Physicochemical properties of films based on bovine gelatin cross-linked with 1,4-butanediol diglycidyl ether

Autores
Martucci, Josefa Fabiana; Espinosa, Juan Pablo; Ruseckaite, Roxana Alejandra
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The effectiveness of 1,4-butanediol diglycidyl ether (BDDGE) as a cross-linking agent of bovine gelatin films plasticized with D-sorbitol intended for food packaging is reported. Free-standing films were produced by casting gelatin film-forming solutions containing D-soritol 30 % (g/100 g dry gelatin) and variable amounts of BDDGE (0?3 g/100 g dry gelatin). The addition of 1 % BDDGE (g/100 g dry gelatin) positively influenced the solubility, water vapor permeability, and mechanical properties of the produced films. Water solubility decreased about 77 %; the water vapor permeability enhanced 20 %, and the stretching ability increased 11 times while the tensile strength was reduced up to 7-fold with regard to the non-cross-linked counterpart. A simple extraction procedure was applied to remove the potential un-reacted BDDGE and its hydrolysis products from BDDGE-treated gelatin films. Quantification was performed by gas chromatography combined with mass spectrometry (GC/MS), being lower than 0.25 μg/kg (below the limit of detection, 0.30 μg/L). Results suggested that water-soluble BDDGE may provide an effective cross-linking alternative to the usual aldehyde-based strategy to manufacture gelatin films with potential use as biodegradable food packaging materials.
Fil: Martucci, Josefa Fabiana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Espinosa, Juan Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Ruseckaite, Roxana Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Materia
Gelatin Films
1,4-Butanediol Diglycidyl Ether
Cross-Linking
Functional Properties
Quantification of Residual Cross-Linking Agent
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/10123
Acceder
id CONICETDig_6ff085c8aac48c260320adb35368e171
oai_identifier_str oai:ri.conicet.gov.ar:11336/10123
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Physicochemical properties of films based on bovine gelatin cross-linked with 1,4-butanediol diglycidyl etherMartucci, Josefa FabianaEspinosa, Juan PabloRuseckaite, Roxana AlejandraGelatin Films1,4-Butanediol Diglycidyl EtherCross-LinkingFunctional PropertiesQuantification of Residual Cross-Linking Agenthttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The effectiveness of 1,4-butanediol diglycidyl ether (BDDGE) as a cross-linking agent of bovine gelatin films plasticized with D-sorbitol intended for food packaging is reported. Free-standing films were produced by casting gelatin film-forming solutions containing D-soritol 30 % (g/100 g dry gelatin) and variable amounts of BDDGE (0?3 g/100 g dry gelatin). The addition of 1 % BDDGE (g/100 g dry gelatin) positively influenced the solubility, water vapor permeability, and mechanical properties of the produced films. Water solubility decreased about 77 %; the water vapor permeability enhanced 20 %, and the stretching ability increased 11 times while the tensile strength was reduced up to 7-fold with regard to the non-cross-linked counterpart. A simple extraction procedure was applied to remove the potential un-reacted BDDGE and its hydrolysis products from BDDGE-treated gelatin films. Quantification was performed by gas chromatography combined with mass spectrometry (GC/MS), being lower than 0.25 μg/kg (below the limit of detection, 0.30 μg/L). Results suggested that water-soluble BDDGE may provide an effective cross-linking alternative to the usual aldehyde-based strategy to manufacture gelatin films with potential use as biodegradable food packaging materials.Fil: Martucci, Josefa Fabiana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Espinosa, Juan Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaFil: Ruseckaite, Roxana Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; ArgentinaSpringer2015-04-21info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/10123Martucci, Josefa Fabiana; Espinosa, Juan Pablo; Ruseckaite, Roxana Alejandra; Physicochemical properties of films based on bovine gelatin cross-linked with 1,4-butanediol diglycidyl ether; Springer; Food And Bioprocess Technology; 8; 8; 21-4-2015; 1645-16561935-5130enginfo:eu-repo/semantics/altIdentifier/url/http://link.springer.com/article/10.1007/s11947-015-1524-xinfo:eu-repo/semantics/altIdentifier/doi/10.1007/s11947-015-1524-xinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:55:50Zoai:ri.conicet.gov.ar:11336/10123instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:55:50.851CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Physicochemical properties of films based on bovine gelatin cross-linked with 1,4-butanediol diglycidyl ether
title Physicochemical properties of films based on bovine gelatin cross-linked with 1,4-butanediol diglycidyl ether
spellingShingle Physicochemical properties of films based on bovine gelatin cross-linked with 1,4-butanediol diglycidyl ether
Martucci, Josefa Fabiana
Gelatin Films
1,4-Butanediol Diglycidyl Ether
Cross-Linking
Functional Properties
Quantification of Residual Cross-Linking Agent
title_short Physicochemical properties of films based on bovine gelatin cross-linked with 1,4-butanediol diglycidyl ether
title_full Physicochemical properties of films based on bovine gelatin cross-linked with 1,4-butanediol diglycidyl ether
title_fullStr Physicochemical properties of films based on bovine gelatin cross-linked with 1,4-butanediol diglycidyl ether
title_full_unstemmed Physicochemical properties of films based on bovine gelatin cross-linked with 1,4-butanediol diglycidyl ether
title_sort Physicochemical properties of films based on bovine gelatin cross-linked with 1,4-butanediol diglycidyl ether
dc.creator.none.fl_str_mv Martucci, Josefa Fabiana
Espinosa, Juan Pablo
Ruseckaite, Roxana Alejandra
author Martucci, Josefa Fabiana
author_facet Martucci, Josefa Fabiana
Espinosa, Juan Pablo
Ruseckaite, Roxana Alejandra
author_role author
author2 Espinosa, Juan Pablo
Ruseckaite, Roxana Alejandra
author2_role author
author
dc.subject.none.fl_str_mv Gelatin Films
1,4-Butanediol Diglycidyl Ether
Cross-Linking
Functional Properties
Quantification of Residual Cross-Linking Agent
topic Gelatin Films
1,4-Butanediol Diglycidyl Ether
Cross-Linking
Functional Properties
Quantification of Residual Cross-Linking Agent
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The effectiveness of 1,4-butanediol diglycidyl ether (BDDGE) as a cross-linking agent of bovine gelatin films plasticized with D-sorbitol intended for food packaging is reported. Free-standing films were produced by casting gelatin film-forming solutions containing D-soritol 30 % (g/100 g dry gelatin) and variable amounts of BDDGE (0?3 g/100 g dry gelatin). The addition of 1 % BDDGE (g/100 g dry gelatin) positively influenced the solubility, water vapor permeability, and mechanical properties of the produced films. Water solubility decreased about 77 %; the water vapor permeability enhanced 20 %, and the stretching ability increased 11 times while the tensile strength was reduced up to 7-fold with regard to the non-cross-linked counterpart. A simple extraction procedure was applied to remove the potential un-reacted BDDGE and its hydrolysis products from BDDGE-treated gelatin films. Quantification was performed by gas chromatography combined with mass spectrometry (GC/MS), being lower than 0.25 μg/kg (below the limit of detection, 0.30 μg/L). Results suggested that water-soluble BDDGE may provide an effective cross-linking alternative to the usual aldehyde-based strategy to manufacture gelatin films with potential use as biodegradable food packaging materials.
Fil: Martucci, Josefa Fabiana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Espinosa, Juan Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
Fil: Ruseckaite, Roxana Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación En Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingeniería; Argentina
description The effectiveness of 1,4-butanediol diglycidyl ether (BDDGE) as a cross-linking agent of bovine gelatin films plasticized with D-sorbitol intended for food packaging is reported. Free-standing films were produced by casting gelatin film-forming solutions containing D-soritol 30 % (g/100 g dry gelatin) and variable amounts of BDDGE (0?3 g/100 g dry gelatin). The addition of 1 % BDDGE (g/100 g dry gelatin) positively influenced the solubility, water vapor permeability, and mechanical properties of the produced films. Water solubility decreased about 77 %; the water vapor permeability enhanced 20 %, and the stretching ability increased 11 times while the tensile strength was reduced up to 7-fold with regard to the non-cross-linked counterpart. A simple extraction procedure was applied to remove the potential un-reacted BDDGE and its hydrolysis products from BDDGE-treated gelatin films. Quantification was performed by gas chromatography combined with mass spectrometry (GC/MS), being lower than 0.25 μg/kg (below the limit of detection, 0.30 μg/L). Results suggested that water-soluble BDDGE may provide an effective cross-linking alternative to the usual aldehyde-based strategy to manufacture gelatin films with potential use as biodegradable food packaging materials.
publishDate 2015
dc.date.none.fl_str_mv 2015-04-21
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/10123
Martucci, Josefa Fabiana; Espinosa, Juan Pablo; Ruseckaite, Roxana Alejandra; Physicochemical properties of films based on bovine gelatin cross-linked with 1,4-butanediol diglycidyl ether; Springer; Food And Bioprocess Technology; 8; 8; 21-4-2015; 1645-1656
1935-5130
url http://hdl.handle.net/11336/10123
identifier_str_mv Martucci, Josefa Fabiana; Espinosa, Juan Pablo; Ruseckaite, Roxana Alejandra; Physicochemical properties of films based on bovine gelatin cross-linked with 1,4-butanediol diglycidyl ether; Springer; Food And Bioprocess Technology; 8; 8; 21-4-2015; 1645-1656
1935-5130
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://link.springer.com/article/10.1007/s11947-015-1524-x
info:eu-repo/semantics/altIdentifier/doi/10.1007/s11947-015-1524-x
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Springer
publisher.none.fl_str_mv Springer
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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