Emulsion Copolymerization of Acrylonitrile and Butadiene in an Industrial Reactor. Mathematical Modelling, Estimation, and Control of Polymer Quality Variables on the Basis of Calo...
- Autores
- Vega, Jorge Ruben; Gugliotta, Luis Marcelino; Meira, Gregorio Raul
- Año de publicación
- 2003
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- An industrial emulsion copolymerization of acrylonitrile and butadiene carried out in a batch (or semibatch) reactor for the production of nitrile rubber (NBR) is investigated. The effect of variable amounts of deactivating impurities on the predictions of a global polymerization model is analyzed; and the advantages of using the model predictions in combination with on-line calorimetric measurements are shown. The adjusted polymerization model allows to adequately monitor main quality variables of the process, such as: monomer conversion, average copolymer composition, average molecular weights, and degree of branching. The semibatch addition of the comonomers and/or the chain transfer agent along the reaction was investigated with the aim of controlling the polymer quality characteristics and increasing the productivity. It is possible to obtain a uniform-composition copolymer with pre-specified profiles of the average molecular weights or the degrees of branching. Furthermore, the NBR productivity can be increased by about 5%, without deteriorating the final copolymer quality with respect to that produced in the more conventional batch operation.
Fil: Vega, Jorge Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Gugliotta, Luis Marcelino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Meira, Gregorio Raul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/28555
Ver los metadatos del registro completo
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Emulsion Copolymerization of Acrylonitrile and Butadiene in an Industrial Reactor. Mathematical Modelling, Estimation, and Control of Polymer Quality Variables on the Basis of Calorimetric MeasurementsVega, Jorge RubenGugliotta, Luis MarcelinoMeira, Gregorio Raulhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2An industrial emulsion copolymerization of acrylonitrile and butadiene carried out in a batch (or semibatch) reactor for the production of nitrile rubber (NBR) is investigated. The effect of variable amounts of deactivating impurities on the predictions of a global polymerization model is analyzed; and the advantages of using the model predictions in combination with on-line calorimetric measurements are shown. The adjusted polymerization model allows to adequately monitor main quality variables of the process, such as: monomer conversion, average copolymer composition, average molecular weights, and degree of branching. The semibatch addition of the comonomers and/or the chain transfer agent along the reaction was investigated with the aim of controlling the polymer quality characteristics and increasing the productivity. It is possible to obtain a uniform-composition copolymer with pre-specified profiles of the average molecular weights or the degrees of branching. Furthermore, the NBR productivity can be increased by about 5%, without deteriorating the final copolymer quality with respect to that produced in the more conventional batch operation.Fil: Vega, Jorge Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Gugliotta, Luis Marcelino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Meira, Gregorio Raul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaPlanta Piloto de Ingeniería Química2003-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/28555Vega, Jorge Ruben; Gugliotta, Luis Marcelino; Meira, Gregorio Raul; Emulsion Copolymerization of Acrylonitrile and Butadiene in an Industrial Reactor. Mathematical Modelling, Estimation, and Control of Polymer Quality Variables on the Basis of Calorimetric Measurements; Planta Piloto de Ingeniería Química; Latin American Applied Research; 33; 2; 5-2003; 115-1220327-07931851-8796CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.laar.uns.edu.ar/indexes/artic_v3302/pag115.pdfinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:39:27Zoai:ri.conicet.gov.ar:11336/28555instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:39:27.408CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Emulsion Copolymerization of Acrylonitrile and Butadiene in an Industrial Reactor. Mathematical Modelling, Estimation, and Control of Polymer Quality Variables on the Basis of Calorimetric Measurements |
title |
Emulsion Copolymerization of Acrylonitrile and Butadiene in an Industrial Reactor. Mathematical Modelling, Estimation, and Control of Polymer Quality Variables on the Basis of Calorimetric Measurements |
spellingShingle |
Emulsion Copolymerization of Acrylonitrile and Butadiene in an Industrial Reactor. Mathematical Modelling, Estimation, and Control of Polymer Quality Variables on the Basis of Calorimetric Measurements Vega, Jorge Ruben |
title_short |
Emulsion Copolymerization of Acrylonitrile and Butadiene in an Industrial Reactor. Mathematical Modelling, Estimation, and Control of Polymer Quality Variables on the Basis of Calorimetric Measurements |
title_full |
Emulsion Copolymerization of Acrylonitrile and Butadiene in an Industrial Reactor. Mathematical Modelling, Estimation, and Control of Polymer Quality Variables on the Basis of Calorimetric Measurements |
title_fullStr |
Emulsion Copolymerization of Acrylonitrile and Butadiene in an Industrial Reactor. Mathematical Modelling, Estimation, and Control of Polymer Quality Variables on the Basis of Calorimetric Measurements |
title_full_unstemmed |
Emulsion Copolymerization of Acrylonitrile and Butadiene in an Industrial Reactor. Mathematical Modelling, Estimation, and Control of Polymer Quality Variables on the Basis of Calorimetric Measurements |
title_sort |
Emulsion Copolymerization of Acrylonitrile and Butadiene in an Industrial Reactor. Mathematical Modelling, Estimation, and Control of Polymer Quality Variables on the Basis of Calorimetric Measurements |
dc.creator.none.fl_str_mv |
Vega, Jorge Ruben Gugliotta, Luis Marcelino Meira, Gregorio Raul |
author |
Vega, Jorge Ruben |
author_facet |
Vega, Jorge Ruben Gugliotta, Luis Marcelino Meira, Gregorio Raul |
author_role |
author |
author2 |
Gugliotta, Luis Marcelino Meira, Gregorio Raul |
author2_role |
author author |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
An industrial emulsion copolymerization of acrylonitrile and butadiene carried out in a batch (or semibatch) reactor for the production of nitrile rubber (NBR) is investigated. The effect of variable amounts of deactivating impurities on the predictions of a global polymerization model is analyzed; and the advantages of using the model predictions in combination with on-line calorimetric measurements are shown. The adjusted polymerization model allows to adequately monitor main quality variables of the process, such as: monomer conversion, average copolymer composition, average molecular weights, and degree of branching. The semibatch addition of the comonomers and/or the chain transfer agent along the reaction was investigated with the aim of controlling the polymer quality characteristics and increasing the productivity. It is possible to obtain a uniform-composition copolymer with pre-specified profiles of the average molecular weights or the degrees of branching. Furthermore, the NBR productivity can be increased by about 5%, without deteriorating the final copolymer quality with respect to that produced in the more conventional batch operation. Fil: Vega, Jorge Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina Fil: Gugliotta, Luis Marcelino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina Fil: Meira, Gregorio Raul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina |
description |
An industrial emulsion copolymerization of acrylonitrile and butadiene carried out in a batch (or semibatch) reactor for the production of nitrile rubber (NBR) is investigated. The effect of variable amounts of deactivating impurities on the predictions of a global polymerization model is analyzed; and the advantages of using the model predictions in combination with on-line calorimetric measurements are shown. The adjusted polymerization model allows to adequately monitor main quality variables of the process, such as: monomer conversion, average copolymer composition, average molecular weights, and degree of branching. The semibatch addition of the comonomers and/or the chain transfer agent along the reaction was investigated with the aim of controlling the polymer quality characteristics and increasing the productivity. It is possible to obtain a uniform-composition copolymer with pre-specified profiles of the average molecular weights or the degrees of branching. Furthermore, the NBR productivity can be increased by about 5%, without deteriorating the final copolymer quality with respect to that produced in the more conventional batch operation. |
publishDate |
2003 |
dc.date.none.fl_str_mv |
2003-05 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/28555 Vega, Jorge Ruben; Gugliotta, Luis Marcelino; Meira, Gregorio Raul; Emulsion Copolymerization of Acrylonitrile and Butadiene in an Industrial Reactor. Mathematical Modelling, Estimation, and Control of Polymer Quality Variables on the Basis of Calorimetric Measurements; Planta Piloto de Ingeniería Química; Latin American Applied Research; 33; 2; 5-2003; 115-122 0327-0793 1851-8796 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/28555 |
identifier_str_mv |
Vega, Jorge Ruben; Gugliotta, Luis Marcelino; Meira, Gregorio Raul; Emulsion Copolymerization of Acrylonitrile and Butadiene in an Industrial Reactor. Mathematical Modelling, Estimation, and Control of Polymer Quality Variables on the Basis of Calorimetric Measurements; Planta Piloto de Ingeniería Química; Latin American Applied Research; 33; 2; 5-2003; 115-122 0327-0793 1851-8796 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://www.laar.uns.edu.ar/indexes/artic_v3302/pag115.pdf |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Planta Piloto de Ingeniería Química |
publisher.none.fl_str_mv |
Planta Piloto de Ingeniería Química |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613248206241792 |
score |
13.070432 |