A new transition metal-tellurite glass family: electrical and structural properties

Autores
Terny, Cintia Soledad; De la Rubia, M.; de Frutos, José; Frechero, Marisa Alejandra
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Glasses of composition 0.8 [xBaO.(1 - x)MgO]. 0.2TM.2TeO2 with TM: MoO3, WO3, V2O5 or Nb2O5 (x = mol content) were obtained by the melt quenching technique. Raman Spectroscopy, Density and Differential Scanning Calorimetry were used to infer their microscopic structure and electrical properties were studied using Impedance Spectroscopy. Some singularities in their electrical and structural properties appeared. Deviations from linearity as a function of alkaline-earth oxide modifier content were observed both on the electrical and structural properties. They were analyzed considering the intensity of the electrical field of the mix of alkaline earth cations which induced changes on the glassy matrix and the mixed alkaline-earth effect was considered. The observed relationships between their electrical and structural properties and the mix of alkaline earth cations were different according to the transition metal oxide present.
Fil: Terny, Cintia Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; Argentina
Fil: De la Rubia, M.. Universidad Politecnica de Madrid; España
Fil: de Frutos, José. Universidad Politecnica de Madrid; España
Fil: Frechero, Marisa Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; Argentina
Materia
Amoorphous Materials
Impedance Spectroscopy
Raman Spectroscopy
Ionic Conductivity
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/4709
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/4709
network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling A new transition metal-tellurite glass family: electrical and structural propertiesTerny, Cintia SoledadDe la Rubia, M.de Frutos, JoséFrechero, Marisa AlejandraAmoorphous MaterialsImpedance SpectroscopyRaman SpectroscopyIonic Conductivityhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1Glasses of composition 0.8 [xBaO.(1 - x)MgO]. 0.2TM.2TeO2 with TM: MoO3, WO3, V2O5 or Nb2O5 (x = mol content) were obtained by the melt quenching technique. Raman Spectroscopy, Density and Differential Scanning Calorimetry were used to infer their microscopic structure and electrical properties were studied using Impedance Spectroscopy. Some singularities in their electrical and structural properties appeared. Deviations from linearity as a function of alkaline-earth oxide modifier content were observed both on the electrical and structural properties. They were analyzed considering the intensity of the electrical field of the mix of alkaline earth cations which induced changes on the glassy matrix and the mixed alkaline-earth effect was considered. The observed relationships between their electrical and structural properties and the mix of alkaline earth cations were different according to the transition metal oxide present.Fil: Terny, Cintia Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; ArgentinaFil: De la Rubia, M.. Universidad Politecnica de Madrid; EspañaFil: de Frutos, José. Universidad Politecnica de Madrid; EspañaFil: Frechero, Marisa Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; ArgentinaElsevier Science2015-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/4709Terny, Cintia Soledad; De la Rubia, M.; de Frutos, José; Frechero, Marisa Alejandra; A new transition metal-tellurite glass family: electrical and structural properties; Elsevier Science; Journal Of Non-crystalline Solids; 433; 12-2015; 68–740022-3093enginfo:eu-repo/semantics/altIdentifier/doi/doi:10.1016/j.jnoncrysol.2015.11.030info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0022309315302763info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:39:39Zoai:ri.conicet.gov.ar:11336/4709instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:39:40.014CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv A new transition metal-tellurite glass family: electrical and structural properties
title A new transition metal-tellurite glass family: electrical and structural properties
spellingShingle A new transition metal-tellurite glass family: electrical and structural properties
Terny, Cintia Soledad
Amoorphous Materials
Impedance Spectroscopy
Raman Spectroscopy
Ionic Conductivity
title_short A new transition metal-tellurite glass family: electrical and structural properties
title_full A new transition metal-tellurite glass family: electrical and structural properties
title_fullStr A new transition metal-tellurite glass family: electrical and structural properties
title_full_unstemmed A new transition metal-tellurite glass family: electrical and structural properties
title_sort A new transition metal-tellurite glass family: electrical and structural properties
dc.creator.none.fl_str_mv Terny, Cintia Soledad
De la Rubia, M.
de Frutos, José
Frechero, Marisa Alejandra
author Terny, Cintia Soledad
author_facet Terny, Cintia Soledad
De la Rubia, M.
de Frutos, José
Frechero, Marisa Alejandra
author_role author
author2 De la Rubia, M.
de Frutos, José
Frechero, Marisa Alejandra
author2_role author
author
author
dc.subject.none.fl_str_mv Amoorphous Materials
Impedance Spectroscopy
Raman Spectroscopy
Ionic Conductivity
topic Amoorphous Materials
Impedance Spectroscopy
Raman Spectroscopy
Ionic Conductivity
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Glasses of composition 0.8 [xBaO.(1 - x)MgO]. 0.2TM.2TeO2 with TM: MoO3, WO3, V2O5 or Nb2O5 (x = mol content) were obtained by the melt quenching technique. Raman Spectroscopy, Density and Differential Scanning Calorimetry were used to infer their microscopic structure and electrical properties were studied using Impedance Spectroscopy. Some singularities in their electrical and structural properties appeared. Deviations from linearity as a function of alkaline-earth oxide modifier content were observed both on the electrical and structural properties. They were analyzed considering the intensity of the electrical field of the mix of alkaline earth cations which induced changes on the glassy matrix and the mixed alkaline-earth effect was considered. The observed relationships between their electrical and structural properties and the mix of alkaline earth cations were different according to the transition metal oxide present.
Fil: Terny, Cintia Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; Argentina
Fil: De la Rubia, M.. Universidad Politecnica de Madrid; España
Fil: de Frutos, José. Universidad Politecnica de Madrid; España
Fil: Frechero, Marisa Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; Argentina
description Glasses of composition 0.8 [xBaO.(1 - x)MgO]. 0.2TM.2TeO2 with TM: MoO3, WO3, V2O5 or Nb2O5 (x = mol content) were obtained by the melt quenching technique. Raman Spectroscopy, Density and Differential Scanning Calorimetry were used to infer their microscopic structure and electrical properties were studied using Impedance Spectroscopy. Some singularities in their electrical and structural properties appeared. Deviations from linearity as a function of alkaline-earth oxide modifier content were observed both on the electrical and structural properties. They were analyzed considering the intensity of the electrical field of the mix of alkaline earth cations which induced changes on the glassy matrix and the mixed alkaline-earth effect was considered. The observed relationships between their electrical and structural properties and the mix of alkaline earth cations were different according to the transition metal oxide present.
publishDate 2015
dc.date.none.fl_str_mv 2015-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/4709
Terny, Cintia Soledad; De la Rubia, M.; de Frutos, José; Frechero, Marisa Alejandra; A new transition metal-tellurite glass family: electrical and structural properties; Elsevier Science; Journal Of Non-crystalline Solids; 433; 12-2015; 68–74
0022-3093
url http://hdl.handle.net/11336/4709
identifier_str_mv Terny, Cintia Soledad; De la Rubia, M.; de Frutos, José; Frechero, Marisa Alejandra; A new transition metal-tellurite glass family: electrical and structural properties; Elsevier Science; Journal Of Non-crystalline Solids; 433; 12-2015; 68–74
0022-3093
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/doi:10.1016/j.jnoncrysol.2015.11.030
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0022309315302763
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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