Sulfur Resistance of Pt-W catalyst

Autores
Betti, Carolina Paola; Badano, Juan Manuel; Rivas, Ivana Lorena; Mazzieri, Vanina Alejandra; Maccarrone, María Juliana; Coloma Pascual, Fernando; Vera, Carlos Roman; Quiroga, Monica Esther
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The sulfur resistance of low-loaded monometallic Pt catalysts and bimetallic Pt-W catalysts during the partial selective hydrogenation of styrene, a model compound of PYGAS streams, was studied. The effect of metal impregnation sequence on the activity and selectivity was also evaluated. Catalysts were characterized by ICP, TPR, XRD and XPS techniques. Catalytic tests with sulfur-free and sulfur-doped feeds were performed.All catalysts showed high selectivities (> 98%) to ethylbenzene. Activity differences between the catalysts were mainly attributed to electronic effects due to the presence of different electron-rich species of Pt0, and electron-deficient species of Ptä+. Pt0 promotes the cleavage of H2 while Ptä+ the adsorption of styrene. The catalyst successively impregnated with W and Pt (WPt/Al) was more active and sulfur resistant than the catalyst prepared with an inverse impregnation order (PtW/Al). The higher poison resistance of WPt/Al was attributed to the presence of chloride that inhibits the adsorption of thiophene because of steric and electronic effects. On the other hand, the lower concentration of chloride and a high concentration of Pt0 electron-rich sites (with low BE values) could contribute to the poisoning, as these species would act as electron donor sites, providing available electrons to be bond with the S atom of thiophene. Both effects would promote a strong adsorption of thiophene and thus an enhanced blocking of the catalyst active sites.
Fil: Betti, Carolina Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Badano, Juan Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Rivas, Ivana Lorena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Mazzieri, Vanina Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Maccarrone, María Juliana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Coloma Pascual, Fernando. Universidad de Alicante. Facultad de Ciencias; España
Fil: Vera, Carlos Roman. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Quiroga, Monica Esther. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Materia
BIMETALLIC CATALYSTS
SELECTIVE HYDROGENATION
PLATINUM
SULFUR RESISTANCE
TUNGSTEN
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/101884
Acceder
id CONICETDig_7398803703cbae573a7fb7a8bf9f011d
oai_identifier_str oai:ri.conicet.gov.ar:11336/101884
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Sulfur Resistance of Pt-W catalystBetti, Carolina PaolaBadano, Juan ManuelRivas, Ivana LorenaMazzieri, Vanina AlejandraMaccarrone, María JulianaColoma Pascual, FernandoVera, Carlos RomanQuiroga, Monica EstherBIMETALLIC CATALYSTSSELECTIVE HYDROGENATIONPLATINUMSULFUR RESISTANCETUNGSTENhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The sulfur resistance of low-loaded monometallic Pt catalysts and bimetallic Pt-W catalysts during the partial selective hydrogenation of styrene, a model compound of PYGAS streams, was studied. The effect of metal impregnation sequence on the activity and selectivity was also evaluated. Catalysts were characterized by ICP, TPR, XRD and XPS techniques. Catalytic tests with sulfur-free and sulfur-doped feeds were performed.All catalysts showed high selectivities (> 98%) to ethylbenzene. Activity differences between the catalysts were mainly attributed to electronic effects due to the presence of different electron-rich species of Pt0, and electron-deficient species of Ptä+. Pt0 promotes the cleavage of H2 while Ptä+ the adsorption of styrene. The catalyst successively impregnated with W and Pt (WPt/Al) was more active and sulfur resistant than the catalyst prepared with an inverse impregnation order (PtW/Al). The higher poison resistance of WPt/Al was attributed to the presence of chloride that inhibits the adsorption of thiophene because of steric and electronic effects. On the other hand, the lower concentration of chloride and a high concentration of Pt0 electron-rich sites (with low BE values) could contribute to the poisoning, as these species would act as electron donor sites, providing available electrons to be bond with the S atom of thiophene. Both effects would promote a strong adsorption of thiophene and thus an enhanced blocking of the catalyst active sites.Fil: Betti, Carolina Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Badano, Juan Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Rivas, Ivana Lorena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Mazzieri, Vanina Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Maccarrone, María Juliana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Coloma Pascual, Fernando. Universidad de Alicante. Facultad de Ciencias; EspañaFil: Vera, Carlos Roman. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Quiroga, Monica Esther. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaHindawi Publishing Corporation2013-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/101884Betti, Carolina Paola; Badano, Juan Manuel; Rivas, Ivana Lorena; Mazzieri, Vanina Alejandra; Maccarrone, María Juliana; et al.; Sulfur Resistance of Pt-W catalyst; Hindawi Publishing Corporation; Journal of Chemistry; 2013; 1-2013; 1-82090-9063CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.hindawi.com/journals/chem/2013/502014/info:eu-repo/semantics/altIdentifier/doi/10.1155/2013/502014info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:44:48Zoai:ri.conicet.gov.ar:11336/101884instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:44:49.201CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Sulfur Resistance of Pt-W catalyst
title Sulfur Resistance of Pt-W catalyst
spellingShingle Sulfur Resistance of Pt-W catalyst
Betti, Carolina Paola
BIMETALLIC CATALYSTS
SELECTIVE HYDROGENATION
PLATINUM
SULFUR RESISTANCE
TUNGSTEN
title_short Sulfur Resistance of Pt-W catalyst
title_full Sulfur Resistance of Pt-W catalyst
title_fullStr Sulfur Resistance of Pt-W catalyst
title_full_unstemmed Sulfur Resistance of Pt-W catalyst
title_sort Sulfur Resistance of Pt-W catalyst
dc.creator.none.fl_str_mv Betti, Carolina Paola
Badano, Juan Manuel
Rivas, Ivana Lorena
Mazzieri, Vanina Alejandra
Maccarrone, María Juliana
Coloma Pascual, Fernando
Vera, Carlos Roman
Quiroga, Monica Esther
author Betti, Carolina Paola
author_facet Betti, Carolina Paola
Badano, Juan Manuel
Rivas, Ivana Lorena
Mazzieri, Vanina Alejandra
Maccarrone, María Juliana
Coloma Pascual, Fernando
Vera, Carlos Roman
Quiroga, Monica Esther
author_role author
author2 Badano, Juan Manuel
Rivas, Ivana Lorena
Mazzieri, Vanina Alejandra
Maccarrone, María Juliana
Coloma Pascual, Fernando
Vera, Carlos Roman
Quiroga, Monica Esther
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv BIMETALLIC CATALYSTS
SELECTIVE HYDROGENATION
PLATINUM
SULFUR RESISTANCE
TUNGSTEN
topic BIMETALLIC CATALYSTS
SELECTIVE HYDROGENATION
PLATINUM
SULFUR RESISTANCE
TUNGSTEN
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The sulfur resistance of low-loaded monometallic Pt catalysts and bimetallic Pt-W catalysts during the partial selective hydrogenation of styrene, a model compound of PYGAS streams, was studied. The effect of metal impregnation sequence on the activity and selectivity was also evaluated. Catalysts were characterized by ICP, TPR, XRD and XPS techniques. Catalytic tests with sulfur-free and sulfur-doped feeds were performed.All catalysts showed high selectivities (> 98%) to ethylbenzene. Activity differences between the catalysts were mainly attributed to electronic effects due to the presence of different electron-rich species of Pt0, and electron-deficient species of Ptä+. Pt0 promotes the cleavage of H2 while Ptä+ the adsorption of styrene. The catalyst successively impregnated with W and Pt (WPt/Al) was more active and sulfur resistant than the catalyst prepared with an inverse impregnation order (PtW/Al). The higher poison resistance of WPt/Al was attributed to the presence of chloride that inhibits the adsorption of thiophene because of steric and electronic effects. On the other hand, the lower concentration of chloride and a high concentration of Pt0 electron-rich sites (with low BE values) could contribute to the poisoning, as these species would act as electron donor sites, providing available electrons to be bond with the S atom of thiophene. Both effects would promote a strong adsorption of thiophene and thus an enhanced blocking of the catalyst active sites.
Fil: Betti, Carolina Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Badano, Juan Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Rivas, Ivana Lorena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Mazzieri, Vanina Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Maccarrone, María Juliana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Coloma Pascual, Fernando. Universidad de Alicante. Facultad de Ciencias; España
Fil: Vera, Carlos Roman. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Quiroga, Monica Esther. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
description The sulfur resistance of low-loaded monometallic Pt catalysts and bimetallic Pt-W catalysts during the partial selective hydrogenation of styrene, a model compound of PYGAS streams, was studied. The effect of metal impregnation sequence on the activity and selectivity was also evaluated. Catalysts were characterized by ICP, TPR, XRD and XPS techniques. Catalytic tests with sulfur-free and sulfur-doped feeds were performed.All catalysts showed high selectivities (> 98%) to ethylbenzene. Activity differences between the catalysts were mainly attributed to electronic effects due to the presence of different electron-rich species of Pt0, and electron-deficient species of Ptä+. Pt0 promotes the cleavage of H2 while Ptä+ the adsorption of styrene. The catalyst successively impregnated with W and Pt (WPt/Al) was more active and sulfur resistant than the catalyst prepared with an inverse impregnation order (PtW/Al). The higher poison resistance of WPt/Al was attributed to the presence of chloride that inhibits the adsorption of thiophene because of steric and electronic effects. On the other hand, the lower concentration of chloride and a high concentration of Pt0 electron-rich sites (with low BE values) could contribute to the poisoning, as these species would act as electron donor sites, providing available electrons to be bond with the S atom of thiophene. Both effects would promote a strong adsorption of thiophene and thus an enhanced blocking of the catalyst active sites.
publishDate 2013
dc.date.none.fl_str_mv 2013-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/101884
Betti, Carolina Paola; Badano, Juan Manuel; Rivas, Ivana Lorena; Mazzieri, Vanina Alejandra; Maccarrone, María Juliana; et al.; Sulfur Resistance of Pt-W catalyst; Hindawi Publishing Corporation; Journal of Chemistry; 2013; 1-2013; 1-8
2090-9063
CONICET Digital
CONICET
url http://hdl.handle.net/11336/101884
identifier_str_mv Betti, Carolina Paola; Badano, Juan Manuel; Rivas, Ivana Lorena; Mazzieri, Vanina Alejandra; Maccarrone, María Juliana; et al.; Sulfur Resistance of Pt-W catalyst; Hindawi Publishing Corporation; Journal of Chemistry; 2013; 1-2013; 1-8
2090-9063
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.hindawi.com/journals/chem/2013/502014/
info:eu-repo/semantics/altIdentifier/doi/10.1155/2013/502014
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Hindawi Publishing Corporation
publisher.none.fl_str_mv Hindawi Publishing Corporation
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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