Emulsion Copolymerization of Acrylonitrile and Butadiene. Semi-Batch Strategies for Controlling Molecular Structure on the Basis of Calorimetric Measurements
- Autores
- Vega, Jorge Ruben; Gugliotta, Luis Marcelino; Meira, Gregorio Raul
- Año de publicación
- 2002
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- A semibatch emulsion copolymerization of acrylonitrile and butadiene is theoretically investigated, with the aim of controlling the molecular structure of the produced NBR. An open-loop estimator based on calorimetric measurements is proposed for monitoring the chemical composition, the average molecular weights, and the average degree of branching. With little effect on the other quality variables, the intermediate addition of acrylonitrile allows to produce a polymer with a constant chemical composition. Similarly, the intermediate addition of the chain transfer agent produces a polymer with either a fixed or with a prespecified linear variation of the average branching. The required feed profiles are obtained from a numerical inversion of a discrete process model. By increasing the initiator loads, the semibatch strategies also allow to increase the final conversion between 3% and 6%, without altering the reaction time nor deteriorating the polymer quality with respect to the batch. The numerical procedures were tested by inputing (relatively noisy) heat measurements from an industrial batch reactor.
Fil: Vega, Jorge Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Gugliotta, Luis Marcelino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Meira, Gregorio Raul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/30072
Ver los metadatos del registro completo
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Emulsion Copolymerization of Acrylonitrile and Butadiene. Semi-Batch Strategies for Controlling Molecular Structure on the Basis of Calorimetric MeasurementsVega, Jorge RubenGugliotta, Luis MarcelinoMeira, Gregorio Raulhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2A semibatch emulsion copolymerization of acrylonitrile and butadiene is theoretically investigated, with the aim of controlling the molecular structure of the produced NBR. An open-loop estimator based on calorimetric measurements is proposed for monitoring the chemical composition, the average molecular weights, and the average degree of branching. With little effect on the other quality variables, the intermediate addition of acrylonitrile allows to produce a polymer with a constant chemical composition. Similarly, the intermediate addition of the chain transfer agent produces a polymer with either a fixed or with a prespecified linear variation of the average branching. The required feed profiles are obtained from a numerical inversion of a discrete process model. By increasing the initiator loads, the semibatch strategies also allow to increase the final conversion between 3% and 6%, without altering the reaction time nor deteriorating the polymer quality with respect to the batch. The numerical procedures were tested by inputing (relatively noisy) heat measurements from an industrial batch reactor.Fil: Vega, Jorge Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Gugliotta, Luis Marcelino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Meira, Gregorio Raul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaTaylor & Francis2002-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/30072Vega, Jorge Ruben; Gugliotta, Luis Marcelino; Meira, Gregorio Raul; Emulsion Copolymerization of Acrylonitrile and Butadiene. Semi-Batch Strategies for Controlling Molecular Structure on the Basis of Calorimetric Measurements; Taylor & Francis; Polymer Reaction Engineering; 10; 12-2002; 59-821054-3414CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.tandfonline.com/doi/full/10.1081/PRE-120003922info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:41:00Zoai:ri.conicet.gov.ar:11336/30072instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:41:01.136CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Emulsion Copolymerization of Acrylonitrile and Butadiene. Semi-Batch Strategies for Controlling Molecular Structure on the Basis of Calorimetric Measurements |
title |
Emulsion Copolymerization of Acrylonitrile and Butadiene. Semi-Batch Strategies for Controlling Molecular Structure on the Basis of Calorimetric Measurements |
spellingShingle |
Emulsion Copolymerization of Acrylonitrile and Butadiene. Semi-Batch Strategies for Controlling Molecular Structure on the Basis of Calorimetric Measurements Vega, Jorge Ruben |
title_short |
Emulsion Copolymerization of Acrylonitrile and Butadiene. Semi-Batch Strategies for Controlling Molecular Structure on the Basis of Calorimetric Measurements |
title_full |
Emulsion Copolymerization of Acrylonitrile and Butadiene. Semi-Batch Strategies for Controlling Molecular Structure on the Basis of Calorimetric Measurements |
title_fullStr |
Emulsion Copolymerization of Acrylonitrile and Butadiene. Semi-Batch Strategies for Controlling Molecular Structure on the Basis of Calorimetric Measurements |
title_full_unstemmed |
Emulsion Copolymerization of Acrylonitrile and Butadiene. Semi-Batch Strategies for Controlling Molecular Structure on the Basis of Calorimetric Measurements |
title_sort |
Emulsion Copolymerization of Acrylonitrile and Butadiene. Semi-Batch Strategies for Controlling Molecular Structure on the Basis of Calorimetric Measurements |
dc.creator.none.fl_str_mv |
Vega, Jorge Ruben Gugliotta, Luis Marcelino Meira, Gregorio Raul |
author |
Vega, Jorge Ruben |
author_facet |
Vega, Jorge Ruben Gugliotta, Luis Marcelino Meira, Gregorio Raul |
author_role |
author |
author2 |
Gugliotta, Luis Marcelino Meira, Gregorio Raul |
author2_role |
author author |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
A semibatch emulsion copolymerization of acrylonitrile and butadiene is theoretically investigated, with the aim of controlling the molecular structure of the produced NBR. An open-loop estimator based on calorimetric measurements is proposed for monitoring the chemical composition, the average molecular weights, and the average degree of branching. With little effect on the other quality variables, the intermediate addition of acrylonitrile allows to produce a polymer with a constant chemical composition. Similarly, the intermediate addition of the chain transfer agent produces a polymer with either a fixed or with a prespecified linear variation of the average branching. The required feed profiles are obtained from a numerical inversion of a discrete process model. By increasing the initiator loads, the semibatch strategies also allow to increase the final conversion between 3% and 6%, without altering the reaction time nor deteriorating the polymer quality with respect to the batch. The numerical procedures were tested by inputing (relatively noisy) heat measurements from an industrial batch reactor. Fil: Vega, Jorge Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina Fil: Gugliotta, Luis Marcelino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina Fil: Meira, Gregorio Raul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina |
description |
A semibatch emulsion copolymerization of acrylonitrile and butadiene is theoretically investigated, with the aim of controlling the molecular structure of the produced NBR. An open-loop estimator based on calorimetric measurements is proposed for monitoring the chemical composition, the average molecular weights, and the average degree of branching. With little effect on the other quality variables, the intermediate addition of acrylonitrile allows to produce a polymer with a constant chemical composition. Similarly, the intermediate addition of the chain transfer agent produces a polymer with either a fixed or with a prespecified linear variation of the average branching. The required feed profiles are obtained from a numerical inversion of a discrete process model. By increasing the initiator loads, the semibatch strategies also allow to increase the final conversion between 3% and 6%, without altering the reaction time nor deteriorating the polymer quality with respect to the batch. The numerical procedures were tested by inputing (relatively noisy) heat measurements from an industrial batch reactor. |
publishDate |
2002 |
dc.date.none.fl_str_mv |
2002-12 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/30072 Vega, Jorge Ruben; Gugliotta, Luis Marcelino; Meira, Gregorio Raul; Emulsion Copolymerization of Acrylonitrile and Butadiene. Semi-Batch Strategies for Controlling Molecular Structure on the Basis of Calorimetric Measurements; Taylor & Francis; Polymer Reaction Engineering; 10; 12-2002; 59-82 1054-3414 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/30072 |
identifier_str_mv |
Vega, Jorge Ruben; Gugliotta, Luis Marcelino; Meira, Gregorio Raul; Emulsion Copolymerization of Acrylonitrile and Butadiene. Semi-Batch Strategies for Controlling Molecular Structure on the Basis of Calorimetric Measurements; Taylor & Francis; Polymer Reaction Engineering; 10; 12-2002; 59-82 1054-3414 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://www.tandfonline.com/doi/full/10.1081/PRE-120003922 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Taylor & Francis |
publisher.none.fl_str_mv |
Taylor & Francis |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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13.070432 |