Victor; Garetto, Teresita Francisca; et al.; Highly selective conversion of maleic anhydride to gamma-butyrolactone over Ni-supported catalysts prepared by precipitation-deposition method; Elsevier Science; Applied Catalysis A: General; 503; 7-2015; 135-146
0926-860X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2015.07.013
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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