Experimental studies and mathematical modeling of the curing reaction of bioinspired copolymers

Autores
Chen, N.; Lee, N.; Bortolato, Santiago Andres; Martino, D. M.
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Polymer curing is a complex process that significantly delineate the final properties of the synthetized material. In this work, the photo-induced crosslinking reaction of synthetic “bioinspired” copolymers based on thymine and ionic groups was studied by gel permeation chromatography and UV absorption spectroscopy. A mathematical model for the curing process based on statistical techniques and coupled to the kinetics of crosslinking was developed. The model allows to predict both, the evolution of the crosslinking degree as a function of curing time and the gel times as a function of the molecular structure of the copolymer and the curing conditions. The theoretical values showed a very good agreement with the UV-Vis and GPC spectroscopy experimental results for all the copolymers studied. A better knowledge of the curing kinetics of thymine-based biopolymers will enable to develop materials with pre-specified properties and to improve their applications.
Fil: Chen, N.. Simmons College; Estados Unidos
Fil: Lee, N.. Simmons College; Estados Unidos
Fil: Bortolato, Santiago Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Química Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario; Argentina
Fil: Martino, D. M.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Física del Sur. Universidad Nacional del Sur. Departamento de Física. Instituto de Física del Sur; Argentina
Materia
CURING KINETICS
MATHEMATICAL MODELING
THYMINE COPOLYMERS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/87156
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Experimental studies and mathematical modeling of the curing reaction of bioinspired copolymersChen, N.Lee, N.Bortolato, Santiago AndresMartino, D. M.CURING KINETICSMATHEMATICAL MODELINGTHYMINE COPOLYMERShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Polymer curing is a complex process that significantly delineate the final properties of the synthetized material. In this work, the photo-induced crosslinking reaction of synthetic “bioinspired” copolymers based on thymine and ionic groups was studied by gel permeation chromatography and UV absorption spectroscopy. A mathematical model for the curing process based on statistical techniques and coupled to the kinetics of crosslinking was developed. The model allows to predict both, the evolution of the crosslinking degree as a function of curing time and the gel times as a function of the molecular structure of the copolymer and the curing conditions. The theoretical values showed a very good agreement with the UV-Vis and GPC spectroscopy experimental results for all the copolymers studied. A better knowledge of the curing kinetics of thymine-based biopolymers will enable to develop materials with pre-specified properties and to improve their applications.Fil: Chen, N.. Simmons College; Estados UnidosFil: Lee, N.. Simmons College; Estados UnidosFil: Bortolato, Santiago Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Química Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario; ArgentinaFil: Martino, D. M.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Física del Sur. Universidad Nacional del Sur. Departamento de Física. Instituto de Física del Sur; ArgentinaTaylor & Francis2018-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/87156Chen, N.; Lee, N.; Bortolato, Santiago Andres; Martino, D. M.; Experimental studies and mathematical modeling of the curing reaction of bioinspired copolymers; Taylor & Francis; Green Chemistry Letters and Reviews; 11; 4; 10-2018; 387-3981751-82531751-7192CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.tandfonline.com/doi/full/10.1080/17518253.2018.1516809info:eu-repo/semantics/altIdentifier/doi/10.1080/17518253.2018.1516809info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:46:21Zoai:ri.conicet.gov.ar:11336/87156instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:46:21.678CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Experimental studies and mathematical modeling of the curing reaction of bioinspired copolymers
title Experimental studies and mathematical modeling of the curing reaction of bioinspired copolymers
spellingShingle Experimental studies and mathematical modeling of the curing reaction of bioinspired copolymers
Chen, N.
CURING KINETICS
MATHEMATICAL MODELING
THYMINE COPOLYMERS
title_short Experimental studies and mathematical modeling of the curing reaction of bioinspired copolymers
title_full Experimental studies and mathematical modeling of the curing reaction of bioinspired copolymers
title_fullStr Experimental studies and mathematical modeling of the curing reaction of bioinspired copolymers
title_full_unstemmed Experimental studies and mathematical modeling of the curing reaction of bioinspired copolymers
title_sort Experimental studies and mathematical modeling of the curing reaction of bioinspired copolymers
dc.creator.none.fl_str_mv Chen, N.
Lee, N.
Bortolato, Santiago Andres
Martino, D. M.
author Chen, N.
author_facet Chen, N.
Lee, N.
Bortolato, Santiago Andres
Martino, D. M.
author_role author
author2 Lee, N.
Bortolato, Santiago Andres
Martino, D. M.
author2_role author
author
author
dc.subject.none.fl_str_mv CURING KINETICS
MATHEMATICAL MODELING
THYMINE COPOLYMERS
topic CURING KINETICS
MATHEMATICAL MODELING
THYMINE COPOLYMERS
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Polymer curing is a complex process that significantly delineate the final properties of the synthetized material. In this work, the photo-induced crosslinking reaction of synthetic “bioinspired” copolymers based on thymine and ionic groups was studied by gel permeation chromatography and UV absorption spectroscopy. A mathematical model for the curing process based on statistical techniques and coupled to the kinetics of crosslinking was developed. The model allows to predict both, the evolution of the crosslinking degree as a function of curing time and the gel times as a function of the molecular structure of the copolymer and the curing conditions. The theoretical values showed a very good agreement with the UV-Vis and GPC spectroscopy experimental results for all the copolymers studied. A better knowledge of the curing kinetics of thymine-based biopolymers will enable to develop materials with pre-specified properties and to improve their applications.
Fil: Chen, N.. Simmons College; Estados Unidos
Fil: Lee, N.. Simmons College; Estados Unidos
Fil: Bortolato, Santiago Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Química Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario; Argentina
Fil: Martino, D. M.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Física del Sur. Universidad Nacional del Sur. Departamento de Física. Instituto de Física del Sur; Argentina
description Polymer curing is a complex process that significantly delineate the final properties of the synthetized material. In this work, the photo-induced crosslinking reaction of synthetic “bioinspired” copolymers based on thymine and ionic groups was studied by gel permeation chromatography and UV absorption spectroscopy. A mathematical model for the curing process based on statistical techniques and coupled to the kinetics of crosslinking was developed. The model allows to predict both, the evolution of the crosslinking degree as a function of curing time and the gel times as a function of the molecular structure of the copolymer and the curing conditions. The theoretical values showed a very good agreement with the UV-Vis and GPC spectroscopy experimental results for all the copolymers studied. A better knowledge of the curing kinetics of thymine-based biopolymers will enable to develop materials with pre-specified properties and to improve their applications.
publishDate 2018
dc.date.none.fl_str_mv 2018-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/87156
Chen, N.; Lee, N.; Bortolato, Santiago Andres; Martino, D. M.; Experimental studies and mathematical modeling of the curing reaction of bioinspired copolymers; Taylor & Francis; Green Chemistry Letters and Reviews; 11; 4; 10-2018; 387-398
1751-8253
1751-7192
CONICET Digital
CONICET
url http://hdl.handle.net/11336/87156
identifier_str_mv Chen, N.; Lee, N.; Bortolato, Santiago Andres; Martino, D. M.; Experimental studies and mathematical modeling of the curing reaction of bioinspired copolymers; Taylor & Francis; Green Chemistry Letters and Reviews; 11; 4; 10-2018; 387-398
1751-8253
1751-7192
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.tandfonline.com/doi/full/10.1080/17518253.2018.1516809
info:eu-repo/semantics/altIdentifier/doi/10.1080/17518253.2018.1516809
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Taylor & Francis
publisher.none.fl_str_mv Taylor & Francis
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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