Design and operational limits of an ATR-FTIR spectroscopic microreactor for investigating reactions at liquid-solid interface

Autores
Aguirre, Alejo; Kler, Pablo Alejandro; Berli, Claudio Luis Alberto; Collins, Sebastián Enrique
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This work presents the design and characterization of an optimized attenuated total reflection (ATR) microfluidic cell to assess intrinsic kinetic parameters of reactions at the liquid/solid interface under chemical control. A theoretical and computational investigation of convection, diffusion, and adsorption is presented. Transport dynamics in transient-flow experiments is characterized by a convective and diffusive mass transport of the solution species to the surface of the ATR crystal. Criteria to determine the mass transport limitations of the adsorption process are presented as a function of the Damköhler and Biot numbers. The CO adsorption on a thin film of platinum is studied in order to validate the model.
Fil: Aguirre, Alejo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Kler, Pablo Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Berli, Claudio Luis Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Collins, Sebastián Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Materia
Atr
Ir
Catalysis
Transport
Surface Reaction
Fluid-Dynamics
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/22401
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/22401
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Design and operational limits of an ATR-FTIR spectroscopic microreactor for investigating reactions at liquid-solid interfaceAguirre, AlejoKler, Pablo AlejandroBerli, Claudio Luis AlbertoCollins, Sebastián EnriqueAtrIrCatalysisTransportSurface ReactionFluid-Dynamicshttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2This work presents the design and characterization of an optimized attenuated total reflection (ATR) microfluidic cell to assess intrinsic kinetic parameters of reactions at the liquid/solid interface under chemical control. A theoretical and computational investigation of convection, diffusion, and adsorption is presented. Transport dynamics in transient-flow experiments is characterized by a convective and diffusive mass transport of the solution species to the surface of the ATR crystal. Criteria to determine the mass transport limitations of the adsorption process are presented as a function of the Damköhler and Biot numbers. The CO adsorption on a thin film of platinum is studied in order to validate the model.Fil: Aguirre, Alejo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Kler, Pablo Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Berli, Claudio Luis Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Collins, Sebastián Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaElsevier Science2014-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/22401Aguirre, Alejo; Kler, Pablo Alejandro; Berli, Claudio Luis Alberto; Collins, Sebastián Enrique; Design and operational limits of an ATR-FTIR spectroscopic microreactor for investigating reactions at liquid-solid interface; Elsevier Science; Chemical Engineering Journal; 243; 1-2014; 197-2061385-8947CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.cej.2014.01.001info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1385894714000175info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:01:08Zoai:ri.conicet.gov.ar:11336/22401instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:01:08.677CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Design and operational limits of an ATR-FTIR spectroscopic microreactor for investigating reactions at liquid-solid interface
title Design and operational limits of an ATR-FTIR spectroscopic microreactor for investigating reactions at liquid-solid interface
spellingShingle Design and operational limits of an ATR-FTIR spectroscopic microreactor for investigating reactions at liquid-solid interface
Aguirre, Alejo
Atr
Ir
Catalysis
Transport
Surface Reaction
Fluid-Dynamics
title_short Design and operational limits of an ATR-FTIR spectroscopic microreactor for investigating reactions at liquid-solid interface
title_full Design and operational limits of an ATR-FTIR spectroscopic microreactor for investigating reactions at liquid-solid interface
title_fullStr Design and operational limits of an ATR-FTIR spectroscopic microreactor for investigating reactions at liquid-solid interface
title_full_unstemmed Design and operational limits of an ATR-FTIR spectroscopic microreactor for investigating reactions at liquid-solid interface
title_sort Design and operational limits of an ATR-FTIR spectroscopic microreactor for investigating reactions at liquid-solid interface
dc.creator.none.fl_str_mv Aguirre, Alejo
Kler, Pablo Alejandro
Berli, Claudio Luis Alberto
Collins, Sebastián Enrique
author Aguirre, Alejo
author_facet Aguirre, Alejo
Kler, Pablo Alejandro
Berli, Claudio Luis Alberto
Collins, Sebastián Enrique
author_role author
author2 Kler, Pablo Alejandro
Berli, Claudio Luis Alberto
Collins, Sebastián Enrique
author2_role author
author
author
dc.subject.none.fl_str_mv Atr
Ir
Catalysis
Transport
Surface Reaction
Fluid-Dynamics
topic Atr
Ir
Catalysis
Transport
Surface Reaction
Fluid-Dynamics
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv This work presents the design and characterization of an optimized attenuated total reflection (ATR) microfluidic cell to assess intrinsic kinetic parameters of reactions at the liquid/solid interface under chemical control. A theoretical and computational investigation of convection, diffusion, and adsorption is presented. Transport dynamics in transient-flow experiments is characterized by a convective and diffusive mass transport of the solution species to the surface of the ATR crystal. Criteria to determine the mass transport limitations of the adsorption process are presented as a function of the Damköhler and Biot numbers. The CO adsorption on a thin film of platinum is studied in order to validate the model.
Fil: Aguirre, Alejo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Kler, Pablo Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Berli, Claudio Luis Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Collins, Sebastián Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
description This work presents the design and characterization of an optimized attenuated total reflection (ATR) microfluidic cell to assess intrinsic kinetic parameters of reactions at the liquid/solid interface under chemical control. A theoretical and computational investigation of convection, diffusion, and adsorption is presented. Transport dynamics in transient-flow experiments is characterized by a convective and diffusive mass transport of the solution species to the surface of the ATR crystal. Criteria to determine the mass transport limitations of the adsorption process are presented as a function of the Damköhler and Biot numbers. The CO adsorption on a thin film of platinum is studied in order to validate the model.
publishDate 2014
dc.date.none.fl_str_mv 2014-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/22401
Aguirre, Alejo; Kler, Pablo Alejandro; Berli, Claudio Luis Alberto; Collins, Sebastián Enrique; Design and operational limits of an ATR-FTIR spectroscopic microreactor for investigating reactions at liquid-solid interface; Elsevier Science; Chemical Engineering Journal; 243; 1-2014; 197-206
1385-8947
CONICET Digital
CONICET
url http://hdl.handle.net/11336/22401
identifier_str_mv Aguirre, Alejo; Kler, Pablo Alejandro; Berli, Claudio Luis Alberto; Collins, Sebastián Enrique; Design and operational limits of an ATR-FTIR spectroscopic microreactor for investigating reactions at liquid-solid interface; Elsevier Science; Chemical Engineering Journal; 243; 1-2014; 197-206
1385-8947
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cej.2014.01.001
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1385894714000175
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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