One-Pot Synthesis of Acidic Mesoporous Activated Carbon Obtained from Yerba Mate Twigs as Suitable Catalyst for the Production of Levulinic Ester Biofuel Additives
- Autores
- Alvear Daza, John Jairo; Sosa, Alexis Alberto; Ruiz, Diego M.; Pasquale, Gustavo A.; Rengifo Herrera, Julian Andres; Romanelli, Gustavo Pablo; Pizzio, Luis Rene
- Año de publicación
- 2024
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- A series of activated carbons (YMBC) obtained from yerba mate twig residue (YMT) were prepared by chemical (H3PO4) and thermal activation. Five materials were synthesized, varying the carbonization temperature (400–600 °C under N2 atmosphere) and H3PO4:YMT ratio (60–80 wt%). They were physicochemically and texturally characterized by SEM-EDX, BET, FT-IR, and 31P MAS-NMR. Potentiometric titration with the n-butylamine technique was used to evaluate their acidic properties. The materials exhibited a high specific surface area (572 m2 g−1 < SBET < 1031 m2 g−1) and mesoporosity (67% < Smeso/SBET < 93%). The results showed that the acid strength and the number of acid sites increased with the H3PO4:YMT ratio and decreased with the calcination temperature increment. The FT-IR and 31P characterization revealed the presence of Hn+2PnO3n+1 species firmly (via P-O-C linkages) and loosely attached (by electrostatic interaction). The latter were successfully removed by refluxing the material in water or n-propanol. The optimal reaction conditions were applied to the synthesis of other levulinic acid esters using YMBC-500-70NP as a catalyst. Furthermore, the effective separation of the product combined with the use of a recyclable catalyst resulted in a clean and environmentally friendly strategy for the synthesis of alkyl levulinates, bioproducts of relevance to the biorefinery industry, which can be applied as fragrances, flavoring agents, as well as fuel additives.
Fil: Alvear Daza, John Jairo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Sosa, Alexis Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Ruiz, Diego M.. Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales. Centro de Investigación de Sanidad Vegetal; Argentina
Fil: Pasquale, Gustavo A.. Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales. Centro de Investigación de Sanidad Vegetal; Argentina
Fil: Rengifo Herrera, Julian Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Pizzio, Luis Rene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina - Materia
-
esterification
levulinic acid
levulinate ester
yerba mate twigs
mesoporous activated carbon - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/261394
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oai:ri.conicet.gov.ar:11336/261394 |
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network_name_str |
CONICET Digital (CONICET) |
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One-Pot Synthesis of Acidic Mesoporous Activated Carbon Obtained from Yerba Mate Twigs as Suitable Catalyst for the Production of Levulinic Ester Biofuel AdditivesAlvear Daza, John JairoSosa, Alexis AlbertoRuiz, Diego M.Pasquale, Gustavo A.Rengifo Herrera, Julian AndresRomanelli, Gustavo PabloPizzio, Luis Reneesterificationlevulinic acidlevulinate esteryerba mate twigsmesoporous activated carbonhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A series of activated carbons (YMBC) obtained from yerba mate twig residue (YMT) were prepared by chemical (H3PO4) and thermal activation. Five materials were synthesized, varying the carbonization temperature (400–600 °C under N2 atmosphere) and H3PO4:YMT ratio (60–80 wt%). They were physicochemically and texturally characterized by SEM-EDX, BET, FT-IR, and 31P MAS-NMR. Potentiometric titration with the n-butylamine technique was used to evaluate their acidic properties. The materials exhibited a high specific surface area (572 m2 g−1 < SBET < 1031 m2 g−1) and mesoporosity (67% < Smeso/SBET < 93%). The results showed that the acid strength and the number of acid sites increased with the H3PO4:YMT ratio and decreased with the calcination temperature increment. The FT-IR and 31P characterization revealed the presence of Hn+2PnO3n+1 species firmly (via P-O-C linkages) and loosely attached (by electrostatic interaction). The latter were successfully removed by refluxing the material in water or n-propanol. The optimal reaction conditions were applied to the synthesis of other levulinic acid esters using YMBC-500-70NP as a catalyst. Furthermore, the effective separation of the product combined with the use of a recyclable catalyst resulted in a clean and environmentally friendly strategy for the synthesis of alkyl levulinates, bioproducts of relevance to the biorefinery industry, which can be applied as fragrances, flavoring agents, as well as fuel additives.Fil: Alvear Daza, John Jairo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Sosa, Alexis Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Ruiz, Diego M.. Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales. Centro de Investigación de Sanidad Vegetal; ArgentinaFil: Pasquale, Gustavo A.. Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales. Centro de Investigación de Sanidad Vegetal; ArgentinaFil: Rengifo Herrera, Julian Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Pizzio, Luis Rene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaMDPI2024-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/261394Alvear Daza, John Jairo; Sosa, Alexis Alberto; Ruiz, Diego M.; Pasquale, Gustavo A.; Rengifo Herrera, Julian Andres; et al.; One-Pot Synthesis of Acidic Mesoporous Activated Carbon Obtained from Yerba Mate Twigs as Suitable Catalyst for the Production of Levulinic Ester Biofuel Additives; MDPI; Catalysts; 14; 8; 8-2024; 1-152073-4344CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2073-4344/14/8/522info:eu-repo/semantics/altIdentifier/doi/10.3390/catal14080522info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:06:42Zoai:ri.conicet.gov.ar:11336/261394instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:06:42.792CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
One-Pot Synthesis of Acidic Mesoporous Activated Carbon Obtained from Yerba Mate Twigs as Suitable Catalyst for the Production of Levulinic Ester Biofuel Additives |
title |
One-Pot Synthesis of Acidic Mesoporous Activated Carbon Obtained from Yerba Mate Twigs as Suitable Catalyst for the Production of Levulinic Ester Biofuel Additives |
spellingShingle |
One-Pot Synthesis of Acidic Mesoporous Activated Carbon Obtained from Yerba Mate Twigs as Suitable Catalyst for the Production of Levulinic Ester Biofuel Additives Alvear Daza, John Jairo esterification levulinic acid levulinate ester yerba mate twigs mesoporous activated carbon |
title_short |
One-Pot Synthesis of Acidic Mesoporous Activated Carbon Obtained from Yerba Mate Twigs as Suitable Catalyst for the Production of Levulinic Ester Biofuel Additives |
title_full |
One-Pot Synthesis of Acidic Mesoporous Activated Carbon Obtained from Yerba Mate Twigs as Suitable Catalyst for the Production of Levulinic Ester Biofuel Additives |
title_fullStr |
One-Pot Synthesis of Acidic Mesoporous Activated Carbon Obtained from Yerba Mate Twigs as Suitable Catalyst for the Production of Levulinic Ester Biofuel Additives |
title_full_unstemmed |
One-Pot Synthesis of Acidic Mesoporous Activated Carbon Obtained from Yerba Mate Twigs as Suitable Catalyst for the Production of Levulinic Ester Biofuel Additives |
title_sort |
One-Pot Synthesis of Acidic Mesoporous Activated Carbon Obtained from Yerba Mate Twigs as Suitable Catalyst for the Production of Levulinic Ester Biofuel Additives |
dc.creator.none.fl_str_mv |
Alvear Daza, John Jairo Sosa, Alexis Alberto Ruiz, Diego M. Pasquale, Gustavo A. Rengifo Herrera, Julian Andres Romanelli, Gustavo Pablo Pizzio, Luis Rene |
author |
Alvear Daza, John Jairo |
author_facet |
Alvear Daza, John Jairo Sosa, Alexis Alberto Ruiz, Diego M. Pasquale, Gustavo A. Rengifo Herrera, Julian Andres Romanelli, Gustavo Pablo Pizzio, Luis Rene |
author_role |
author |
author2 |
Sosa, Alexis Alberto Ruiz, Diego M. Pasquale, Gustavo A. Rengifo Herrera, Julian Andres Romanelli, Gustavo Pablo Pizzio, Luis Rene |
author2_role |
author author author author author author |
dc.subject.none.fl_str_mv |
esterification levulinic acid levulinate ester yerba mate twigs mesoporous activated carbon |
topic |
esterification levulinic acid levulinate ester yerba mate twigs mesoporous activated carbon |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
A series of activated carbons (YMBC) obtained from yerba mate twig residue (YMT) were prepared by chemical (H3PO4) and thermal activation. Five materials were synthesized, varying the carbonization temperature (400–600 °C under N2 atmosphere) and H3PO4:YMT ratio (60–80 wt%). They were physicochemically and texturally characterized by SEM-EDX, BET, FT-IR, and 31P MAS-NMR. Potentiometric titration with the n-butylamine technique was used to evaluate their acidic properties. The materials exhibited a high specific surface area (572 m2 g−1 < SBET < 1031 m2 g−1) and mesoporosity (67% < Smeso/SBET < 93%). The results showed that the acid strength and the number of acid sites increased with the H3PO4:YMT ratio and decreased with the calcination temperature increment. The FT-IR and 31P characterization revealed the presence of Hn+2PnO3n+1 species firmly (via P-O-C linkages) and loosely attached (by electrostatic interaction). The latter were successfully removed by refluxing the material in water or n-propanol. The optimal reaction conditions were applied to the synthesis of other levulinic acid esters using YMBC-500-70NP as a catalyst. Furthermore, the effective separation of the product combined with the use of a recyclable catalyst resulted in a clean and environmentally friendly strategy for the synthesis of alkyl levulinates, bioproducts of relevance to the biorefinery industry, which can be applied as fragrances, flavoring agents, as well as fuel additives. Fil: Alvear Daza, John Jairo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina Fil: Sosa, Alexis Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina Fil: Ruiz, Diego M.. Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales. Centro de Investigación de Sanidad Vegetal; Argentina Fil: Pasquale, Gustavo A.. Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales. Centro de Investigación de Sanidad Vegetal; Argentina Fil: Rengifo Herrera, Julian Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina Fil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina Fil: Pizzio, Luis Rene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina |
description |
A series of activated carbons (YMBC) obtained from yerba mate twig residue (YMT) were prepared by chemical (H3PO4) and thermal activation. Five materials were synthesized, varying the carbonization temperature (400–600 °C under N2 atmosphere) and H3PO4:YMT ratio (60–80 wt%). They were physicochemically and texturally characterized by SEM-EDX, BET, FT-IR, and 31P MAS-NMR. Potentiometric titration with the n-butylamine technique was used to evaluate their acidic properties. The materials exhibited a high specific surface area (572 m2 g−1 < SBET < 1031 m2 g−1) and mesoporosity (67% < Smeso/SBET < 93%). The results showed that the acid strength and the number of acid sites increased with the H3PO4:YMT ratio and decreased with the calcination temperature increment. The FT-IR and 31P characterization revealed the presence of Hn+2PnO3n+1 species firmly (via P-O-C linkages) and loosely attached (by electrostatic interaction). The latter were successfully removed by refluxing the material in water or n-propanol. The optimal reaction conditions were applied to the synthesis of other levulinic acid esters using YMBC-500-70NP as a catalyst. Furthermore, the effective separation of the product combined with the use of a recyclable catalyst resulted in a clean and environmentally friendly strategy for the synthesis of alkyl levulinates, bioproducts of relevance to the biorefinery industry, which can be applied as fragrances, flavoring agents, as well as fuel additives. |
publishDate |
2024 |
dc.date.none.fl_str_mv |
2024-08 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/261394 Alvear Daza, John Jairo; Sosa, Alexis Alberto; Ruiz, Diego M.; Pasquale, Gustavo A.; Rengifo Herrera, Julian Andres; et al.; One-Pot Synthesis of Acidic Mesoporous Activated Carbon Obtained from Yerba Mate Twigs as Suitable Catalyst for the Production of Levulinic Ester Biofuel Additives; MDPI; Catalysts; 14; 8; 8-2024; 1-15 2073-4344 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/261394 |
identifier_str_mv |
Alvear Daza, John Jairo; Sosa, Alexis Alberto; Ruiz, Diego M.; Pasquale, Gustavo A.; Rengifo Herrera, Julian Andres; et al.; One-Pot Synthesis of Acidic Mesoporous Activated Carbon Obtained from Yerba Mate Twigs as Suitable Catalyst for the Production of Levulinic Ester Biofuel Additives; MDPI; Catalysts; 14; 8; 8-2024; 1-15 2073-4344 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2073-4344/14/8/522 info:eu-repo/semantics/altIdentifier/doi/10.3390/catal14080522 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
MDPI |
publisher.none.fl_str_mv |
MDPI |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1844613918500061184 |
score |
13.070432 |