Nanoreinforcement as a strategy to improve physical properties of biodegradable composite films based on biopolymers

Autores
Hoyos Merlano, Nurys Tatiana; Borroni, Maria Virginia; Rodríguez Batiller, María Jose; Candal, Roberto Jorge; Herrera, Maria Lidia
Año de publicación
2022
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Food packaging is evolving from inert plastic to renewable biopolymer film that acts as barrier against gases, light radiation, and microorganisms, reducing food waste without environmental damage. Distinct starting systems were selected to prepare films: single polymer matrix, blend of polymers, cross-linked polymers, and emulsion-based matrix. The blend of polymers was one of the best approaches to improve mechanical and barrier properties of films, especially when one of the polymers was pectin, gelatin or xanthan gum. These polymers can form a gel and increase the viscosity of the starting systems leading to a more elastic matrix. Although some of these films showed potential to replace plastic materials, their physical properties were poor compared to plastics. Thus, several strategies were used to strengthen matrix building block connections or interactions between nanoreiforcement and matrix compounds with the aim of improving physical properties. Among metal oxides, TiO2, ZnO, CaO, and MgO were the most studied, alone or in combinations with other reinforcements. Natural fillers, like chitosan and cellulose nanofibers were also added to improve the biopolymer's performance. Several of these systems successfully extended the shelf life of food systems by retarding spoilage, showing great potential to improve food quality and reduce waste. However, most of the studies were carried out on a laboratory scale and it would be necessary to explore the feasibility of producing these films on an industrial scale.
Fil: Hoyos Merlano, Nurys Tatiana. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina
Fil: Borroni, Maria Virginia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina
Fil: Rodríguez Batiller, María Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina
Fil: Candal, Roberto Jorge. Universidad Nacional de San Martín. Instituto de Investigación en Ingeniería Ambiental; Argentina. Universidad Nacional de San Martín. Instituto de Investigación e Ingeniería Ambiental. - Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Instituto de Investigación e Ingeniería Ambiental; Argentina
Fil: Herrera, Maria Lidia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina
Materia
CROSS-LINKING
FILMS
MATRIX
METAL OXIDES
NANOLOAD
NATURAL FILLERS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/204227

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network_name_str CONICET Digital (CONICET)
spelling Nanoreinforcement as a strategy to improve physical properties of biodegradable composite films based on biopolymersHoyos Merlano, Nurys TatianaBorroni, Maria VirginiaRodríguez Batiller, María JoseCandal, Roberto JorgeHerrera, Maria LidiaCROSS-LINKINGFILMSMATRIXMETAL OXIDESNANOLOADNATURAL FILLERShttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2Food packaging is evolving from inert plastic to renewable biopolymer film that acts as barrier against gases, light radiation, and microorganisms, reducing food waste without environmental damage. Distinct starting systems were selected to prepare films: single polymer matrix, blend of polymers, cross-linked polymers, and emulsion-based matrix. The blend of polymers was one of the best approaches to improve mechanical and barrier properties of films, especially when one of the polymers was pectin, gelatin or xanthan gum. These polymers can form a gel and increase the viscosity of the starting systems leading to a more elastic matrix. Although some of these films showed potential to replace plastic materials, their physical properties were poor compared to plastics. Thus, several strategies were used to strengthen matrix building block connections or interactions between nanoreiforcement and matrix compounds with the aim of improving physical properties. Among metal oxides, TiO2, ZnO, CaO, and MgO were the most studied, alone or in combinations with other reinforcements. Natural fillers, like chitosan and cellulose nanofibers were also added to improve the biopolymer's performance. Several of these systems successfully extended the shelf life of food systems by retarding spoilage, showing great potential to improve food quality and reduce waste. However, most of the studies were carried out on a laboratory scale and it would be necessary to explore the feasibility of producing these films on an industrial scale.Fil: Hoyos Merlano, Nurys Tatiana. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; ArgentinaFil: Borroni, Maria Virginia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; ArgentinaFil: Rodríguez Batiller, María Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; ArgentinaFil: Candal, Roberto Jorge. Universidad Nacional de San Martín. Instituto de Investigación en Ingeniería Ambiental; Argentina. Universidad Nacional de San Martín. Instituto de Investigación e Ingeniería Ambiental. - Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Instituto de Investigación e Ingeniería Ambiental; ArgentinaFil: Herrera, Maria Lidia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; ArgentinaElsevier Science2022-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/204227Hoyos Merlano, Nurys Tatiana; Borroni, Maria Virginia; Rodríguez Batiller, María Jose; Candal, Roberto Jorge; Herrera, Maria Lidia; Nanoreinforcement as a strategy to improve physical properties of biodegradable composite films based on biopolymers; Elsevier Science; Food Research International; 162; 112178; 12-2022; 1-530963-9969CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0963996922012364info:eu-repo/semantics/altIdentifier/doi/10.1016/j.foodres.2022.112178info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:42:23Zoai:ri.conicet.gov.ar:11336/204227instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:42:23.386CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Nanoreinforcement as a strategy to improve physical properties of biodegradable composite films based on biopolymers
title Nanoreinforcement as a strategy to improve physical properties of biodegradable composite films based on biopolymers
spellingShingle Nanoreinforcement as a strategy to improve physical properties of biodegradable composite films based on biopolymers
Hoyos Merlano, Nurys Tatiana
CROSS-LINKING
FILMS
MATRIX
METAL OXIDES
NANOLOAD
NATURAL FILLERS
title_short Nanoreinforcement as a strategy to improve physical properties of biodegradable composite films based on biopolymers
title_full Nanoreinforcement as a strategy to improve physical properties of biodegradable composite films based on biopolymers
title_fullStr Nanoreinforcement as a strategy to improve physical properties of biodegradable composite films based on biopolymers
title_full_unstemmed Nanoreinforcement as a strategy to improve physical properties of biodegradable composite films based on biopolymers
title_sort Nanoreinforcement as a strategy to improve physical properties of biodegradable composite films based on biopolymers
dc.creator.none.fl_str_mv Hoyos Merlano, Nurys Tatiana
Borroni, Maria Virginia
Rodríguez Batiller, María Jose
Candal, Roberto Jorge
Herrera, Maria Lidia
author Hoyos Merlano, Nurys Tatiana
author_facet Hoyos Merlano, Nurys Tatiana
Borroni, Maria Virginia
Rodríguez Batiller, María Jose
Candal, Roberto Jorge
Herrera, Maria Lidia
author_role author
author2 Borroni, Maria Virginia
Rodríguez Batiller, María Jose
Candal, Roberto Jorge
Herrera, Maria Lidia
author2_role author
author
author
author
dc.subject.none.fl_str_mv CROSS-LINKING
FILMS
MATRIX
METAL OXIDES
NANOLOAD
NATURAL FILLERS
topic CROSS-LINKING
FILMS
MATRIX
METAL OXIDES
NANOLOAD
NATURAL FILLERS
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Food packaging is evolving from inert plastic to renewable biopolymer film that acts as barrier against gases, light radiation, and microorganisms, reducing food waste without environmental damage. Distinct starting systems were selected to prepare films: single polymer matrix, blend of polymers, cross-linked polymers, and emulsion-based matrix. The blend of polymers was one of the best approaches to improve mechanical and barrier properties of films, especially when one of the polymers was pectin, gelatin or xanthan gum. These polymers can form a gel and increase the viscosity of the starting systems leading to a more elastic matrix. Although some of these films showed potential to replace plastic materials, their physical properties were poor compared to plastics. Thus, several strategies were used to strengthen matrix building block connections or interactions between nanoreiforcement and matrix compounds with the aim of improving physical properties. Among metal oxides, TiO2, ZnO, CaO, and MgO were the most studied, alone or in combinations with other reinforcements. Natural fillers, like chitosan and cellulose nanofibers were also added to improve the biopolymer's performance. Several of these systems successfully extended the shelf life of food systems by retarding spoilage, showing great potential to improve food quality and reduce waste. However, most of the studies were carried out on a laboratory scale and it would be necessary to explore the feasibility of producing these films on an industrial scale.
Fil: Hoyos Merlano, Nurys Tatiana. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina
Fil: Borroni, Maria Virginia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina
Fil: Rodríguez Batiller, María Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina
Fil: Candal, Roberto Jorge. Universidad Nacional de San Martín. Instituto de Investigación en Ingeniería Ambiental; Argentina. Universidad Nacional de San Martín. Instituto de Investigación e Ingeniería Ambiental. - Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Parque Centenario. Instituto de Investigación e Ingeniería Ambiental; Argentina
Fil: Herrera, Maria Lidia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina
description Food packaging is evolving from inert plastic to renewable biopolymer film that acts as barrier against gases, light radiation, and microorganisms, reducing food waste without environmental damage. Distinct starting systems were selected to prepare films: single polymer matrix, blend of polymers, cross-linked polymers, and emulsion-based matrix. The blend of polymers was one of the best approaches to improve mechanical and barrier properties of films, especially when one of the polymers was pectin, gelatin or xanthan gum. These polymers can form a gel and increase the viscosity of the starting systems leading to a more elastic matrix. Although some of these films showed potential to replace plastic materials, their physical properties were poor compared to plastics. Thus, several strategies were used to strengthen matrix building block connections or interactions between nanoreiforcement and matrix compounds with the aim of improving physical properties. Among metal oxides, TiO2, ZnO, CaO, and MgO were the most studied, alone or in combinations with other reinforcements. Natural fillers, like chitosan and cellulose nanofibers were also added to improve the biopolymer's performance. Several of these systems successfully extended the shelf life of food systems by retarding spoilage, showing great potential to improve food quality and reduce waste. However, most of the studies were carried out on a laboratory scale and it would be necessary to explore the feasibility of producing these films on an industrial scale.
publishDate 2022
dc.date.none.fl_str_mv 2022-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/204227
Hoyos Merlano, Nurys Tatiana; Borroni, Maria Virginia; Rodríguez Batiller, María Jose; Candal, Roberto Jorge; Herrera, Maria Lidia; Nanoreinforcement as a strategy to improve physical properties of biodegradable composite films based on biopolymers; Elsevier Science; Food Research International; 162; 112178; 12-2022; 1-53
0963-9969
CONICET Digital
CONICET
url http://hdl.handle.net/11336/204227
identifier_str_mv Hoyos Merlano, Nurys Tatiana; Borroni, Maria Virginia; Rodríguez Batiller, María Jose; Candal, Roberto Jorge; Herrera, Maria Lidia; Nanoreinforcement as a strategy to improve physical properties of biodegradable composite films based on biopolymers; Elsevier Science; Food Research International; 162; 112178; 12-2022; 1-53
0963-9969
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0963996922012364
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.foodres.2022.112178
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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