Simultaneous removal of soot and nitrogen oxides from diesel engine exhausts

Autores
Pisarello Milesi, Maria Laura; Milt, Viviana Guadalupe; Peralta, María Ariela; Querini, Carlos Alberto; Miro, Eduardo Ernesto
Año de publicación
2002
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this paper, previously reported findings and new results presented here are discussed with the main objective of establishing the reaction mechanism for soot oxidation on different supports and catalysts formulations. Catalysts containing Co, K and/or Ba supported on MgO, La2O3 and CeO2 have been studied for diesel soot catalytic combustion. Among them, K/La2O3 and K/CeO2 showed the best activity and stability for the combustion of soot with oxygen. A reaction mechanism involving the redox sites and the surface-carbonate species takes place on these catalysts. On the other hand, Co,K/La2O3 and Co,K/CeO2 catalysts display activity for the simultaneous removal of soot and nitric oxide. The soot-catalyst contacting phenomenon was also addressed. A synergic La-K effect was observed in which the mechanical mixtures of soot with K-La2O3 showed higher combustion rates than those observed when K and La were directly deposited on the soot surface. The effect of the addition of Ba was explored with the aim of promoting the interaction of the solid with NO2, thus combining the NOx catalytic trap concept with the soot combustion for filter regeneration. Ba/CeO2 and Ba,K/CeO2 were effective in NOx absorption as shown in the microbalance experiments. However, the formation of stable nitrate species inhibits the soot combustion reaction. © 2002 Elsevier Science B.V. All rights reserved.
Fil: Pisarello Milesi, Maria Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Milt, Viviana Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Peralta, María Ariela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Querini, Carlos Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Miro, Eduardo Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Materia
Co-K-Ba Catalysts
Nitric Oxide Removal
Soot Combustion
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/40100
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/40100
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Simultaneous removal of soot and nitrogen oxides from diesel engine exhaustsPisarello Milesi, Maria LauraMilt, Viviana GuadalupePeralta, María ArielaQuerini, Carlos AlbertoMiro, Eduardo ErnestoCo-K-Ba CatalystsNitric Oxide RemovalSoot Combustionhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2In this paper, previously reported findings and new results presented here are discussed with the main objective of establishing the reaction mechanism for soot oxidation on different supports and catalysts formulations. Catalysts containing Co, K and/or Ba supported on MgO, La2O3 and CeO2 have been studied for diesel soot catalytic combustion. Among them, K/La2O3 and K/CeO2 showed the best activity and stability for the combustion of soot with oxygen. A reaction mechanism involving the redox sites and the surface-carbonate species takes place on these catalysts. On the other hand, Co,K/La2O3 and Co,K/CeO2 catalysts display activity for the simultaneous removal of soot and nitric oxide. The soot-catalyst contacting phenomenon was also addressed. A synergic La-K effect was observed in which the mechanical mixtures of soot with K-La2O3 showed higher combustion rates than those observed when K and La were directly deposited on the soot surface. The effect of the addition of Ba was explored with the aim of promoting the interaction of the solid with NO2, thus combining the NOx catalytic trap concept with the soot combustion for filter regeneration. Ba/CeO2 and Ba,K/CeO2 were effective in NOx absorption as shown in the microbalance experiments. However, the formation of stable nitrate species inhibits the soot combustion reaction. © 2002 Elsevier Science B.V. All rights reserved.Fil: Pisarello Milesi, Maria Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Milt, Viviana Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Peralta, María Ariela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Querini, Carlos Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Miro, Eduardo Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaElsevier Science2002-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/40100Pisarello Milesi, Maria Laura; Milt, Viviana Guadalupe; Peralta, María Ariela; Querini, Carlos Alberto; Miro, Eduardo Ernesto; Simultaneous removal of soot and nitrogen oxides from diesel engine exhausts; Elsevier Science; Catalysis Today; 75; 1-4; 7-2002; 465-4700920-5861CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/S0920-5861(02)00097-4info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0920586102000974info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:36:23Zoai:ri.conicet.gov.ar:11336/40100instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:36:23.294CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Simultaneous removal of soot and nitrogen oxides from diesel engine exhausts
title Simultaneous removal of soot and nitrogen oxides from diesel engine exhausts
spellingShingle Simultaneous removal of soot and nitrogen oxides from diesel engine exhausts
Pisarello Milesi, Maria Laura
Co-K-Ba Catalysts
Nitric Oxide Removal
Soot Combustion
title_short Simultaneous removal of soot and nitrogen oxides from diesel engine exhausts
title_full Simultaneous removal of soot and nitrogen oxides from diesel engine exhausts
title_fullStr Simultaneous removal of soot and nitrogen oxides from diesel engine exhausts
title_full_unstemmed Simultaneous removal of soot and nitrogen oxides from diesel engine exhausts
title_sort Simultaneous removal of soot and nitrogen oxides from diesel engine exhausts
dc.creator.none.fl_str_mv Pisarello Milesi, Maria Laura
Milt, Viviana Guadalupe
Peralta, María Ariela
Querini, Carlos Alberto
Miro, Eduardo Ernesto
author Pisarello Milesi, Maria Laura
author_facet Pisarello Milesi, Maria Laura
Milt, Viviana Guadalupe
Peralta, María Ariela
Querini, Carlos Alberto
Miro, Eduardo Ernesto
author_role author
author2 Milt, Viviana Guadalupe
Peralta, María Ariela
Querini, Carlos Alberto
Miro, Eduardo Ernesto
author2_role author
author
author
author
dc.subject.none.fl_str_mv Co-K-Ba Catalysts
Nitric Oxide Removal
Soot Combustion
topic Co-K-Ba Catalysts
Nitric Oxide Removal
Soot Combustion
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv In this paper, previously reported findings and new results presented here are discussed with the main objective of establishing the reaction mechanism for soot oxidation on different supports and catalysts formulations. Catalysts containing Co, K and/or Ba supported on MgO, La2O3 and CeO2 have been studied for diesel soot catalytic combustion. Among them, K/La2O3 and K/CeO2 showed the best activity and stability for the combustion of soot with oxygen. A reaction mechanism involving the redox sites and the surface-carbonate species takes place on these catalysts. On the other hand, Co,K/La2O3 and Co,K/CeO2 catalysts display activity for the simultaneous removal of soot and nitric oxide. The soot-catalyst contacting phenomenon was also addressed. A synergic La-K effect was observed in which the mechanical mixtures of soot with K-La2O3 showed higher combustion rates than those observed when K and La were directly deposited on the soot surface. The effect of the addition of Ba was explored with the aim of promoting the interaction of the solid with NO2, thus combining the NOx catalytic trap concept with the soot combustion for filter regeneration. Ba/CeO2 and Ba,K/CeO2 were effective in NOx absorption as shown in the microbalance experiments. However, the formation of stable nitrate species inhibits the soot combustion reaction. © 2002 Elsevier Science B.V. All rights reserved.
Fil: Pisarello Milesi, Maria Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Milt, Viviana Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Peralta, María Ariela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Querini, Carlos Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Miro, Eduardo Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
description In this paper, previously reported findings and new results presented here are discussed with the main objective of establishing the reaction mechanism for soot oxidation on different supports and catalysts formulations. Catalysts containing Co, K and/or Ba supported on MgO, La2O3 and CeO2 have been studied for diesel soot catalytic combustion. Among them, K/La2O3 and K/CeO2 showed the best activity and stability for the combustion of soot with oxygen. A reaction mechanism involving the redox sites and the surface-carbonate species takes place on these catalysts. On the other hand, Co,K/La2O3 and Co,K/CeO2 catalysts display activity for the simultaneous removal of soot and nitric oxide. The soot-catalyst contacting phenomenon was also addressed. A synergic La-K effect was observed in which the mechanical mixtures of soot with K-La2O3 showed higher combustion rates than those observed when K and La were directly deposited on the soot surface. The effect of the addition of Ba was explored with the aim of promoting the interaction of the solid with NO2, thus combining the NOx catalytic trap concept with the soot combustion for filter regeneration. Ba/CeO2 and Ba,K/CeO2 were effective in NOx absorption as shown in the microbalance experiments. However, the formation of stable nitrate species inhibits the soot combustion reaction. © 2002 Elsevier Science B.V. All rights reserved.
publishDate 2002
dc.date.none.fl_str_mv 2002-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/40100
Pisarello Milesi, Maria Laura; Milt, Viviana Guadalupe; Peralta, María Ariela; Querini, Carlos Alberto; Miro, Eduardo Ernesto; Simultaneous removal of soot and nitrogen oxides from diesel engine exhausts; Elsevier Science; Catalysis Today; 75; 1-4; 7-2002; 465-470
0920-5861
CONICET Digital
CONICET
url http://hdl.handle.net/11336/40100
identifier_str_mv Pisarello Milesi, Maria Laura; Milt, Viviana Guadalupe; Peralta, María Ariela; Querini, Carlos Alberto; Miro, Eduardo Ernesto; Simultaneous removal of soot and nitrogen oxides from diesel engine exhausts; Elsevier Science; Catalysis Today; 75; 1-4; 7-2002; 465-470
0920-5861
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/S0920-5861(02)00097-4
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0920586102000974
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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