Carbon-supported PtSn Catalysts: Characterization and Catalytic Properties
- Autores
- Román Martínez, María Carmen; Cazorla Amorós, Diego; de Miguel, Sergio Ruben; Scelza, Osvaldo Antonio
- Año de publicación
- 2004
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Carbon-supported PtSn catalysts were prepared by impregnation using a commercial activated carbon after purification and oxidation (H2O2, 20 v/v%) treatments. The support surface chemistry of the carbon after purification and the oxidized carbon, and successive impregnation or coimpregnation procedures were the variables investigated. The catalysts obtained were characterized using the following techniques: TPD and TPR experiments, H2 chemisorption, XPS and XAFS, and activity assessment in the following reactions: cyclohexane dehydrogenation (reaction insensitive to structure), cyclopentane hydrogenolysis (reaction sensitive to structure) and carvone hydrogenation, which allows analysis of the selectivity of PtSn catalysts (carvone contains one C=O group and two C=C bonds for hydrogenation). The objective of the study is to find any relationships between the preparation procedure and the support properties, the characteristics of the resulting catalysts, and the catalytic behavior. The porosity of the carbon support together with the surface oxidation determines the accessibility of reactants to the active sites. Unusual selectivity to alcohols was found. Addition of tin caused blocking and dilution of the platinum clusters. The carbon support also affected the selectivity either because of its electronic properties or because of the particular metal structures developed.
Fil: Román Martínez, María Carmen. Universidad de Alicante; España
Fil: Cazorla Amorós, Diego. Universidad de Alicante; España
Fil: de Miguel, Sergio Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Scelza, Osvaldo Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina - Materia
-
Platinum Tin Catalyst
Carbon Support
Carvone Hydrogenation
Xafs
Tpr - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/55833
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spelling |
Carbon-supported PtSn Catalysts: Characterization and Catalytic PropertiesRomán Martínez, María CarmenCazorla Amorós, Diegode Miguel, Sergio RubenScelza, Osvaldo AntonioPlatinum Tin CatalystCarbon SupportCarvone HydrogenationXafsTprhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Carbon-supported PtSn catalysts were prepared by impregnation using a commercial activated carbon after purification and oxidation (H2O2, 20 v/v%) treatments. The support surface chemistry of the carbon after purification and the oxidized carbon, and successive impregnation or coimpregnation procedures were the variables investigated. The catalysts obtained were characterized using the following techniques: TPD and TPR experiments, H2 chemisorption, XPS and XAFS, and activity assessment in the following reactions: cyclohexane dehydrogenation (reaction insensitive to structure), cyclopentane hydrogenolysis (reaction sensitive to structure) and carvone hydrogenation, which allows analysis of the selectivity of PtSn catalysts (carvone contains one C=O group and two C=C bonds for hydrogenation). The objective of the study is to find any relationships between the preparation procedure and the support properties, the characteristics of the resulting catalysts, and the catalytic behavior. The porosity of the carbon support together with the surface oxidation determines the accessibility of reactants to the active sites. Unusual selectivity to alcohols was found. Addition of tin caused blocking and dilution of the platinum clusters. The carbon support also affected the selectivity either because of its electronic properties or because of the particular metal structures developed.Fil: Román Martínez, María Carmen. Universidad de Alicante; EspañaFil: Cazorla Amorós, Diego. Universidad de Alicante; EspañaFil: de Miguel, Sergio Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Scelza, Osvaldo Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaJapan Petroleum Inst2004-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/55833Román Martínez, María Carmen; Cazorla Amorós, Diego; de Miguel, Sergio Ruben; Scelza, Osvaldo Antonio; Carbon-supported PtSn Catalysts: Characterization and Catalytic Properties; Japan Petroleum Inst; Journal Of The Japan Petroleum Institute; 47; 3; 12-2004; 164-1781346-88041349-273XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.jstage.jst.go.jp/article/jpi/47/3/47_3_164/_pdfinfo:eu-repo/semantics/altIdentifier/doi/10.1627/jpi.47.164info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:48:46Zoai:ri.conicet.gov.ar:11336/55833instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:48:46.951CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Carbon-supported PtSn Catalysts: Characterization and Catalytic Properties |
title |
Carbon-supported PtSn Catalysts: Characterization and Catalytic Properties |
spellingShingle |
Carbon-supported PtSn Catalysts: Characterization and Catalytic Properties Román Martínez, María Carmen Platinum Tin Catalyst Carbon Support Carvone Hydrogenation Xafs Tpr |
title_short |
Carbon-supported PtSn Catalysts: Characterization and Catalytic Properties |
title_full |
Carbon-supported PtSn Catalysts: Characterization and Catalytic Properties |
title_fullStr |
Carbon-supported PtSn Catalysts: Characterization and Catalytic Properties |
title_full_unstemmed |
Carbon-supported PtSn Catalysts: Characterization and Catalytic Properties |
title_sort |
Carbon-supported PtSn Catalysts: Characterization and Catalytic Properties |
dc.creator.none.fl_str_mv |
Román Martínez, María Carmen Cazorla Amorós, Diego de Miguel, Sergio Ruben Scelza, Osvaldo Antonio |
author |
Román Martínez, María Carmen |
author_facet |
Román Martínez, María Carmen Cazorla Amorós, Diego de Miguel, Sergio Ruben Scelza, Osvaldo Antonio |
author_role |
author |
author2 |
Cazorla Amorós, Diego de Miguel, Sergio Ruben Scelza, Osvaldo Antonio |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Platinum Tin Catalyst Carbon Support Carvone Hydrogenation Xafs Tpr |
topic |
Platinum Tin Catalyst Carbon Support Carvone Hydrogenation Xafs Tpr |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
Carbon-supported PtSn catalysts were prepared by impregnation using a commercial activated carbon after purification and oxidation (H2O2, 20 v/v%) treatments. The support surface chemistry of the carbon after purification and the oxidized carbon, and successive impregnation or coimpregnation procedures were the variables investigated. The catalysts obtained were characterized using the following techniques: TPD and TPR experiments, H2 chemisorption, XPS and XAFS, and activity assessment in the following reactions: cyclohexane dehydrogenation (reaction insensitive to structure), cyclopentane hydrogenolysis (reaction sensitive to structure) and carvone hydrogenation, which allows analysis of the selectivity of PtSn catalysts (carvone contains one C=O group and two C=C bonds for hydrogenation). The objective of the study is to find any relationships between the preparation procedure and the support properties, the characteristics of the resulting catalysts, and the catalytic behavior. The porosity of the carbon support together with the surface oxidation determines the accessibility of reactants to the active sites. Unusual selectivity to alcohols was found. Addition of tin caused blocking and dilution of the platinum clusters. The carbon support also affected the selectivity either because of its electronic properties or because of the particular metal structures developed. Fil: Román Martínez, María Carmen. Universidad de Alicante; España Fil: Cazorla Amorós, Diego. Universidad de Alicante; España Fil: de Miguel, Sergio Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina Fil: Scelza, Osvaldo Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina |
description |
Carbon-supported PtSn catalysts were prepared by impregnation using a commercial activated carbon after purification and oxidation (H2O2, 20 v/v%) treatments. The support surface chemistry of the carbon after purification and the oxidized carbon, and successive impregnation or coimpregnation procedures were the variables investigated. The catalysts obtained were characterized using the following techniques: TPD and TPR experiments, H2 chemisorption, XPS and XAFS, and activity assessment in the following reactions: cyclohexane dehydrogenation (reaction insensitive to structure), cyclopentane hydrogenolysis (reaction sensitive to structure) and carvone hydrogenation, which allows analysis of the selectivity of PtSn catalysts (carvone contains one C=O group and two C=C bonds for hydrogenation). The objective of the study is to find any relationships between the preparation procedure and the support properties, the characteristics of the resulting catalysts, and the catalytic behavior. The porosity of the carbon support together with the surface oxidation determines the accessibility of reactants to the active sites. Unusual selectivity to alcohols was found. Addition of tin caused blocking and dilution of the platinum clusters. The carbon support also affected the selectivity either because of its electronic properties or because of the particular metal structures developed. |
publishDate |
2004 |
dc.date.none.fl_str_mv |
2004-12 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/55833 Román Martínez, María Carmen; Cazorla Amorós, Diego; de Miguel, Sergio Ruben; Scelza, Osvaldo Antonio; Carbon-supported PtSn Catalysts: Characterization and Catalytic Properties; Japan Petroleum Inst; Journal Of The Japan Petroleum Institute; 47; 3; 12-2004; 164-178 1346-8804 1349-273X CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/55833 |
identifier_str_mv |
Román Martínez, María Carmen; Cazorla Amorós, Diego; de Miguel, Sergio Ruben; Scelza, Osvaldo Antonio; Carbon-supported PtSn Catalysts: Characterization and Catalytic Properties; Japan Petroleum Inst; Journal Of The Japan Petroleum Institute; 47; 3; 12-2004; 164-178 1346-8804 1349-273X CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://www.jstage.jst.go.jp/article/jpi/47/3/47_3_164/_pdf info:eu-repo/semantics/altIdentifier/doi/10.1627/jpi.47.164 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Japan Petroleum Inst |
publisher.none.fl_str_mv |
Japan Petroleum Inst |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1842268938975576064 |
score |
13.13397 |