Pt, PtSn and PtGe catalysts supported on granular carbon for fine chemistry hydrogenation reactions
- Autores
- Vilella, Irene María Julieta; de Miguel, Sergio Ruben; Scelza, Osvaldo Antonio
- Año de publicación
- 2008
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Two series of PtSn and PtGe catalysts with different metallic loadings, supported on activated carbon powder, were prepared by successive impregnation. Both the effects of the second metal addition and the Sn or Ge loading on the activity and selectivity in the carvone and the citral hydrogenations (used as catalytic tests) were investigated. In all cases the support was purified to eliminate undesirable elements such as sulfur and, for high Pt loadings, carbon was functionalized with nitric acid so as to introduce more oxygen-containing groups. The carvone hydrogenation was carried out with PtSn catalysts, the Pt and Sn loadings being very low. The citral hydrogenation was carried out with PtSn and PtGe catalysts with higher metal loadings supported on both purified, and purified and functionalized carbons. Besides, the effect of the branched solvent in the activity and selectivity of the citral hydrogenation reaction was also studied with PtSn catalysts. The catalysts were characterized by temperature-programmed reaction (TPR), test reactions of the metallic phase (cyclohexane dehydrogenation and cyclopentane hydrogenolysis), hydrogen chemisorption and by X-ray photoelectron spectroscopy (XPS). The catalytic activity in the carvone hydrogenation showed a maximum for the monometallic catalyst with respect to the Sn loading. For the catalyst with the highest tin loading (0.4 wt%) even though the activity drastically decreased, the selectivity to the doubled unsaturated alcohol (carveol) was very important. Although the citral hydrogenation gave very good results with PtSn systems with high metallic loadings, the opposite happened with the PtGe ones. Moreover, the more branched solvents modified the selectivity to unsaturated alcohols of the PtSn catalyst in the citral hydrogenation.
Fil: Vilella, Irene María Julieta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: de Miguel, Sergio Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Scelza, Osvaldo Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina - Materia
-
Activated Carbon Powder
Carvone Hydrogenation
Citral Hydrogenation
Ptge Catalysts
Ptsn - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/65249
Ver los metadatos del registro completo
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Pt, PtSn and PtGe catalysts supported on granular carbon for fine chemistry hydrogenation reactionsVilella, Irene María Julietade Miguel, Sergio RubenScelza, Osvaldo AntonioActivated Carbon PowderCarvone HydrogenationCitral HydrogenationPtge CatalystsPtsnhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Two series of PtSn and PtGe catalysts with different metallic loadings, supported on activated carbon powder, were prepared by successive impregnation. Both the effects of the second metal addition and the Sn or Ge loading on the activity and selectivity in the carvone and the citral hydrogenations (used as catalytic tests) were investigated. In all cases the support was purified to eliminate undesirable elements such as sulfur and, for high Pt loadings, carbon was functionalized with nitric acid so as to introduce more oxygen-containing groups. The carvone hydrogenation was carried out with PtSn catalysts, the Pt and Sn loadings being very low. The citral hydrogenation was carried out with PtSn and PtGe catalysts with higher metal loadings supported on both purified, and purified and functionalized carbons. Besides, the effect of the branched solvent in the activity and selectivity of the citral hydrogenation reaction was also studied with PtSn catalysts. The catalysts were characterized by temperature-programmed reaction (TPR), test reactions of the metallic phase (cyclohexane dehydrogenation and cyclopentane hydrogenolysis), hydrogen chemisorption and by X-ray photoelectron spectroscopy (XPS). The catalytic activity in the carvone hydrogenation showed a maximum for the monometallic catalyst with respect to the Sn loading. For the catalyst with the highest tin loading (0.4 wt%) even though the activity drastically decreased, the selectivity to the doubled unsaturated alcohol (carveol) was very important. Although the citral hydrogenation gave very good results with PtSn systems with high metallic loadings, the opposite happened with the PtGe ones. Moreover, the more branched solvents modified the selectivity to unsaturated alcohols of the PtSn catalyst in the citral hydrogenation.Fil: Vilella, Irene María Julieta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: de Miguel, Sergio Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Scelza, Osvaldo Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaElsevier Science2008-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/65249Vilella, Irene María Julieta; de Miguel, Sergio Ruben; Scelza, Osvaldo Antonio; Pt, PtSn and PtGe catalysts supported on granular carbon for fine chemistry hydrogenation reactions; Elsevier Science; Journal of Molecular Catalysis A: Chemical; 284; 1-2; 4-2008; 161-1711381-1169CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.molcata.2008.01.017info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:53:54Zoai:ri.conicet.gov.ar:11336/65249instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:53:54.57CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Pt, PtSn and PtGe catalysts supported on granular carbon for fine chemistry hydrogenation reactions |
title |
Pt, PtSn and PtGe catalysts supported on granular carbon for fine chemistry hydrogenation reactions |
spellingShingle |
Pt, PtSn and PtGe catalysts supported on granular carbon for fine chemistry hydrogenation reactions Vilella, Irene María Julieta Activated Carbon Powder Carvone Hydrogenation Citral Hydrogenation Ptge Catalysts Ptsn |
title_short |
Pt, PtSn and PtGe catalysts supported on granular carbon for fine chemistry hydrogenation reactions |
title_full |
Pt, PtSn and PtGe catalysts supported on granular carbon for fine chemistry hydrogenation reactions |
title_fullStr |
Pt, PtSn and PtGe catalysts supported on granular carbon for fine chemistry hydrogenation reactions |
title_full_unstemmed |
Pt, PtSn and PtGe catalysts supported on granular carbon for fine chemistry hydrogenation reactions |
title_sort |
Pt, PtSn and PtGe catalysts supported on granular carbon for fine chemistry hydrogenation reactions |
dc.creator.none.fl_str_mv |
Vilella, Irene María Julieta de Miguel, Sergio Ruben Scelza, Osvaldo Antonio |
author |
Vilella, Irene María Julieta |
author_facet |
Vilella, Irene María Julieta de Miguel, Sergio Ruben Scelza, Osvaldo Antonio |
author_role |
author |
author2 |
de Miguel, Sergio Ruben Scelza, Osvaldo Antonio |
author2_role |
author author |
dc.subject.none.fl_str_mv |
Activated Carbon Powder Carvone Hydrogenation Citral Hydrogenation Ptge Catalysts Ptsn |
topic |
Activated Carbon Powder Carvone Hydrogenation Citral Hydrogenation Ptge Catalysts Ptsn |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
Two series of PtSn and PtGe catalysts with different metallic loadings, supported on activated carbon powder, were prepared by successive impregnation. Both the effects of the second metal addition and the Sn or Ge loading on the activity and selectivity in the carvone and the citral hydrogenations (used as catalytic tests) were investigated. In all cases the support was purified to eliminate undesirable elements such as sulfur and, for high Pt loadings, carbon was functionalized with nitric acid so as to introduce more oxygen-containing groups. The carvone hydrogenation was carried out with PtSn catalysts, the Pt and Sn loadings being very low. The citral hydrogenation was carried out with PtSn and PtGe catalysts with higher metal loadings supported on both purified, and purified and functionalized carbons. Besides, the effect of the branched solvent in the activity and selectivity of the citral hydrogenation reaction was also studied with PtSn catalysts. The catalysts were characterized by temperature-programmed reaction (TPR), test reactions of the metallic phase (cyclohexane dehydrogenation and cyclopentane hydrogenolysis), hydrogen chemisorption and by X-ray photoelectron spectroscopy (XPS). The catalytic activity in the carvone hydrogenation showed a maximum for the monometallic catalyst with respect to the Sn loading. For the catalyst with the highest tin loading (0.4 wt%) even though the activity drastically decreased, the selectivity to the doubled unsaturated alcohol (carveol) was very important. Although the citral hydrogenation gave very good results with PtSn systems with high metallic loadings, the opposite happened with the PtGe ones. Moreover, the more branched solvents modified the selectivity to unsaturated alcohols of the PtSn catalyst in the citral hydrogenation. Fil: Vilella, Irene María Julieta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina Fil: de Miguel, Sergio Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina Fil: Scelza, Osvaldo Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina |
description |
Two series of PtSn and PtGe catalysts with different metallic loadings, supported on activated carbon powder, were prepared by successive impregnation. Both the effects of the second metal addition and the Sn or Ge loading on the activity and selectivity in the carvone and the citral hydrogenations (used as catalytic tests) were investigated. In all cases the support was purified to eliminate undesirable elements such as sulfur and, for high Pt loadings, carbon was functionalized with nitric acid so as to introduce more oxygen-containing groups. The carvone hydrogenation was carried out with PtSn catalysts, the Pt and Sn loadings being very low. The citral hydrogenation was carried out with PtSn and PtGe catalysts with higher metal loadings supported on both purified, and purified and functionalized carbons. Besides, the effect of the branched solvent in the activity and selectivity of the citral hydrogenation reaction was also studied with PtSn catalysts. The catalysts were characterized by temperature-programmed reaction (TPR), test reactions of the metallic phase (cyclohexane dehydrogenation and cyclopentane hydrogenolysis), hydrogen chemisorption and by X-ray photoelectron spectroscopy (XPS). The catalytic activity in the carvone hydrogenation showed a maximum for the monometallic catalyst with respect to the Sn loading. For the catalyst with the highest tin loading (0.4 wt%) even though the activity drastically decreased, the selectivity to the doubled unsaturated alcohol (carveol) was very important. Although the citral hydrogenation gave very good results with PtSn systems with high metallic loadings, the opposite happened with the PtGe ones. Moreover, the more branched solvents modified the selectivity to unsaturated alcohols of the PtSn catalyst in the citral hydrogenation. |
publishDate |
2008 |
dc.date.none.fl_str_mv |
2008-04 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/65249 Vilella, Irene María Julieta; de Miguel, Sergio Ruben; Scelza, Osvaldo Antonio; Pt, PtSn and PtGe catalysts supported on granular carbon for fine chemistry hydrogenation reactions; Elsevier Science; Journal of Molecular Catalysis A: Chemical; 284; 1-2; 4-2008; 161-171 1381-1169 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/65249 |
identifier_str_mv |
Vilella, Irene María Julieta; de Miguel, Sergio Ruben; Scelza, Osvaldo Antonio; Pt, PtSn and PtGe catalysts supported on granular carbon for fine chemistry hydrogenation reactions; Elsevier Science; Journal of Molecular Catalysis A: Chemical; 284; 1-2; 4-2008; 161-171 1381-1169 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.molcata.2008.01.017 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1842269255939129344 |
score |
13.13397 |