Kinetic study of the partial hydrogenation of 1-heptyne on tungsten oxide supported on alumina

Autores
Maccarrone, María Juliana; Torres, Gerardo; Lederhos, Cecilia Rosa; Badano, Juan Manuel; Vera, Carlos Roman; Quiroga, Monica Esther; Yori, Juan Carlos
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
BACKGROUND: Partial hydrogenation of alkynes have industrial and academic relevance on a large scale; industries such as petrochemical, pharmacology and agrochemical use these compounds as raw material. Typical commercial catalysts contains palladium. Finding an economic, active and selective catalyst for the production of alkenes via partial hydrogenation of alkynes is thus an important challenge. On the other hand, the literature on kinetic studies of partial hydrogenation of heavy alkynes is scarce. So the main objectives of this work were to prepare a cheaper catalyst based on low W loading, and study the kinetic of the partial hydrogenation of 1-heptyne. A pseudo-homogeneous and six heterogeneous kinetic models were analyzed. The catalyst was characterized by ICP, XPS, DRX, TPR and hydrogen chemisorption techniques. RESULTS: The characterization results indicate that only WO x species are present on the alumina surface. The WO x/Al 2O 3 catalyst was active and selective for producing 1-heptene even at low reaction temperatures, the partial hydrogenation of 1-heptyne proceeds via two irreversible reactions in parallel. CONCLUSION: The best fit of the experimental data was achieved with a heterogeneous Langmuir-Hinshelwood-Hougen-Watson model in which the rate controlling step is the dissociative adsorption of hydrogen. The activation energy was estimated as E H2 = 34.8 kJ mol -1.
Fil: Maccarrone, María Juliana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Torres, Gerardo. Universidad Nacional del Litoral. Facultad de Ingeniería Química; Argentina
Fil: Lederhos, Cecilia Rosa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Badano, Juan Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Vera, Carlos Roman. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Quiroga, Monica Esther. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Yori, Juan Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Materia
Alkyne
Kinetic Study
Selective Hydrogenation
Tungsten Catalysts
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/52813
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/52813
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Kinetic study of the partial hydrogenation of 1-heptyne on tungsten oxide supported on aluminaMaccarrone, María JulianaTorres, GerardoLederhos, Cecilia RosaBadano, Juan ManuelVera, Carlos RomanQuiroga, Monica EstherYori, Juan CarlosAlkyneKinetic StudySelective HydrogenationTungsten Catalystshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1BACKGROUND: Partial hydrogenation of alkynes have industrial and academic relevance on a large scale; industries such as petrochemical, pharmacology and agrochemical use these compounds as raw material. Typical commercial catalysts contains palladium. Finding an economic, active and selective catalyst for the production of alkenes via partial hydrogenation of alkynes is thus an important challenge. On the other hand, the literature on kinetic studies of partial hydrogenation of heavy alkynes is scarce. So the main objectives of this work were to prepare a cheaper catalyst based on low W loading, and study the kinetic of the partial hydrogenation of 1-heptyne. A pseudo-homogeneous and six heterogeneous kinetic models were analyzed. The catalyst was characterized by ICP, XPS, DRX, TPR and hydrogen chemisorption techniques. RESULTS: The characterization results indicate that only WO x species are present on the alumina surface. The WO x/Al 2O 3 catalyst was active and selective for producing 1-heptene even at low reaction temperatures, the partial hydrogenation of 1-heptyne proceeds via two irreversible reactions in parallel. CONCLUSION: The best fit of the experimental data was achieved with a heterogeneous Langmuir-Hinshelwood-Hougen-Watson model in which the rate controlling step is the dissociative adsorption of hydrogen. The activation energy was estimated as E H2 = 34.8 kJ mol -1.Fil: Maccarrone, María Juliana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Torres, Gerardo. Universidad Nacional del Litoral. Facultad de Ingeniería Química; ArgentinaFil: Lederhos, Cecilia Rosa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Badano, Juan Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Vera, Carlos Roman. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Quiroga, Monica Esther. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Yori, Juan Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaJohn Wiley & Sons Ltd2012-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/52813Maccarrone, María Juliana; Torres, Gerardo; Lederhos, Cecilia Rosa; Badano, Juan Manuel; Vera, Carlos Roman; et al.; Kinetic study of the partial hydrogenation of 1-heptyne on tungsten oxide supported on alumina; John Wiley & Sons Ltd; Journal of Chemical Technology and Biotechnology; 87; 11; 3-2012; 1521-15280268-2575CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/jctb.3778info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/jctb.3778info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:11:05Zoai:ri.conicet.gov.ar:11336/52813instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:11:05.439CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Kinetic study of the partial hydrogenation of 1-heptyne on tungsten oxide supported on alumina
title Kinetic study of the partial hydrogenation of 1-heptyne on tungsten oxide supported on alumina
spellingShingle Kinetic study of the partial hydrogenation of 1-heptyne on tungsten oxide supported on alumina
Maccarrone, María Juliana
Alkyne
Kinetic Study
Selective Hydrogenation
Tungsten Catalysts
title_short Kinetic study of the partial hydrogenation of 1-heptyne on tungsten oxide supported on alumina
title_full Kinetic study of the partial hydrogenation of 1-heptyne on tungsten oxide supported on alumina
title_fullStr Kinetic study of the partial hydrogenation of 1-heptyne on tungsten oxide supported on alumina
title_full_unstemmed Kinetic study of the partial hydrogenation of 1-heptyne on tungsten oxide supported on alumina
title_sort Kinetic study of the partial hydrogenation of 1-heptyne on tungsten oxide supported on alumina
dc.creator.none.fl_str_mv Maccarrone, María Juliana
Torres, Gerardo
Lederhos, Cecilia Rosa
Badano, Juan Manuel
Vera, Carlos Roman
Quiroga, Monica Esther
Yori, Juan Carlos
author Maccarrone, María Juliana
author_facet Maccarrone, María Juliana
Torres, Gerardo
Lederhos, Cecilia Rosa
Badano, Juan Manuel
Vera, Carlos Roman
Quiroga, Monica Esther
Yori, Juan Carlos
author_role author
author2 Torres, Gerardo
Lederhos, Cecilia Rosa
Badano, Juan Manuel
Vera, Carlos Roman
Quiroga, Monica Esther
Yori, Juan Carlos
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Alkyne
Kinetic Study
Selective Hydrogenation
Tungsten Catalysts
topic Alkyne
Kinetic Study
Selective Hydrogenation
Tungsten Catalysts
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv BACKGROUND: Partial hydrogenation of alkynes have industrial and academic relevance on a large scale; industries such as petrochemical, pharmacology and agrochemical use these compounds as raw material. Typical commercial catalysts contains palladium. Finding an economic, active and selective catalyst for the production of alkenes via partial hydrogenation of alkynes is thus an important challenge. On the other hand, the literature on kinetic studies of partial hydrogenation of heavy alkynes is scarce. So the main objectives of this work were to prepare a cheaper catalyst based on low W loading, and study the kinetic of the partial hydrogenation of 1-heptyne. A pseudo-homogeneous and six heterogeneous kinetic models were analyzed. The catalyst was characterized by ICP, XPS, DRX, TPR and hydrogen chemisorption techniques. RESULTS: The characterization results indicate that only WO x species are present on the alumina surface. The WO x/Al 2O 3 catalyst was active and selective for producing 1-heptene even at low reaction temperatures, the partial hydrogenation of 1-heptyne proceeds via two irreversible reactions in parallel. CONCLUSION: The best fit of the experimental data was achieved with a heterogeneous Langmuir-Hinshelwood-Hougen-Watson model in which the rate controlling step is the dissociative adsorption of hydrogen. The activation energy was estimated as E H2 = 34.8 kJ mol -1.
Fil: Maccarrone, María Juliana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Torres, Gerardo. Universidad Nacional del Litoral. Facultad de Ingeniería Química; Argentina
Fil: Lederhos, Cecilia Rosa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Badano, Juan Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Vera, Carlos Roman. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Quiroga, Monica Esther. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Yori, Juan Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
description BACKGROUND: Partial hydrogenation of alkynes have industrial and academic relevance on a large scale; industries such as petrochemical, pharmacology and agrochemical use these compounds as raw material. Typical commercial catalysts contains palladium. Finding an economic, active and selective catalyst for the production of alkenes via partial hydrogenation of alkynes is thus an important challenge. On the other hand, the literature on kinetic studies of partial hydrogenation of heavy alkynes is scarce. So the main objectives of this work were to prepare a cheaper catalyst based on low W loading, and study the kinetic of the partial hydrogenation of 1-heptyne. A pseudo-homogeneous and six heterogeneous kinetic models were analyzed. The catalyst was characterized by ICP, XPS, DRX, TPR and hydrogen chemisorption techniques. RESULTS: The characterization results indicate that only WO x species are present on the alumina surface. The WO x/Al 2O 3 catalyst was active and selective for producing 1-heptene even at low reaction temperatures, the partial hydrogenation of 1-heptyne proceeds via two irreversible reactions in parallel. CONCLUSION: The best fit of the experimental data was achieved with a heterogeneous Langmuir-Hinshelwood-Hougen-Watson model in which the rate controlling step is the dissociative adsorption of hydrogen. The activation energy was estimated as E H2 = 34.8 kJ mol -1.
publishDate 2012
dc.date.none.fl_str_mv 2012-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/52813
Maccarrone, María Juliana; Torres, Gerardo; Lederhos, Cecilia Rosa; Badano, Juan Manuel; Vera, Carlos Roman; et al.; Kinetic study of the partial hydrogenation of 1-heptyne on tungsten oxide supported on alumina; John Wiley & Sons Ltd; Journal of Chemical Technology and Biotechnology; 87; 11; 3-2012; 1521-1528
0268-2575
CONICET Digital
CONICET
url http://hdl.handle.net/11336/52813
identifier_str_mv Maccarrone, María Juliana; Torres, Gerardo; Lederhos, Cecilia Rosa; Badano, Juan Manuel; Vera, Carlos Roman; et al.; Kinetic study of the partial hydrogenation of 1-heptyne on tungsten oxide supported on alumina; John Wiley & Sons Ltd; Journal of Chemical Technology and Biotechnology; 87; 11; 3-2012; 1521-1528
0268-2575
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/jctb.3778
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/jctb.3778
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons Ltd
publisher.none.fl_str_mv John Wiley & Sons Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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