Fractional statistical theory of finite multilayer adsorption

Autores
Takara, Eduardo Andres; Quiroga, Evelina; Matoz Fernandez, Daniel Alejandro; Ochoa, Nelio Ariel; Ramirez Pastor, Antonio Jose
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In the present paper, finite multilayer adsorption is described as a fractional statistics problem, based on Haldane's statistics. In this scheme, the Helmholtz free energy and its derivatives are written in terms of a parameter g, which relates to the configuration of the molecules in the adsorbed state. For values of g ranging between 0 and 1 the formalism is used to model experimental data of bovine serum albumin (BSA) adsorbed onto an ion exchange resin for different values of pH and temperature. Excellent agreement between theory and experiments was found.
Fil: Takara, Eduardo Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; Argentina
Fil: Quiroga, Evelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; Argentina
Fil: Matoz Fernandez, Daniel Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; Argentina
Fil: Ochoa, Nelio Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; Argentina
Fil: Ramirez Pastor, Antonio Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; Argentina
Materia
Adsorption Isotherms
Bsa Protein Adsorption
Equilibrium Thermodynamics And Statistical Mechanics
Multilayer Adsorption
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/60469
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/60469
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Fractional statistical theory of finite multilayer adsorptionTakara, Eduardo AndresQuiroga, EvelinaMatoz Fernandez, Daniel AlejandroOchoa, Nelio ArielRamirez Pastor, Antonio JoseAdsorption IsothermsBsa Protein AdsorptionEquilibrium Thermodynamics And Statistical MechanicsMultilayer Adsorptionhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1In the present paper, finite multilayer adsorption is described as a fractional statistics problem, based on Haldane's statistics. In this scheme, the Helmholtz free energy and its derivatives are written in terms of a parameter g, which relates to the configuration of the molecules in the adsorbed state. For values of g ranging between 0 and 1 the formalism is used to model experimental data of bovine serum albumin (BSA) adsorbed onto an ion exchange resin for different values of pH and temperature. Excellent agreement between theory and experiments was found.Fil: Takara, Eduardo Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; ArgentinaFil: Quiroga, Evelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; ArgentinaFil: Matoz Fernandez, Daniel Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; ArgentinaFil: Ochoa, Nelio Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; ArgentinaFil: Ramirez Pastor, Antonio Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; ArgentinaElsevier Science2016-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/60469Takara, Eduardo Andres; Quiroga, Evelina; Matoz Fernandez, Daniel Alejandro; Ochoa, Nelio Ariel; Ramirez Pastor, Antonio Jose; Fractional statistical theory of finite multilayer adsorption; Elsevier Science; Applied Surface Science; 360; 1-2016; 14-190169-4332CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.apsusc.2015.10.211info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0169433215026410info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:44:34Zoai:ri.conicet.gov.ar:11336/60469instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:44:34.956CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Fractional statistical theory of finite multilayer adsorption
title Fractional statistical theory of finite multilayer adsorption
spellingShingle Fractional statistical theory of finite multilayer adsorption
Takara, Eduardo Andres
Adsorption Isotherms
Bsa Protein Adsorption
Equilibrium Thermodynamics And Statistical Mechanics
Multilayer Adsorption
title_short Fractional statistical theory of finite multilayer adsorption
title_full Fractional statistical theory of finite multilayer adsorption
title_fullStr Fractional statistical theory of finite multilayer adsorption
title_full_unstemmed Fractional statistical theory of finite multilayer adsorption
title_sort Fractional statistical theory of finite multilayer adsorption
dc.creator.none.fl_str_mv Takara, Eduardo Andres
Quiroga, Evelina
Matoz Fernandez, Daniel Alejandro
Ochoa, Nelio Ariel
Ramirez Pastor, Antonio Jose
author Takara, Eduardo Andres
author_facet Takara, Eduardo Andres
Quiroga, Evelina
Matoz Fernandez, Daniel Alejandro
Ochoa, Nelio Ariel
Ramirez Pastor, Antonio Jose
author_role author
author2 Quiroga, Evelina
Matoz Fernandez, Daniel Alejandro
Ochoa, Nelio Ariel
Ramirez Pastor, Antonio Jose
author2_role author
author
author
author
dc.subject.none.fl_str_mv Adsorption Isotherms
Bsa Protein Adsorption
Equilibrium Thermodynamics And Statistical Mechanics
Multilayer Adsorption
topic Adsorption Isotherms
Bsa Protein Adsorption
Equilibrium Thermodynamics And Statistical Mechanics
Multilayer Adsorption
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv In the present paper, finite multilayer adsorption is described as a fractional statistics problem, based on Haldane's statistics. In this scheme, the Helmholtz free energy and its derivatives are written in terms of a parameter g, which relates to the configuration of the molecules in the adsorbed state. For values of g ranging between 0 and 1 the formalism is used to model experimental data of bovine serum albumin (BSA) adsorbed onto an ion exchange resin for different values of pH and temperature. Excellent agreement between theory and experiments was found.
Fil: Takara, Eduardo Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; Argentina
Fil: Quiroga, Evelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; Argentina
Fil: Matoz Fernandez, Daniel Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; Argentina
Fil: Ochoa, Nelio Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; Argentina
Fil: Ramirez Pastor, Antonio Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; Argentina
description In the present paper, finite multilayer adsorption is described as a fractional statistics problem, based on Haldane's statistics. In this scheme, the Helmholtz free energy and its derivatives are written in terms of a parameter g, which relates to the configuration of the molecules in the adsorbed state. For values of g ranging between 0 and 1 the formalism is used to model experimental data of bovine serum albumin (BSA) adsorbed onto an ion exchange resin for different values of pH and temperature. Excellent agreement between theory and experiments was found.
publishDate 2016
dc.date.none.fl_str_mv 2016-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/60469
Takara, Eduardo Andres; Quiroga, Evelina; Matoz Fernandez, Daniel Alejandro; Ochoa, Nelio Ariel; Ramirez Pastor, Antonio Jose; Fractional statistical theory of finite multilayer adsorption; Elsevier Science; Applied Surface Science; 360; 1-2016; 14-19
0169-4332
CONICET Digital
CONICET
url http://hdl.handle.net/11336/60469
identifier_str_mv Takara, Eduardo Andres; Quiroga, Evelina; Matoz Fernandez, Daniel Alejandro; Ochoa, Nelio Ariel; Ramirez Pastor, Antonio Jose; Fractional statistical theory of finite multilayer adsorption; Elsevier Science; Applied Surface Science; 360; 1-2016; 14-19
0169-4332
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apsusc.2015.10.211
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0169433215026410
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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