Emulsion Copolymerization of Acrylonitrile and Butadiene. Semi-Batch Strategies for Controlling Molecular Structure on the Basis of Calorimetric Measurements

Autores
Vega, Jorge Ruben; Gugliotta, Luis Marcelino; Meira, Gregorio Raul
Año de publicación
2002
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A semibatch emulsion copolymerization of acrylonitrile and butadiene is theoretically investigated, with the aim of controlling the molecular structure of the produced NBR. An open-loop estimator based on calorimetric measurements is proposed for monitoring the chemical composition, the average molecular weights, and the average degree of branching. With little effect on the other quality variables, the intermediate addition of acrylonitrile allows to produce a polymer with a constant chemical composition. Similarly, the intermediate addition of the chain transfer agent produces a polymer with either a fixed or with a prespecified linear variation of the average branching. The required feed profiles are obtained from a numerical inversion of a discrete process model. By increasing the initiator loads, the semibatch strategies also allow to increase the final conversion between 3% and 6%, without altering the reaction time nor deteriorating the polymer quality with respect to the batch. The numerical procedures were tested by inputing (relatively noisy) heat measurements from an industrial batch reactor.
Fil: Vega, Jorge Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Gugliotta, Luis Marcelino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Meira, Gregorio Raul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/30072
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Emulsion Copolymerization of Acrylonitrile and Butadiene. Semi-Batch Strategies for Controlling Molecular Structure on the Basis of Calorimetric MeasurementsVega, Jorge RubenGugliotta, Luis MarcelinoMeira, Gregorio Raulhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2A semibatch emulsion copolymerization of acrylonitrile and butadiene is theoretically investigated, with the aim of controlling the molecular structure of the produced NBR. An open-loop estimator based on calorimetric measurements is proposed for monitoring the chemical composition, the average molecular weights, and the average degree of branching. With little effect on the other quality variables, the intermediate addition of acrylonitrile allows to produce a polymer with a constant chemical composition. Similarly, the intermediate addition of the chain transfer agent produces a polymer with either a fixed or with a prespecified linear variation of the average branching. The required feed profiles are obtained from a numerical inversion of a discrete process model. By increasing the initiator loads, the semibatch strategies also allow to increase the final conversion between 3% and 6%, without altering the reaction time nor deteriorating the polymer quality with respect to the batch. The numerical procedures were tested by inputing (relatively noisy) heat measurements from an industrial batch reactor.Fil: Vega, Jorge Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Gugliotta, Luis Marcelino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Meira, Gregorio Raul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaTaylor & Francis2002-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/30072Vega, Jorge Ruben; Gugliotta, Luis Marcelino; Meira, Gregorio Raul; Emulsion Copolymerization of Acrylonitrile and Butadiene. Semi-Batch Strategies for Controlling Molecular Structure on the Basis of Calorimetric Measurements; Taylor & Francis; Polymer Reaction Engineering; 10; 12-2002; 59-821054-3414CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.tandfonline.com/doi/full/10.1081/PRE-120003922info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:09:37Zoai:ri.conicet.gov.ar:11336/30072instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:09:37.77CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Emulsion Copolymerization of Acrylonitrile and Butadiene. Semi-Batch Strategies for Controlling Molecular Structure on the Basis of Calorimetric Measurements
title Emulsion Copolymerization of Acrylonitrile and Butadiene. Semi-Batch Strategies for Controlling Molecular Structure on the Basis of Calorimetric Measurements
spellingShingle Emulsion Copolymerization of Acrylonitrile and Butadiene. Semi-Batch Strategies for Controlling Molecular Structure on the Basis of Calorimetric Measurements
Vega, Jorge Ruben
title_short Emulsion Copolymerization of Acrylonitrile and Butadiene. Semi-Batch Strategies for Controlling Molecular Structure on the Basis of Calorimetric Measurements
title_full Emulsion Copolymerization of Acrylonitrile and Butadiene. Semi-Batch Strategies for Controlling Molecular Structure on the Basis of Calorimetric Measurements
title_fullStr Emulsion Copolymerization of Acrylonitrile and Butadiene. Semi-Batch Strategies for Controlling Molecular Structure on the Basis of Calorimetric Measurements
title_full_unstemmed Emulsion Copolymerization of Acrylonitrile and Butadiene. Semi-Batch Strategies for Controlling Molecular Structure on the Basis of Calorimetric Measurements
title_sort Emulsion Copolymerization of Acrylonitrile and Butadiene. Semi-Batch Strategies for Controlling Molecular Structure on the Basis of Calorimetric Measurements
dc.creator.none.fl_str_mv Vega, Jorge Ruben
Gugliotta, Luis Marcelino
Meira, Gregorio Raul
author Vega, Jorge Ruben
author_facet Vega, Jorge Ruben
Gugliotta, Luis Marcelino
Meira, Gregorio Raul
author_role author
author2 Gugliotta, Luis Marcelino
Meira, Gregorio Raul
author2_role author
author
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv A semibatch emulsion copolymerization of acrylonitrile and butadiene is theoretically investigated, with the aim of controlling the molecular structure of the produced NBR. An open-loop estimator based on calorimetric measurements is proposed for monitoring the chemical composition, the average molecular weights, and the average degree of branching. With little effect on the other quality variables, the intermediate addition of acrylonitrile allows to produce a polymer with a constant chemical composition. Similarly, the intermediate addition of the chain transfer agent produces a polymer with either a fixed or with a prespecified linear variation of the average branching. The required feed profiles are obtained from a numerical inversion of a discrete process model. By increasing the initiator loads, the semibatch strategies also allow to increase the final conversion between 3% and 6%, without altering the reaction time nor deteriorating the polymer quality with respect to the batch. The numerical procedures were tested by inputing (relatively noisy) heat measurements from an industrial batch reactor.
Fil: Vega, Jorge Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Gugliotta, Luis Marcelino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Meira, Gregorio Raul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
description A semibatch emulsion copolymerization of acrylonitrile and butadiene is theoretically investigated, with the aim of controlling the molecular structure of the produced NBR. An open-loop estimator based on calorimetric measurements is proposed for monitoring the chemical composition, the average molecular weights, and the average degree of branching. With little effect on the other quality variables, the intermediate addition of acrylonitrile allows to produce a polymer with a constant chemical composition. Similarly, the intermediate addition of the chain transfer agent produces a polymer with either a fixed or with a prespecified linear variation of the average branching. The required feed profiles are obtained from a numerical inversion of a discrete process model. By increasing the initiator loads, the semibatch strategies also allow to increase the final conversion between 3% and 6%, without altering the reaction time nor deteriorating the polymer quality with respect to the batch. The numerical procedures were tested by inputing (relatively noisy) heat measurements from an industrial batch reactor.
publishDate 2002
dc.date.none.fl_str_mv 2002-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/30072
Vega, Jorge Ruben; Gugliotta, Luis Marcelino; Meira, Gregorio Raul; Emulsion Copolymerization of Acrylonitrile and Butadiene. Semi-Batch Strategies for Controlling Molecular Structure on the Basis of Calorimetric Measurements; Taylor & Francis; Polymer Reaction Engineering; 10; 12-2002; 59-82
1054-3414
CONICET Digital
CONICET
url http://hdl.handle.net/11336/30072
identifier_str_mv Vega, Jorge Ruben; Gugliotta, Luis Marcelino; Meira, Gregorio Raul; Emulsion Copolymerization of Acrylonitrile and Butadiene. Semi-Batch Strategies for Controlling Molecular Structure on the Basis of Calorimetric Measurements; Taylor & Francis; Polymer Reaction Engineering; 10; 12-2002; 59-82
1054-3414
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.tandfonline.com/doi/full/10.1081/PRE-120003922
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Taylor & Francis
publisher.none.fl_str_mv Taylor & Francis
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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