Optimization of Acid Hydrolysis Process for the Preparation Cellulose Nanofibrils

Autores
Bracone, Melina Ethel; Ludueña, Leandro Nicolás; Alvarez, Vera Alejandra
Año de publicación
2019
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Cellulose nanofibrils can be obtained from microcrystalline cellulose by acid hydrolysis processes. Under optimum hydrolysis conditions is possible to obtain cellulose nanofibers with high surface / volume ratio, high aspect ratio (length to diameter), high crystallinity and improved thermal stability. All these parameters then determine their effectiveness as reinforcement in a polymer matrix. In this work, cellulose nanofibrils were obtained from commercial microcellulose supplied by Aldrich. The acid hydrolysis synthesis was optimized studying the effect of reaction time and temperature and acid solution concentration. The optimized parameters were selected so as to obtain fibers with high crystallinity, high aspect ratio with diameter in nanoscale and high thermal stability. The morphology and size (length and diameter) of the fibers was analyzed by Field Emission Scanning Electron Microscopy (FESEM), the chemical structure by Fourier Transform Infrared Spectroscopy (FTIR), thermal stability by Thermogravimetric Analysis (TGA) and crystallinity by X-ray Diffraction (XRD).
Fil: Bracone, Melina Ethel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Ludueña, Leandro Nicolás. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Alvarez, Vera Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Materia
CELLULOSE
NANOFIBRILS
OPTIMIZATION
ACID-HYDROLYSIS
CHARACTERIZATION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/119233
Acceder
id CONICETDig_75bdf701741ff31cb61d74945490fde9
oai_identifier_str oai:ri.conicet.gov.ar:11336/119233
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Optimization of Acid Hydrolysis Process for the Preparation Cellulose NanofibrilsBracone, Melina EthelLudueña, Leandro NicolásAlvarez, Vera AlejandraCELLULOSENANOFIBRILSOPTIMIZATIONACID-HYDROLYSISCHARACTERIZATIONhttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2Cellulose nanofibrils can be obtained from microcrystalline cellulose by acid hydrolysis processes. Under optimum hydrolysis conditions is possible to obtain cellulose nanofibers with high surface / volume ratio, high aspect ratio (length to diameter), high crystallinity and improved thermal stability. All these parameters then determine their effectiveness as reinforcement in a polymer matrix. In this work, cellulose nanofibrils were obtained from commercial microcellulose supplied by Aldrich. The acid hydrolysis synthesis was optimized studying the effect of reaction time and temperature and acid solution concentration. The optimized parameters were selected so as to obtain fibers with high crystallinity, high aspect ratio with diameter in nanoscale and high thermal stability. The morphology and size (length and diameter) of the fibers was analyzed by Field Emission Scanning Electron Microscopy (FESEM), the chemical structure by Fourier Transform Infrared Spectroscopy (FTIR), thermal stability by Thermogravimetric Analysis (TGA) and crystallinity by X-ray Diffraction (XRD).Fil: Bracone, Melina Ethel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Ludueña, Leandro Nicolás. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Alvarez, Vera Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaVBRI Press2019-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/119233Bracone, Melina Ethel; Ludueña, Leandro Nicolás; Alvarez, Vera Alejandra; Optimization of Acid Hydrolysis Process for the Preparation Cellulose Nanofibrils; VBRI Press; Advanced Materials Letters; 10; 7; 2-2019; 499-5070976-397XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.5185/amlett.2019.2182info:eu-repo/semantics/altIdentifier/url/https://www.vbripress.com/aml/articles/details/1375info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:35:48Zoai:ri.conicet.gov.ar:11336/119233instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:35:48.284CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Optimization of Acid Hydrolysis Process for the Preparation Cellulose Nanofibrils
title Optimization of Acid Hydrolysis Process for the Preparation Cellulose Nanofibrils
spellingShingle Optimization of Acid Hydrolysis Process for the Preparation Cellulose Nanofibrils
Bracone, Melina Ethel
CELLULOSE
NANOFIBRILS
OPTIMIZATION
ACID-HYDROLYSIS
CHARACTERIZATION
title_short Optimization of Acid Hydrolysis Process for the Preparation Cellulose Nanofibrils
title_full Optimization of Acid Hydrolysis Process for the Preparation Cellulose Nanofibrils
title_fullStr Optimization of Acid Hydrolysis Process for the Preparation Cellulose Nanofibrils
title_full_unstemmed Optimization of Acid Hydrolysis Process for the Preparation Cellulose Nanofibrils
title_sort Optimization of Acid Hydrolysis Process for the Preparation Cellulose Nanofibrils
dc.creator.none.fl_str_mv Bracone, Melina Ethel
Ludueña, Leandro Nicolás
Alvarez, Vera Alejandra
author Bracone, Melina Ethel
author_facet Bracone, Melina Ethel
Ludueña, Leandro Nicolás
Alvarez, Vera Alejandra
author_role author
author2 Ludueña, Leandro Nicolás
Alvarez, Vera Alejandra
author2_role author
author
dc.subject.none.fl_str_mv CELLULOSE
NANOFIBRILS
OPTIMIZATION
ACID-HYDROLYSIS
CHARACTERIZATION
topic CELLULOSE
NANOFIBRILS
OPTIMIZATION
ACID-HYDROLYSIS
CHARACTERIZATION
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Cellulose nanofibrils can be obtained from microcrystalline cellulose by acid hydrolysis processes. Under optimum hydrolysis conditions is possible to obtain cellulose nanofibers with high surface / volume ratio, high aspect ratio (length to diameter), high crystallinity and improved thermal stability. All these parameters then determine their effectiveness as reinforcement in a polymer matrix. In this work, cellulose nanofibrils were obtained from commercial microcellulose supplied by Aldrich. The acid hydrolysis synthesis was optimized studying the effect of reaction time and temperature and acid solution concentration. The optimized parameters were selected so as to obtain fibers with high crystallinity, high aspect ratio with diameter in nanoscale and high thermal stability. The morphology and size (length and diameter) of the fibers was analyzed by Field Emission Scanning Electron Microscopy (FESEM), the chemical structure by Fourier Transform Infrared Spectroscopy (FTIR), thermal stability by Thermogravimetric Analysis (TGA) and crystallinity by X-ray Diffraction (XRD).
Fil: Bracone, Melina Ethel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Ludueña, Leandro Nicolás. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Alvarez, Vera Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
description Cellulose nanofibrils can be obtained from microcrystalline cellulose by acid hydrolysis processes. Under optimum hydrolysis conditions is possible to obtain cellulose nanofibers with high surface / volume ratio, high aspect ratio (length to diameter), high crystallinity and improved thermal stability. All these parameters then determine their effectiveness as reinforcement in a polymer matrix. In this work, cellulose nanofibrils were obtained from commercial microcellulose supplied by Aldrich. The acid hydrolysis synthesis was optimized studying the effect of reaction time and temperature and acid solution concentration. The optimized parameters were selected so as to obtain fibers with high crystallinity, high aspect ratio with diameter in nanoscale and high thermal stability. The morphology and size (length and diameter) of the fibers was analyzed by Field Emission Scanning Electron Microscopy (FESEM), the chemical structure by Fourier Transform Infrared Spectroscopy (FTIR), thermal stability by Thermogravimetric Analysis (TGA) and crystallinity by X-ray Diffraction (XRD).
publishDate 2019
dc.date.none.fl_str_mv 2019-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/119233
Bracone, Melina Ethel; Ludueña, Leandro Nicolás; Alvarez, Vera Alejandra; Optimization of Acid Hydrolysis Process for the Preparation Cellulose Nanofibrils; VBRI Press; Advanced Materials Letters; 10; 7; 2-2019; 499-507
0976-397X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/119233
identifier_str_mv Bracone, Melina Ethel; Ludueña, Leandro Nicolás; Alvarez, Vera Alejandra; Optimization of Acid Hydrolysis Process for the Preparation Cellulose Nanofibrils; VBRI Press; Advanced Materials Letters; 10; 7; 2-2019; 499-507
0976-397X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.5185/amlett.2019.2182
info:eu-repo/semantics/altIdentifier/url/https://www.vbripress.com/aml/articles/details/1375
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv VBRI Press
publisher.none.fl_str_mv VBRI Press
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613118254120960
score 13.069144

Publicaciones similares