An overview of the obtaining of biomass-derived gamma-valerolactone from levulinic acid or esters without H2 supply

Autores
González, Roxana Giselle; Area, Maria Cristina
Año de publicación
2021
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Gamma-valerolactone (GVL) is a highly reactive keto-lactone and a promising platform biomolecule, used as an additive for food and fuels, green solvent, and fuels precursor, among others. Its production from biomass usually involves hydrogenation and subsequent cyclization of levulinic acid or its esters. The process of conventional hydrogenation requires high pressures and temperatures, an external hydrogen source, and scarce noble/precious materials as catalysts. However, it could be produced under mild conditions, using bifunctional metal-acid catalysts with high metal dispersion and meso or microporosity, high surface area, temperatures lower than 200 °C, pressures ≤ 1MPa, and secondary alcohols (such as isopropanol) as hydrogen donors. The catalytic transfer hydrogenation followed by cyclization (CTHC) of levulinic acid (LA) and its esters (LE) to produce GVL using secondary alcohols as H donor is a great alternative. Variables involved in CTHC such as raw material, time, temperature, and type of catalyst, mainly transition metals and their combinations, are reviewed in this work.
Fil: González, Roxana Giselle. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Area, Maria Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Materia
BIOREFINERY
CATALYTIC TRANSFER HYDROGENATION
GAMMA-VALEROLACTONE
HETEROGENEOUS CATALYSTS
TRANSITION METALS
LEVULINIC ACID
LEVULINIC ESTERS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/151062
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling An overview of the obtaining of biomass-derived gamma-valerolactone from levulinic acid or esters without H2 supplyGonzález, Roxana GiselleArea, Maria CristinaBIOREFINERYCATALYTIC TRANSFER HYDROGENATIONGAMMA-VALEROLACTONEHETEROGENEOUS CATALYSTSTRANSITION METALSLEVULINIC ACIDLEVULINIC ESTERShttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Gamma-valerolactone (GVL) is a highly reactive keto-lactone and a promising platform biomolecule, used as an additive for food and fuels, green solvent, and fuels precursor, among others. Its production from biomass usually involves hydrogenation and subsequent cyclization of levulinic acid or its esters. The process of conventional hydrogenation requires high pressures and temperatures, an external hydrogen source, and scarce noble/precious materials as catalysts. However, it could be produced under mild conditions, using bifunctional metal-acid catalysts with high metal dispersion and meso or microporosity, high surface area, temperatures lower than 200 °C, pressures ≤ 1MPa, and secondary alcohols (such as isopropanol) as hydrogen donors. The catalytic transfer hydrogenation followed by cyclization (CTHC) of levulinic acid (LA) and its esters (LE) to produce GVL using secondary alcohols as H donor is a great alternative. Variables involved in CTHC such as raw material, time, temperature, and type of catalyst, mainly transition metals and their combinations, are reviewed in this work.Fil: González, Roxana Giselle. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; ArgentinaFil: Area, Maria Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; ArgentinaNorth Carolina State University. Department of Wood and Paper Science2021-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/151062González, Roxana Giselle; Area, Maria Cristina; An overview of the obtaining of biomass-derived gamma-valerolactone from levulinic acid or esters without H2 supply; North Carolina State University. Department of Wood and Paper Science; Bioresources; 16; 4; 8-2021; 8417-84441930-2126CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://bioresources.cnr.ncsu.edu/resources/an-overview-of-the-obtaining-of-biomass-derived-gamma-valerolactone-from-levulinic-acid-or-esters-without-h2-supply/info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-10T13:04:27Zoai:ri.conicet.gov.ar:11336/151062instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-10 13:04:27.613CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv An overview of the obtaining of biomass-derived gamma-valerolactone from levulinic acid or esters without H2 supply
title An overview of the obtaining of biomass-derived gamma-valerolactone from levulinic acid or esters without H2 supply
spellingShingle An overview of the obtaining of biomass-derived gamma-valerolactone from levulinic acid or esters without H2 supply
González, Roxana Giselle
BIOREFINERY
CATALYTIC TRANSFER HYDROGENATION
GAMMA-VALEROLACTONE
HETEROGENEOUS CATALYSTS
TRANSITION METALS
LEVULINIC ACID
LEVULINIC ESTERS
title_short An overview of the obtaining of biomass-derived gamma-valerolactone from levulinic acid or esters without H2 supply
title_full An overview of the obtaining of biomass-derived gamma-valerolactone from levulinic acid or esters without H2 supply
title_fullStr An overview of the obtaining of biomass-derived gamma-valerolactone from levulinic acid or esters without H2 supply
title_full_unstemmed An overview of the obtaining of biomass-derived gamma-valerolactone from levulinic acid or esters without H2 supply
title_sort An overview of the obtaining of biomass-derived gamma-valerolactone from levulinic acid or esters without H2 supply
dc.creator.none.fl_str_mv González, Roxana Giselle
Area, Maria Cristina
author González, Roxana Giselle
author_facet González, Roxana Giselle
Area, Maria Cristina
author_role author
author2 Area, Maria Cristina
author2_role author
dc.subject.none.fl_str_mv BIOREFINERY
CATALYTIC TRANSFER HYDROGENATION
GAMMA-VALEROLACTONE
HETEROGENEOUS CATALYSTS
TRANSITION METALS
LEVULINIC ACID
LEVULINIC ESTERS
topic BIOREFINERY
CATALYTIC TRANSFER HYDROGENATION
GAMMA-VALEROLACTONE
HETEROGENEOUS CATALYSTS
TRANSITION METALS
LEVULINIC ACID
LEVULINIC ESTERS
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Gamma-valerolactone (GVL) is a highly reactive keto-lactone and a promising platform biomolecule, used as an additive for food and fuels, green solvent, and fuels precursor, among others. Its production from biomass usually involves hydrogenation and subsequent cyclization of levulinic acid or its esters. The process of conventional hydrogenation requires high pressures and temperatures, an external hydrogen source, and scarce noble/precious materials as catalysts. However, it could be produced under mild conditions, using bifunctional metal-acid catalysts with high metal dispersion and meso or microporosity, high surface area, temperatures lower than 200 °C, pressures ≤ 1MPa, and secondary alcohols (such as isopropanol) as hydrogen donors. The catalytic transfer hydrogenation followed by cyclization (CTHC) of levulinic acid (LA) and its esters (LE) to produce GVL using secondary alcohols as H donor is a great alternative. Variables involved in CTHC such as raw material, time, temperature, and type of catalyst, mainly transition metals and their combinations, are reviewed in this work.
Fil: González, Roxana Giselle. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Area, Maria Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
description Gamma-valerolactone (GVL) is a highly reactive keto-lactone and a promising platform biomolecule, used as an additive for food and fuels, green solvent, and fuels precursor, among others. Its production from biomass usually involves hydrogenation and subsequent cyclization of levulinic acid or its esters. The process of conventional hydrogenation requires high pressures and temperatures, an external hydrogen source, and scarce noble/precious materials as catalysts. However, it could be produced under mild conditions, using bifunctional metal-acid catalysts with high metal dispersion and meso or microporosity, high surface area, temperatures lower than 200 °C, pressures ≤ 1MPa, and secondary alcohols (such as isopropanol) as hydrogen donors. The catalytic transfer hydrogenation followed by cyclization (CTHC) of levulinic acid (LA) and its esters (LE) to produce GVL using secondary alcohols as H donor is a great alternative. Variables involved in CTHC such as raw material, time, temperature, and type of catalyst, mainly transition metals and their combinations, are reviewed in this work.
publishDate 2021
dc.date.none.fl_str_mv 2021-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/151062
González, Roxana Giselle; Area, Maria Cristina; An overview of the obtaining of biomass-derived gamma-valerolactone from levulinic acid or esters without H2 supply; North Carolina State University. Department of Wood and Paper Science; Bioresources; 16; 4; 8-2021; 8417-8444
1930-2126
CONICET Digital
CONICET
url http://hdl.handle.net/11336/151062
identifier_str_mv González, Roxana Giselle; Area, Maria Cristina; An overview of the obtaining of biomass-derived gamma-valerolactone from levulinic acid or esters without H2 supply; North Carolina State University. Department of Wood and Paper Science; Bioresources; 16; 4; 8-2021; 8417-8444
1930-2126
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://bioresources.cnr.ncsu.edu/resources/an-overview-of-the-obtaining-of-biomass-derived-gamma-valerolactone-from-levulinic-acid-or-esters-without-h2-supply/
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv North Carolina State University. Department of Wood and Paper Science
publisher.none.fl_str_mv North Carolina State University. Department of Wood and Paper Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842980149263335424
score 12.993085

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