Structure and electrical behavior relationship of a magnesium-tellurite glass using Raman and impedance spectroscopy

Autores
Terny, S.; De la Rubia, M. A.; Alonso, R. E.; de Frutos, J.; Frechero, Marisa Alejandra
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this paper we present the study of the glassy systems of formula: xMgO(1 − x)(0.5V 2 O 5 ·0.5MoO 3 )2TeO 2 , with (0 b x b 1). The aim of the work is to understand the relationship between in the induced changes in the glassy matrix by the incorporation of MgO in a vanadium?tellurite glass and the electrical response of the material. It has been found that the incorporation of MgO in the glassy matrix raises the glass transition temperature. The whole system´s electrical behavior is explained by the small polaron hopping, in good agreement with the vari- able range polaron hopping model. In this matrix, an ionic transport by Mg 2+ is not allowed. The study gives an opportunity to understand how to tune in the middle-range glassy structural order and, as a direct implication, how to control the electrical conduction process.
Fil: Terny, S.. Universidad Politecnica de Madrid; España. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Instituto de Física La Plata; Argentina
Fil: De la Rubia, M. A.. Universidad Politecnica de Madrid; España
Fil: Alonso, R. E.. Universidad Politecnica de Madrid; España
Fil: de Frutos, J.. Universidad Politecnica de Madrid; España
Fil: Frechero, Marisa Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; Argentina
Materia
Tellurite Glasses
Raman Spectroscopy
Impedance Spectroscopy
Polaron Hopping
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/4711
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/4711
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Structure and electrical behavior relationship of a magnesium-tellurite glass using Raman and impedance spectroscopyTerny, S.De la Rubia, M. A.Alonso, R. E.de Frutos, J.Frechero, Marisa AlejandraTellurite GlassesRaman SpectroscopyImpedance SpectroscopyPolaron Hoppinghttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1In this paper we present the study of the glassy systems of formula: xMgO(1 − x)(0.5V 2 O 5 ·0.5MoO 3 )2TeO 2 , with (0 b x b 1). The aim of the work is to understand the relationship between in the induced changes in the glassy matrix by the incorporation of MgO in a vanadium?tellurite glass and the electrical response of the material. It has been found that the incorporation of MgO in the glassy matrix raises the glass transition temperature. The whole system´s electrical behavior is explained by the small polaron hopping, in good agreement with the vari- able range polaron hopping model. In this matrix, an ionic transport by Mg 2+ is not allowed. The study gives an opportunity to understand how to tune in the middle-range glassy structural order and, as a direct implication, how to control the electrical conduction process.Fil: Terny, S.. Universidad Politecnica de Madrid; España. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Instituto de Física La Plata; ArgentinaFil: De la Rubia, M. A.. Universidad Politecnica de Madrid; EspañaFil: Alonso, R. E.. Universidad Politecnica de Madrid; EspañaFil: de Frutos, J.. Universidad Politecnica de Madrid; EspañaFil: Frechero, Marisa Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; ArgentinaElsevier Science2015-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/4711Terny, S.; De la Rubia, M. A.; Alonso, R. E.; de Frutos, J.; Frechero, Marisa Alejandra; Structure and electrical behavior relationship of a magnesium-tellurite glass using Raman and impedance spectroscopy; Elsevier Science; Journal Of Non-crystalline Solids; 411; 1-2015; 13-180022-3093enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0022309314006668info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jnoncrysol.2014.12.026info:eu-repo/semantics/altIdentifier/issn/0022-3093info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:44:58Zoai:ri.conicet.gov.ar:11336/4711instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:44:58.707CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Structure and electrical behavior relationship of a magnesium-tellurite glass using Raman and impedance spectroscopy
title Structure and electrical behavior relationship of a magnesium-tellurite glass using Raman and impedance spectroscopy
spellingShingle Structure and electrical behavior relationship of a magnesium-tellurite glass using Raman and impedance spectroscopy
Terny, S.
Tellurite Glasses
Raman Spectroscopy
Impedance Spectroscopy
Polaron Hopping
title_short Structure and electrical behavior relationship of a magnesium-tellurite glass using Raman and impedance spectroscopy
title_full Structure and electrical behavior relationship of a magnesium-tellurite glass using Raman and impedance spectroscopy
title_fullStr Structure and electrical behavior relationship of a magnesium-tellurite glass using Raman and impedance spectroscopy
title_full_unstemmed Structure and electrical behavior relationship of a magnesium-tellurite glass using Raman and impedance spectroscopy
title_sort Structure and electrical behavior relationship of a magnesium-tellurite glass using Raman and impedance spectroscopy
dc.creator.none.fl_str_mv Terny, S.
De la Rubia, M. A.
Alonso, R. E.
de Frutos, J.
Frechero, Marisa Alejandra
author Terny, S.
author_facet Terny, S.
De la Rubia, M. A.
Alonso, R. E.
de Frutos, J.
Frechero, Marisa Alejandra
author_role author
author2 De la Rubia, M. A.
Alonso, R. E.
de Frutos, J.
Frechero, Marisa Alejandra
author2_role author
author
author
author
dc.subject.none.fl_str_mv Tellurite Glasses
Raman Spectroscopy
Impedance Spectroscopy
Polaron Hopping
topic Tellurite Glasses
Raman Spectroscopy
Impedance Spectroscopy
Polaron Hopping
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv In this paper we present the study of the glassy systems of formula: xMgO(1 − x)(0.5V 2 O 5 ·0.5MoO 3 )2TeO 2 , with (0 b x b 1). The aim of the work is to understand the relationship between in the induced changes in the glassy matrix by the incorporation of MgO in a vanadium?tellurite glass and the electrical response of the material. It has been found that the incorporation of MgO in the glassy matrix raises the glass transition temperature. The whole system´s electrical behavior is explained by the small polaron hopping, in good agreement with the vari- able range polaron hopping model. In this matrix, an ionic transport by Mg 2+ is not allowed. The study gives an opportunity to understand how to tune in the middle-range glassy structural order and, as a direct implication, how to control the electrical conduction process.
Fil: Terny, S.. Universidad Politecnica de Madrid; España. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico La Plata. Instituto de Física La Plata; Argentina
Fil: De la Rubia, M. A.. Universidad Politecnica de Madrid; España
Fil: Alonso, R. E.. Universidad Politecnica de Madrid; España
Fil: de Frutos, J.. Universidad Politecnica de Madrid; España
Fil: Frechero, Marisa Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; Argentina
description In this paper we present the study of the glassy systems of formula: xMgO(1 − x)(0.5V 2 O 5 ·0.5MoO 3 )2TeO 2 , with (0 b x b 1). The aim of the work is to understand the relationship between in the induced changes in the glassy matrix by the incorporation of MgO in a vanadium?tellurite glass and the electrical response of the material. It has been found that the incorporation of MgO in the glassy matrix raises the glass transition temperature. The whole system´s electrical behavior is explained by the small polaron hopping, in good agreement with the vari- able range polaron hopping model. In this matrix, an ionic transport by Mg 2+ is not allowed. The study gives an opportunity to understand how to tune in the middle-range glassy structural order and, as a direct implication, how to control the electrical conduction process.
publishDate 2015
dc.date.none.fl_str_mv 2015-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/4711
Terny, S.; De la Rubia, M. A.; Alonso, R. E.; de Frutos, J.; Frechero, Marisa Alejandra; Structure and electrical behavior relationship of a magnesium-tellurite glass using Raman and impedance spectroscopy; Elsevier Science; Journal Of Non-crystalline Solids; 411; 1-2015; 13-18
0022-3093
url http://hdl.handle.net/11336/4711
identifier_str_mv Terny, S.; De la Rubia, M. A.; Alonso, R. E.; de Frutos, J.; Frechero, Marisa Alejandra; Structure and electrical behavior relationship of a magnesium-tellurite glass using Raman and impedance spectroscopy; Elsevier Science; Journal Of Non-crystalline Solids; 411; 1-2015; 13-18
0022-3093
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0022309314006668
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jnoncrysol.2014.12.026
info:eu-repo/semantics/altIdentifier/issn/0022-3093
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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