Fluorescence spectroscopy and multivariate analysis as a greener monitoring tool: characterization of the curing kinetics of bioinspired polymers

Autores
Ledesma, Julieta; Bortolato, Santiago Andres; Martino, Debora Marcela; Boschetti, Carlos Eugenio
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The photo-induced curing kinetics of bioinspired copolymers vinylbenzyl thymine (VBT) and vinylphenyl sulfonatewas studied usingfluorescence spectroscopy in combination with multivariate analysis. Fluorescence spectroscopyenables a detailed description of the curing process of VBT copolymers in real time, combining selectivity,simplicity and sensitivity, without the need of sample pre-treatments, being an advantage from the green analyticalchemistry point of view. Two chemometric strategies were used to decompose the data matrix generated whilemonitoring the curing reaction, identifying the evolution of each species involved in the process in conjunctionwith the corresponding pure spectra. A comprehensive comparison between the developed approaches was made,clearly highlighting the advantages and disadvantages of both of them. The use of multivariate analysis applied tofluorescence spectroscopic data to study curing reactions have several advantages such as no sample pre-treatment,no sophisticated equipment requirement, reduced analysis time and use of non-toxic solvents, among others.
Fil: Ledesma, Julieta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Procesos Biotecnológicos y Quimicos Rosario. Universidad Nacional de Rosario. Facultad de Cs.bioquímicas y Farmaceuticas. Instituto de Procesos Biotecnológicos y Quimicos Rosario; Argentina
Fil: Bortolato, Santiago Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Química Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario; Argentina
Fil: Martino, Debora Marcela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Física del Litoral. Universidad Nacional del Litoral. Instituto de Física del Litoral; Argentina
Fil: Boschetti, Carlos Eugenio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Procesos Biotecnológicos y Quimicos Rosario. Universidad Nacional de Rosario. Facultad de Cs.bioquímicas y Farmaceuticas. Instituto de Procesos Biotecnológicos y Quimicos Rosario; Argentina
Materia
Biopolymers
Thymine
Photo-Induced Curing Kinetics
Multivariate Analysis
Fluorescense Spectroscopy
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/27586
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Fluorescence spectroscopy and multivariate analysis as a greener monitoring tool: characterization of the curing kinetics of bioinspired polymersLedesma, JulietaBortolato, Santiago AndresMartino, Debora MarcelaBoschetti, Carlos EugenioBiopolymersThyminePhoto-Induced Curing KineticsMultivariate AnalysisFluorescense Spectroscopyhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The photo-induced curing kinetics of bioinspired copolymers vinylbenzyl thymine (VBT) and vinylphenyl sulfonatewas studied usingfluorescence spectroscopy in combination with multivariate analysis. Fluorescence spectroscopyenables a detailed description of the curing process of VBT copolymers in real time, combining selectivity,simplicity and sensitivity, without the need of sample pre-treatments, being an advantage from the green analyticalchemistry point of view. Two chemometric strategies were used to decompose the data matrix generated whilemonitoring the curing reaction, identifying the evolution of each species involved in the process in conjunctionwith the corresponding pure spectra. A comprehensive comparison between the developed approaches was made,clearly highlighting the advantages and disadvantages of both of them. The use of multivariate analysis applied tofluorescence spectroscopic data to study curing reactions have several advantages such as no sample pre-treatment,no sophisticated equipment requirement, reduced analysis time and use of non-toxic solvents, among others.Fil: Ledesma, Julieta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Procesos Biotecnológicos y Quimicos Rosario. Universidad Nacional de Rosario. Facultad de Cs.bioquímicas y Farmaceuticas. Instituto de Procesos Biotecnológicos y Quimicos Rosario; ArgentinaFil: Bortolato, Santiago Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Química Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario; ArgentinaFil: Martino, Debora Marcela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Física del Litoral. Universidad Nacional del Litoral. Instituto de Física del Litoral; ArgentinaFil: Boschetti, Carlos Eugenio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Procesos Biotecnológicos y Quimicos Rosario. Universidad Nacional de Rosario. Facultad de Cs.bioquímicas y Farmaceuticas. Instituto de Procesos Biotecnológicos y Quimicos Rosario; ArgentinaTaylor & Francis2015-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/27586Ledesma, Julieta; Bortolato, Santiago Andres; Martino, Debora Marcela; Boschetti, Carlos Eugenio; Fluorescence spectroscopy and multivariate analysis as a greener monitoring tool: characterization of the curing kinetics of bioinspired polymers; Taylor & Francis; Green Chemistry Letters and Reviews; 8; 2; 9-2015; 26-381751-8253CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1080/17518253.2015.1073798info:eu-repo/semantics/altIdentifier/url/http://www.tandfonline.com/doi/full/10.1080/17518253.2015.1073798info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:06:29Zoai:ri.conicet.gov.ar:11336/27586instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:06:29.467CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Fluorescence spectroscopy and multivariate analysis as a greener monitoring tool: characterization of the curing kinetics of bioinspired polymers
title Fluorescence spectroscopy and multivariate analysis as a greener monitoring tool: characterization of the curing kinetics of bioinspired polymers
spellingShingle Fluorescence spectroscopy and multivariate analysis as a greener monitoring tool: characterization of the curing kinetics of bioinspired polymers
Ledesma, Julieta
Biopolymers
Thymine
Photo-Induced Curing Kinetics
Multivariate Analysis
Fluorescense Spectroscopy
title_short Fluorescence spectroscopy and multivariate analysis as a greener monitoring tool: characterization of the curing kinetics of bioinspired polymers
title_full Fluorescence spectroscopy and multivariate analysis as a greener monitoring tool: characterization of the curing kinetics of bioinspired polymers
title_fullStr Fluorescence spectroscopy and multivariate analysis as a greener monitoring tool: characterization of the curing kinetics of bioinspired polymers
title_full_unstemmed Fluorescence spectroscopy and multivariate analysis as a greener monitoring tool: characterization of the curing kinetics of bioinspired polymers
title_sort Fluorescence spectroscopy and multivariate analysis as a greener monitoring tool: characterization of the curing kinetics of bioinspired polymers
dc.creator.none.fl_str_mv Ledesma, Julieta
Bortolato, Santiago Andres
Martino, Debora Marcela
Boschetti, Carlos Eugenio
author Ledesma, Julieta
author_facet Ledesma, Julieta
Bortolato, Santiago Andres
Martino, Debora Marcela
Boschetti, Carlos Eugenio
author_role author
author2 Bortolato, Santiago Andres
Martino, Debora Marcela
Boschetti, Carlos Eugenio
author2_role author
author
author
dc.subject.none.fl_str_mv Biopolymers
Thymine
Photo-Induced Curing Kinetics
Multivariate Analysis
Fluorescense Spectroscopy
topic Biopolymers
Thymine
Photo-Induced Curing Kinetics
Multivariate Analysis
Fluorescense Spectroscopy
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The photo-induced curing kinetics of bioinspired copolymers vinylbenzyl thymine (VBT) and vinylphenyl sulfonatewas studied usingfluorescence spectroscopy in combination with multivariate analysis. Fluorescence spectroscopyenables a detailed description of the curing process of VBT copolymers in real time, combining selectivity,simplicity and sensitivity, without the need of sample pre-treatments, being an advantage from the green analyticalchemistry point of view. Two chemometric strategies were used to decompose the data matrix generated whilemonitoring the curing reaction, identifying the evolution of each species involved in the process in conjunctionwith the corresponding pure spectra. A comprehensive comparison between the developed approaches was made,clearly highlighting the advantages and disadvantages of both of them. The use of multivariate analysis applied tofluorescence spectroscopic data to study curing reactions have several advantages such as no sample pre-treatment,no sophisticated equipment requirement, reduced analysis time and use of non-toxic solvents, among others.
Fil: Ledesma, Julieta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Procesos Biotecnológicos y Quimicos Rosario. Universidad Nacional de Rosario. Facultad de Cs.bioquímicas y Farmaceuticas. Instituto de Procesos Biotecnológicos y Quimicos Rosario; Argentina
Fil: Bortolato, Santiago Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Química Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario; Argentina
Fil: Martino, Debora Marcela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Física del Litoral. Universidad Nacional del Litoral. Instituto de Física del Litoral; Argentina
Fil: Boschetti, Carlos Eugenio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Procesos Biotecnológicos y Quimicos Rosario. Universidad Nacional de Rosario. Facultad de Cs.bioquímicas y Farmaceuticas. Instituto de Procesos Biotecnológicos y Quimicos Rosario; Argentina
description The photo-induced curing kinetics of bioinspired copolymers vinylbenzyl thymine (VBT) and vinylphenyl sulfonatewas studied usingfluorescence spectroscopy in combination with multivariate analysis. Fluorescence spectroscopyenables a detailed description of the curing process of VBT copolymers in real time, combining selectivity,simplicity and sensitivity, without the need of sample pre-treatments, being an advantage from the green analyticalchemistry point of view. Two chemometric strategies were used to decompose the data matrix generated whilemonitoring the curing reaction, identifying the evolution of each species involved in the process in conjunctionwith the corresponding pure spectra. A comprehensive comparison between the developed approaches was made,clearly highlighting the advantages and disadvantages of both of them. The use of multivariate analysis applied tofluorescence spectroscopic data to study curing reactions have several advantages such as no sample pre-treatment,no sophisticated equipment requirement, reduced analysis time and use of non-toxic solvents, among others.
publishDate 2015
dc.date.none.fl_str_mv 2015-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/27586
Ledesma, Julieta; Bortolato, Santiago Andres; Martino, Debora Marcela; Boschetti, Carlos Eugenio; Fluorescence spectroscopy and multivariate analysis as a greener monitoring tool: characterization of the curing kinetics of bioinspired polymers; Taylor & Francis; Green Chemistry Letters and Reviews; 8; 2; 9-2015; 26-38
1751-8253
CONICET Digital
CONICET
url http://hdl.handle.net/11336/27586
identifier_str_mv Ledesma, Julieta; Bortolato, Santiago Andres; Martino, Debora Marcela; Boschetti, Carlos Eugenio; Fluorescence spectroscopy and multivariate analysis as a greener monitoring tool: characterization of the curing kinetics of bioinspired polymers; Taylor & Francis; Green Chemistry Letters and Reviews; 8; 2; 9-2015; 26-38
1751-8253
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1080/17518253.2015.1073798
info:eu-repo/semantics/altIdentifier/url/http://www.tandfonline.com/doi/full/10.1080/17518253.2015.1073798
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Taylor & Francis
publisher.none.fl_str_mv Taylor & Francis
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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