Synthesis of Ni nanoparticles by Femtosecond Laser ablation in liquids: structure and sizing

Autores
Muñetón Arboleda, David; Santillán, Jesica María José; Mendoza Herrera, Luis Joaquin; Fernandez Van Raap, Marcela Beatriz; Mendoza Zélis, Pedro; Muraca, Diego; Schinca, Daniel C.; Scaffardi, Lucia Beatriz
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Synthesis of nickel (Ni) nanoparticles (NPs) suspensions was performed using a 120 fs (femtosecond) pulse laser to ablate a Ni solid target in n-heptane and water. Analysis of structure, configuration, and sizing was carried out using different independent techniques, such as optical extinction spectroscopy (OES), atomic force microscopy (AFM), transmission electron microscopy (TEM), and electron diffraction (ED), which yield interrelated information. AFM microscopy allows determining the spherical shape and size distribution of the NPs in the obtained colloids, while TEM provides knowledge about shape, structure, and size distribution. ED allows identification of the different metal and metal oxide compositions as well as their crystallographic phase. On the other hand, OES gives information related to size distribution, structure, configuration, and composition. Interpretation of these spectra is based on Mie theory, which, in turn, depends on Ni dielectric function. For NP radii smaller than 3 nm, sizedependent free and bound electron contributions to the dielectric function must be considered. To account for the full size span, complete Mie expansion was used for optical extinction cross-section calculations. A theoretical analysis of the dependence of plasmon resonance of bare core and core−shell Ni NPs with core size and shell thickness provides insight about their spectroscopic features. For n-heptane, species like bare core Ni and hollow Ni NPs are found in the colloid, the latter being reported for the first time in this work. Instead, for water, the colloid contains hollow nickel NPs and nickel oxide in different core−shell configurations: Ni−NiO and NiO−Ni, the latter also being reported for the first time in this paper. In both cases, the size distribution agrees with that derived from TEM and AFM analysis. The formation of the oxide species is discussed in terms of oxidation−reduction processes during ablation. Possible mechanisms for the formation of hollow species are proposed.
Fil: Muñetón Arboleda, David. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigaciones Opticas (i); Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; Argentina
Fil: Santillán, Jesica María José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigaciones Opticas (i); Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; Argentina. Universidad Nacional de Catamarca; Argentina
Fil: Mendoza Herrera, Luis Joaquin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigaciones Opticas (i); Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; Argentina
Fil: Fernandez Van Raap, Marcela Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Instituto de Física La Plata; Argentina. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Departamento de Física; Argentina
Fil: Mendoza Zélis, Pedro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Instituto de Física La Plata; Argentina. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Departamento de Física; Argentina. Universidad Nacional de La Plata. Facultad de Ingenieria; Argentina
Fil: Muraca, Diego. Universidade Estadual de Campinas; Brasil. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Schinca, Daniel C.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigaciones Opticas (i); Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; Argentina. Universidad Nacional de La Plata. Facultad de Ingenieria; Argentina
Fil: Scaffardi, Lucia Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigaciones Opticas (i); Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; Argentina. Universidad Nacional de La Plata. Facultad de Ingenieria; Argentina
Materia
Nickel Nanoparticles
Femtosecond Laser Ablation
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/12029
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/12029
network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling Synthesis of Ni nanoparticles by Femtosecond Laser ablation in liquids: structure and sizingMuñetón Arboleda, DavidSantillán, Jesica María JoséMendoza Herrera, Luis JoaquinFernandez Van Raap, Marcela BeatrizMendoza Zélis, PedroMuraca, DiegoSchinca, Daniel C.Scaffardi, Lucia BeatrizNickel NanoparticlesFemtosecond Laser Ablationhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1Synthesis of nickel (Ni) nanoparticles (NPs) suspensions was performed using a 120 fs (femtosecond) pulse laser to ablate a Ni solid target in n-heptane and water. Analysis of structure, configuration, and sizing was carried out using different independent techniques, such as optical extinction spectroscopy (OES), atomic force microscopy (AFM), transmission electron microscopy (TEM), and electron diffraction (ED), which yield interrelated information. AFM microscopy allows determining the spherical shape and size distribution of the NPs in the obtained colloids, while TEM provides knowledge about shape, structure, and size distribution. ED allows identification of the different metal and metal oxide compositions as well as their crystallographic phase. On the other hand, OES gives information related to size distribution, structure, configuration, and composition. Interpretation of these spectra is based on Mie theory, which, in turn, depends on Ni dielectric function. For NP radii smaller than 3 nm, sizedependent free and bound electron contributions to the dielectric function must be considered. To account for the full size span, complete Mie expansion was used for optical extinction cross-section calculations. A theoretical analysis of the dependence of plasmon resonance of bare core and core−shell Ni NPs with core size and shell thickness provides insight about their spectroscopic features. For n-heptane, species like bare core Ni and hollow Ni NPs are found in the colloid, the latter being reported for the first time in this work. Instead, for water, the colloid contains hollow nickel NPs and nickel oxide in different core−shell configurations: Ni−NiO and NiO−Ni, the latter also being reported for the first time in this paper. In both cases, the size distribution agrees with that derived from TEM and AFM analysis. The formation of the oxide species is discussed in terms of oxidation−reduction processes during ablation. Possible mechanisms for the formation of hollow species are proposed.Fil: Muñetón Arboleda, David. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigaciones Opticas (i); Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; ArgentinaFil: Santillán, Jesica María José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigaciones Opticas (i); Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; Argentina. Universidad Nacional de Catamarca; ArgentinaFil: Mendoza Herrera, Luis Joaquin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigaciones Opticas (i); Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; ArgentinaFil: Fernandez Van Raap, Marcela Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Instituto de Física La Plata; Argentina. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Departamento de Física; ArgentinaFil: Mendoza Zélis, Pedro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Instituto de Física La Plata; Argentina. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Departamento de Física; Argentina. Universidad Nacional de La Plata. Facultad de Ingenieria; ArgentinaFil: Muraca, Diego. Universidade Estadual de Campinas; Brasil. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Schinca, Daniel C.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigaciones Opticas (i); Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; Argentina. Universidad Nacional de La Plata. Facultad de Ingenieria; ArgentinaFil: Scaffardi, Lucia Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigaciones Opticas (i); Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; Argentina. Universidad Nacional de La Plata. Facultad de Ingenieria; ArgentinaAmerican Chemical Society2015-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/12029Muñetón Arboleda, David; Santillán, Jesica María José; Mendoza Herrera, Luis Joaquin; Fernandez Van Raap, Marcela Beatriz; Mendoza Zélis, Pedro; et al.; Synthesis of Ni nanoparticles by Femtosecond Laser ablation in liquids: structure and sizing; American Chemical Society; Journal Of Physical Chemistry C; 119; 23; 5-2015; 13184–131931932-74471932-7455enginfo:eu-repo/semantics/altIdentifier/doi/10.1021/acs.jpcc.5b03124info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/acs.jpcc.5b03124info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:06:11Zoai:ri.conicet.gov.ar:11336/12029instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:06:11.984CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synthesis of Ni nanoparticles by Femtosecond Laser ablation in liquids: structure and sizing
title Synthesis of Ni nanoparticles by Femtosecond Laser ablation in liquids: structure and sizing
spellingShingle Synthesis of Ni nanoparticles by Femtosecond Laser ablation in liquids: structure and sizing
Muñetón Arboleda, David
Nickel Nanoparticles
Femtosecond Laser Ablation
title_short Synthesis of Ni nanoparticles by Femtosecond Laser ablation in liquids: structure and sizing
title_full Synthesis of Ni nanoparticles by Femtosecond Laser ablation in liquids: structure and sizing
title_fullStr Synthesis of Ni nanoparticles by Femtosecond Laser ablation in liquids: structure and sizing
title_full_unstemmed Synthesis of Ni nanoparticles by Femtosecond Laser ablation in liquids: structure and sizing
title_sort Synthesis of Ni nanoparticles by Femtosecond Laser ablation in liquids: structure and sizing
dc.creator.none.fl_str_mv Muñetón Arboleda, David
Santillán, Jesica María José
Mendoza Herrera, Luis Joaquin
Fernandez Van Raap, Marcela Beatriz
Mendoza Zélis, Pedro
Muraca, Diego
Schinca, Daniel C.
Scaffardi, Lucia Beatriz
author Muñetón Arboleda, David
author_facet Muñetón Arboleda, David
Santillán, Jesica María José
Mendoza Herrera, Luis Joaquin
Fernandez Van Raap, Marcela Beatriz
Mendoza Zélis, Pedro
Muraca, Diego
Schinca, Daniel C.
Scaffardi, Lucia Beatriz
author_role author
author2 Santillán, Jesica María José
Mendoza Herrera, Luis Joaquin
Fernandez Van Raap, Marcela Beatriz
Mendoza Zélis, Pedro
Muraca, Diego
Schinca, Daniel C.
Scaffardi, Lucia Beatriz
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Nickel Nanoparticles
Femtosecond Laser Ablation
topic Nickel Nanoparticles
Femtosecond Laser Ablation
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Synthesis of nickel (Ni) nanoparticles (NPs) suspensions was performed using a 120 fs (femtosecond) pulse laser to ablate a Ni solid target in n-heptane and water. Analysis of structure, configuration, and sizing was carried out using different independent techniques, such as optical extinction spectroscopy (OES), atomic force microscopy (AFM), transmission electron microscopy (TEM), and electron diffraction (ED), which yield interrelated information. AFM microscopy allows determining the spherical shape and size distribution of the NPs in the obtained colloids, while TEM provides knowledge about shape, structure, and size distribution. ED allows identification of the different metal and metal oxide compositions as well as their crystallographic phase. On the other hand, OES gives information related to size distribution, structure, configuration, and composition. Interpretation of these spectra is based on Mie theory, which, in turn, depends on Ni dielectric function. For NP radii smaller than 3 nm, sizedependent free and bound electron contributions to the dielectric function must be considered. To account for the full size span, complete Mie expansion was used for optical extinction cross-section calculations. A theoretical analysis of the dependence of plasmon resonance of bare core and core−shell Ni NPs with core size and shell thickness provides insight about their spectroscopic features. For n-heptane, species like bare core Ni and hollow Ni NPs are found in the colloid, the latter being reported for the first time in this work. Instead, for water, the colloid contains hollow nickel NPs and nickel oxide in different core−shell configurations: Ni−NiO and NiO−Ni, the latter also being reported for the first time in this paper. In both cases, the size distribution agrees with that derived from TEM and AFM analysis. The formation of the oxide species is discussed in terms of oxidation−reduction processes during ablation. Possible mechanisms for the formation of hollow species are proposed.
Fil: Muñetón Arboleda, David. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigaciones Opticas (i); Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; Argentina
Fil: Santillán, Jesica María José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigaciones Opticas (i); Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; Argentina. Universidad Nacional de Catamarca; Argentina
Fil: Mendoza Herrera, Luis Joaquin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigaciones Opticas (i); Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; Argentina
Fil: Fernandez Van Raap, Marcela Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Instituto de Física La Plata; Argentina. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Departamento de Física; Argentina
Fil: Mendoza Zélis, Pedro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Instituto de Física La Plata; Argentina. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Departamento de Física; Argentina. Universidad Nacional de La Plata. Facultad de Ingenieria; Argentina
Fil: Muraca, Diego. Universidade Estadual de Campinas; Brasil. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Schinca, Daniel C.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigaciones Opticas (i); Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; Argentina. Universidad Nacional de La Plata. Facultad de Ingenieria; Argentina
Fil: Scaffardi, Lucia Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Centro de Investigaciones Opticas (i); Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas; Argentina. Universidad Nacional de La Plata. Facultad de Ingenieria; Argentina
description Synthesis of nickel (Ni) nanoparticles (NPs) suspensions was performed using a 120 fs (femtosecond) pulse laser to ablate a Ni solid target in n-heptane and water. Analysis of structure, configuration, and sizing was carried out using different independent techniques, such as optical extinction spectroscopy (OES), atomic force microscopy (AFM), transmission electron microscopy (TEM), and electron diffraction (ED), which yield interrelated information. AFM microscopy allows determining the spherical shape and size distribution of the NPs in the obtained colloids, while TEM provides knowledge about shape, structure, and size distribution. ED allows identification of the different metal and metal oxide compositions as well as their crystallographic phase. On the other hand, OES gives information related to size distribution, structure, configuration, and composition. Interpretation of these spectra is based on Mie theory, which, in turn, depends on Ni dielectric function. For NP radii smaller than 3 nm, sizedependent free and bound electron contributions to the dielectric function must be considered. To account for the full size span, complete Mie expansion was used for optical extinction cross-section calculations. A theoretical analysis of the dependence of plasmon resonance of bare core and core−shell Ni NPs with core size and shell thickness provides insight about their spectroscopic features. For n-heptane, species like bare core Ni and hollow Ni NPs are found in the colloid, the latter being reported for the first time in this work. Instead, for water, the colloid contains hollow nickel NPs and nickel oxide in different core−shell configurations: Ni−NiO and NiO−Ni, the latter also being reported for the first time in this paper. In both cases, the size distribution agrees with that derived from TEM and AFM analysis. The formation of the oxide species is discussed in terms of oxidation−reduction processes during ablation. Possible mechanisms for the formation of hollow species are proposed.
publishDate 2015
dc.date.none.fl_str_mv 2015-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/12029
Muñetón Arboleda, David; Santillán, Jesica María José; Mendoza Herrera, Luis Joaquin; Fernandez Van Raap, Marcela Beatriz; Mendoza Zélis, Pedro; et al.; Synthesis of Ni nanoparticles by Femtosecond Laser ablation in liquids: structure and sizing; American Chemical Society; Journal Of Physical Chemistry C; 119; 23; 5-2015; 13184–13193
1932-7447
1932-7455
url http://hdl.handle.net/11336/12029
identifier_str_mv Muñetón Arboleda, David; Santillán, Jesica María José; Mendoza Herrera, Luis Joaquin; Fernandez Van Raap, Marcela Beatriz; Mendoza Zélis, Pedro; et al.; Synthesis of Ni nanoparticles by Femtosecond Laser ablation in liquids: structure and sizing; American Chemical Society; Journal Of Physical Chemistry C; 119; 23; 5-2015; 13184–13193
1932-7447
1932-7455
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.jpcc.5b03124
info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/acs.jpcc.5b03124
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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