Clean rhodium nanoparticles prepared by laser ablation in liquid for high performance electrocatalysis of the hydrogen evolution reaction

Autores
Volpato, Giulia Alice; Muñetón Arboleda, David; Brandiele, Riccardo; Carraro, Francesco; Sartori, Giovanni Battista; Cardelli, Andrea; Badocco, Denis; Pastore, Paolo; Agnoli, Stefano; Durante, Christian; Amendola, Vincenzo; Sartorel, Andrea
Año de publicación
2019
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Rhodium nanoparticles (NPs) were prepared by a one-step, green and facile procedure consisting in laser ablation of a bulk Rh target immersed in pure water (W–Rh-NPs) or ethanol (E–Rh-NPs). When embedded in mesoporous carbon based inks, both W–Rh-NPs and E– Rh-NPs show excellent activity towards the hydrogen evolution reaction in acidic media, operating close to the thermodynamic potential with 85–97% faradaic yields and low Tafel slopes of 50– 54 mV per decade in the low overpotential region (h < 20 mV). A superior activity of W–Rh-NPs with respect to E–Rh-NPs is ascribed to the absence of surface carbon reducible species derived from the synthesis in organic solvent, and thus confirms the importance of the use of water as the preferred medium for laser synthesis of clean nanocrystals in liquid environment. These results provide an important contribution to the impelling need for the preparation of nanocatalysts based on energy critical materials by clean, sustainable and low cost routes.
Fil: Volpato, Giulia Alice. Università di Padova; Italia
Fil: Muñetón Arboleda, David. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones Ópticas. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones Ópticas. Universidad Nacional de La Plata. Centro de Investigaciones Ópticas; Argentina
Fil: Brandiele, Riccardo. Università di Padova; Italia
Fil: Carraro, Francesco. Università di Padova; Italia
Fil: Sartori, Giovanni Battista. Università di Padova; Italia
Fil: Cardelli, Andrea. Università di Padova; Italia
Fil: Badocco, Denis. Università di Padova; Italia
Fil: Pastore, Paolo. Università di Padova; Italia
Fil: Agnoli, Stefano. Università di Padova; Italia
Fil: Durante, Christian. Università di Padova; Italia
Fil: Amendola, Vincenzo. Università di Padova; Italia
Fil: Sartorel, Andrea. Università di Padova; Italia
Materia
RHODIUM NANOPARTICLES
LASER ABLATION
CATALYSIS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/143087
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/143087
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Clean rhodium nanoparticles prepared by laser ablation in liquid for high performance electrocatalysis of the hydrogen evolution reactionVolpato, Giulia AliceMuñetón Arboleda, DavidBrandiele, RiccardoCarraro, FrancescoSartori, Giovanni BattistaCardelli, AndreaBadocco, DenisPastore, PaoloAgnoli, StefanoDurante, ChristianAmendola, VincenzoSartorel, AndreaRHODIUM NANOPARTICLESLASER ABLATIONCATALYSIShttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2Rhodium nanoparticles (NPs) were prepared by a one-step, green and facile procedure consisting in laser ablation of a bulk Rh target immersed in pure water (W–Rh-NPs) or ethanol (E–Rh-NPs). When embedded in mesoporous carbon based inks, both W–Rh-NPs and E– Rh-NPs show excellent activity towards the hydrogen evolution reaction in acidic media, operating close to the thermodynamic potential with 85–97% faradaic yields and low Tafel slopes of 50– 54 mV per decade in the low overpotential region (h < 20 mV). A superior activity of W–Rh-NPs with respect to E–Rh-NPs is ascribed to the absence of surface carbon reducible species derived from the synthesis in organic solvent, and thus confirms the importance of the use of water as the preferred medium for laser synthesis of clean nanocrystals in liquid environment. These results provide an important contribution to the impelling need for the preparation of nanocatalysts based on energy critical materials by clean, sustainable and low cost routes.Fil: Volpato, Giulia Alice. Università di Padova; ItaliaFil: Muñetón Arboleda, David. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones Ópticas. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones Ópticas. Universidad Nacional de La Plata. Centro de Investigaciones Ópticas; ArgentinaFil: Brandiele, Riccardo. Università di Padova; ItaliaFil: Carraro, Francesco. Università di Padova; ItaliaFil: Sartori, Giovanni Battista. Università di Padova; ItaliaFil: Cardelli, Andrea. Università di Padova; ItaliaFil: Badocco, Denis. Università di Padova; ItaliaFil: Pastore, Paolo. Università di Padova; ItaliaFil: Agnoli, Stefano. Università di Padova; ItaliaFil: Durante, Christian. Università di Padova; ItaliaFil: Amendola, Vincenzo. Università di Padova; ItaliaFil: Sartorel, Andrea. Università di Padova; ItaliaRoyal Society of Chemistry2019-10-16info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/143087Volpato, Giulia Alice; Muñetón Arboleda, David; Brandiele, Riccardo; Carraro, Francesco; Sartori, Giovanni Battista; et al.; Clean rhodium nanoparticles prepared by laser ablation in liquid for high performance electrocatalysis of the hydrogen evolution reaction; Royal Society of Chemistry; Nanoscale Advances; 1; 11; 16-10-2019; 4296-43002516-0230CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://xlink.rsc.org/?DOI=C9NA00510Binfo:eu-repo/semantics/altIdentifier/doi/10.1039/C9NA00510Binfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:54:16Zoai:ri.conicet.gov.ar:11336/143087instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:54:17.233CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Clean rhodium nanoparticles prepared by laser ablation in liquid for high performance electrocatalysis of the hydrogen evolution reaction
title Clean rhodium nanoparticles prepared by laser ablation in liquid for high performance electrocatalysis of the hydrogen evolution reaction
spellingShingle Clean rhodium nanoparticles prepared by laser ablation in liquid for high performance electrocatalysis of the hydrogen evolution reaction
Volpato, Giulia Alice
RHODIUM NANOPARTICLES
LASER ABLATION
CATALYSIS
title_short Clean rhodium nanoparticles prepared by laser ablation in liquid for high performance electrocatalysis of the hydrogen evolution reaction
title_full Clean rhodium nanoparticles prepared by laser ablation in liquid for high performance electrocatalysis of the hydrogen evolution reaction
title_fullStr Clean rhodium nanoparticles prepared by laser ablation in liquid for high performance electrocatalysis of the hydrogen evolution reaction
title_full_unstemmed Clean rhodium nanoparticles prepared by laser ablation in liquid for high performance electrocatalysis of the hydrogen evolution reaction
title_sort Clean rhodium nanoparticles prepared by laser ablation in liquid for high performance electrocatalysis of the hydrogen evolution reaction
dc.creator.none.fl_str_mv Volpato, Giulia Alice
Muñetón Arboleda, David
Brandiele, Riccardo
Carraro, Francesco
Sartori, Giovanni Battista
Cardelli, Andrea
Badocco, Denis
Pastore, Paolo
Agnoli, Stefano
Durante, Christian
Amendola, Vincenzo
Sartorel, Andrea
author Volpato, Giulia Alice
author_facet Volpato, Giulia Alice
Muñetón Arboleda, David
Brandiele, Riccardo
Carraro, Francesco
Sartori, Giovanni Battista
Cardelli, Andrea
Badocco, Denis
Pastore, Paolo
Agnoli, Stefano
Durante, Christian
Amendola, Vincenzo
Sartorel, Andrea
author_role author
author2 Muñetón Arboleda, David
Brandiele, Riccardo
Carraro, Francesco
Sartori, Giovanni Battista
Cardelli, Andrea
Badocco, Denis
Pastore, Paolo
Agnoli, Stefano
Durante, Christian
Amendola, Vincenzo
Sartorel, Andrea
author2_role author
author
author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv RHODIUM NANOPARTICLES
LASER ABLATION
CATALYSIS
topic RHODIUM NANOPARTICLES
LASER ABLATION
CATALYSIS
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Rhodium nanoparticles (NPs) were prepared by a one-step, green and facile procedure consisting in laser ablation of a bulk Rh target immersed in pure water (W–Rh-NPs) or ethanol (E–Rh-NPs). When embedded in mesoporous carbon based inks, both W–Rh-NPs and E– Rh-NPs show excellent activity towards the hydrogen evolution reaction in acidic media, operating close to the thermodynamic potential with 85–97% faradaic yields and low Tafel slopes of 50– 54 mV per decade in the low overpotential region (h < 20 mV). A superior activity of W–Rh-NPs with respect to E–Rh-NPs is ascribed to the absence of surface carbon reducible species derived from the synthesis in organic solvent, and thus confirms the importance of the use of water as the preferred medium for laser synthesis of clean nanocrystals in liquid environment. These results provide an important contribution to the impelling need for the preparation of nanocatalysts based on energy critical materials by clean, sustainable and low cost routes.
Fil: Volpato, Giulia Alice. Università di Padova; Italia
Fil: Muñetón Arboleda, David. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigaciones Ópticas. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigaciones Ópticas. Universidad Nacional de La Plata. Centro de Investigaciones Ópticas; Argentina
Fil: Brandiele, Riccardo. Università di Padova; Italia
Fil: Carraro, Francesco. Università di Padova; Italia
Fil: Sartori, Giovanni Battista. Università di Padova; Italia
Fil: Cardelli, Andrea. Università di Padova; Italia
Fil: Badocco, Denis. Università di Padova; Italia
Fil: Pastore, Paolo. Università di Padova; Italia
Fil: Agnoli, Stefano. Università di Padova; Italia
Fil: Durante, Christian. Università di Padova; Italia
Fil: Amendola, Vincenzo. Università di Padova; Italia
Fil: Sartorel, Andrea. Università di Padova; Italia
description Rhodium nanoparticles (NPs) were prepared by a one-step, green and facile procedure consisting in laser ablation of a bulk Rh target immersed in pure water (W–Rh-NPs) or ethanol (E–Rh-NPs). When embedded in mesoporous carbon based inks, both W–Rh-NPs and E– Rh-NPs show excellent activity towards the hydrogen evolution reaction in acidic media, operating close to the thermodynamic potential with 85–97% faradaic yields and low Tafel slopes of 50– 54 mV per decade in the low overpotential region (h < 20 mV). A superior activity of W–Rh-NPs with respect to E–Rh-NPs is ascribed to the absence of surface carbon reducible species derived from the synthesis in organic solvent, and thus confirms the importance of the use of water as the preferred medium for laser synthesis of clean nanocrystals in liquid environment. These results provide an important contribution to the impelling need for the preparation of nanocatalysts based on energy critical materials by clean, sustainable and low cost routes.
publishDate 2019
dc.date.none.fl_str_mv 2019-10-16
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/143087
Volpato, Giulia Alice; Muñetón Arboleda, David; Brandiele, Riccardo; Carraro, Francesco; Sartori, Giovanni Battista; et al.; Clean rhodium nanoparticles prepared by laser ablation in liquid for high performance electrocatalysis of the hydrogen evolution reaction; Royal Society of Chemistry; Nanoscale Advances; 1; 11; 16-10-2019; 4296-4300
2516-0230
CONICET Digital
CONICET
url http://hdl.handle.net/11336/143087
identifier_str_mv Volpato, Giulia Alice; Muñetón Arboleda, David; Brandiele, Riccardo; Carraro, Francesco; Sartori, Giovanni Battista; et al.; Clean rhodium nanoparticles prepared by laser ablation in liquid for high performance electrocatalysis of the hydrogen evolution reaction; Royal Society of Chemistry; Nanoscale Advances; 1; 11; 16-10-2019; 4296-4300
2516-0230
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://xlink.rsc.org/?DOI=C9NA00510B
info:eu-repo/semantics/altIdentifier/doi/10.1039/C9NA00510B
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842269276047671296
score 13.13397

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