Hydrogen recovery from the purge stream of an HDA process using the concept of Mass Exchange Networks

Autores
Fischer, Carlos Daniel; Iribarren, Oscar Alberto
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this paper we use the concept of Mass Exchange Networks to design the hydrogen recovery from the purge stream of an HDA Process by implementing a recently proposed counter current gas permeation equipment to exchange hydrogen between the purge and the toluene feed to the process. This design would correspond to the final design refinement step in the Douglas and hierarchical process design procedure, proposed by Fischer and Iribarren. The goal of this design is recovering part of the hydrogen available in the purge stream, and results in a process alternative different from other flow sheet recently proposed by Bouton and Luyben, also resorting to gas permeation membrane units, but in a traditional arrangement. Two different types of available zeolite ceramic membranes were studied, of different permeability and selectivity. The here proposed mass exchange design recovers a similar amount of hydrogen as the process alternative proposed by Bouton and Luyben who use a less expensive type of polymeric membrane, but need a compressor to recycle the permeate stream because they use transmembrane pressure as the driving force. The here proposed design at actual cost of zeolite membranes allows an 153.9% increase of the Net Annual Savings with respect to the pressure driven membrane system when using the less selective ceramic membrane, while this figure descents to a 32.61% when using the most selective (which is also the most expensive alternative).
Fil: Fischer, Carlos Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo y Diseño (i); Argentina. Universidad Tecnológica Nacional. Facultad Regional Reconquista; Argentina
Fil: Iribarren, Oscar Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo y Diseño (i); Argentina. Universidad Tecnológica Nacional. Facultad Regional Reconquista; Argentina
Materia
Hda
Hydrogen
Mass Exchange
Integration
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/7080

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spelling Hydrogen recovery from the purge stream of an HDA process using the concept of Mass Exchange NetworksFischer, Carlos DanielIribarren, Oscar AlbertoHdaHydrogenMass ExchangeIntegrationhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2In this paper we use the concept of Mass Exchange Networks to design the hydrogen recovery from the purge stream of an HDA Process by implementing a recently proposed counter current gas permeation equipment to exchange hydrogen between the purge and the toluene feed to the process. This design would correspond to the final design refinement step in the Douglas and hierarchical process design procedure, proposed by Fischer and Iribarren. The goal of this design is recovering part of the hydrogen available in the purge stream, and results in a process alternative different from other flow sheet recently proposed by Bouton and Luyben, also resorting to gas permeation membrane units, but in a traditional arrangement. Two different types of available zeolite ceramic membranes were studied, of different permeability and selectivity. The here proposed mass exchange design recovers a similar amount of hydrogen as the process alternative proposed by Bouton and Luyben who use a less expensive type of polymeric membrane, but need a compressor to recycle the permeate stream because they use transmembrane pressure as the driving force. The here proposed design at actual cost of zeolite membranes allows an 153.9% increase of the Net Annual Savings with respect to the pressure driven membrane system when using the less selective ceramic membrane, while this figure descents to a 32.61% when using the most selective (which is also the most expensive alternative).Fil: Fischer, Carlos Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo y Diseño (i); Argentina. Universidad Tecnológica Nacional. Facultad Regional Reconquista; ArgentinaFil: Iribarren, Oscar Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo y Diseño (i); Argentina. Universidad Tecnológica Nacional. Facultad Regional Reconquista; ArgentinaElsevier2013-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/7080Fischer, Carlos Daniel; Iribarren, Oscar Alberto; Hydrogen recovery from the purge stream of an HDA process using the concept of Mass Exchange Networks; Elsevier; International Journal Of Hydrogen Energy; 38; 15; 4-2013; 6381-63900360-3199enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0360319913006654info:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijhydene.2013.03.055info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:32:26Zoai:ri.conicet.gov.ar:11336/7080instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:32:26.542CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Hydrogen recovery from the purge stream of an HDA process using the concept of Mass Exchange Networks
title Hydrogen recovery from the purge stream of an HDA process using the concept of Mass Exchange Networks
spellingShingle Hydrogen recovery from the purge stream of an HDA process using the concept of Mass Exchange Networks
Fischer, Carlos Daniel
Hda
Hydrogen
Mass Exchange
Integration
title_short Hydrogen recovery from the purge stream of an HDA process using the concept of Mass Exchange Networks
title_full Hydrogen recovery from the purge stream of an HDA process using the concept of Mass Exchange Networks
title_fullStr Hydrogen recovery from the purge stream of an HDA process using the concept of Mass Exchange Networks
title_full_unstemmed Hydrogen recovery from the purge stream of an HDA process using the concept of Mass Exchange Networks
title_sort Hydrogen recovery from the purge stream of an HDA process using the concept of Mass Exchange Networks
dc.creator.none.fl_str_mv Fischer, Carlos Daniel
Iribarren, Oscar Alberto
author Fischer, Carlos Daniel
author_facet Fischer, Carlos Daniel
Iribarren, Oscar Alberto
author_role author
author2 Iribarren, Oscar Alberto
author2_role author
dc.subject.none.fl_str_mv Hda
Hydrogen
Mass Exchange
Integration
topic Hda
Hydrogen
Mass Exchange
Integration
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv In this paper we use the concept of Mass Exchange Networks to design the hydrogen recovery from the purge stream of an HDA Process by implementing a recently proposed counter current gas permeation equipment to exchange hydrogen between the purge and the toluene feed to the process. This design would correspond to the final design refinement step in the Douglas and hierarchical process design procedure, proposed by Fischer and Iribarren. The goal of this design is recovering part of the hydrogen available in the purge stream, and results in a process alternative different from other flow sheet recently proposed by Bouton and Luyben, also resorting to gas permeation membrane units, but in a traditional arrangement. Two different types of available zeolite ceramic membranes were studied, of different permeability and selectivity. The here proposed mass exchange design recovers a similar amount of hydrogen as the process alternative proposed by Bouton and Luyben who use a less expensive type of polymeric membrane, but need a compressor to recycle the permeate stream because they use transmembrane pressure as the driving force. The here proposed design at actual cost of zeolite membranes allows an 153.9% increase of the Net Annual Savings with respect to the pressure driven membrane system when using the less selective ceramic membrane, while this figure descents to a 32.61% when using the most selective (which is also the most expensive alternative).
Fil: Fischer, Carlos Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo y Diseño (i); Argentina. Universidad Tecnológica Nacional. Facultad Regional Reconquista; Argentina
Fil: Iribarren, Oscar Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo y Diseño (i); Argentina. Universidad Tecnológica Nacional. Facultad Regional Reconquista; Argentina
description In this paper we use the concept of Mass Exchange Networks to design the hydrogen recovery from the purge stream of an HDA Process by implementing a recently proposed counter current gas permeation equipment to exchange hydrogen between the purge and the toluene feed to the process. This design would correspond to the final design refinement step in the Douglas and hierarchical process design procedure, proposed by Fischer and Iribarren. The goal of this design is recovering part of the hydrogen available in the purge stream, and results in a process alternative different from other flow sheet recently proposed by Bouton and Luyben, also resorting to gas permeation membrane units, but in a traditional arrangement. Two different types of available zeolite ceramic membranes were studied, of different permeability and selectivity. The here proposed mass exchange design recovers a similar amount of hydrogen as the process alternative proposed by Bouton and Luyben who use a less expensive type of polymeric membrane, but need a compressor to recycle the permeate stream because they use transmembrane pressure as the driving force. The here proposed design at actual cost of zeolite membranes allows an 153.9% increase of the Net Annual Savings with respect to the pressure driven membrane system when using the less selective ceramic membrane, while this figure descents to a 32.61% when using the most selective (which is also the most expensive alternative).
publishDate 2013
dc.date.none.fl_str_mv 2013-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/7080
Fischer, Carlos Daniel; Iribarren, Oscar Alberto; Hydrogen recovery from the purge stream of an HDA process using the concept of Mass Exchange Networks; Elsevier; International Journal Of Hydrogen Energy; 38; 15; 4-2013; 6381-6390
0360-3199
url http://hdl.handle.net/11336/7080
identifier_str_mv Fischer, Carlos Daniel; Iribarren, Oscar Alberto; Hydrogen recovery from the purge stream of an HDA process using the concept of Mass Exchange Networks; Elsevier; International Journal Of Hydrogen Energy; 38; 15; 4-2013; 6381-6390
0360-3199
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0360319913006654
info:eu-repo/semantics/altIdentifier/doi/
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijhydene.2013.03.055
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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