Determination of Nanoscale Mechanical Properties of Polymers via Plasmonic Nanoantennas

Autores
Boggiano, Hilario Daniel; Berté, Rodrigo; Scarpettini, Alberto Franco; Cortés, Emiliano; Maier, Stefan A.; Bragas, Andrea Veronica
Año de publicación
2020
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Nanotechnology and the consequent emergence of miniaturized devices are driving the need to improve our understanding of the mechanical properties of a myriad of materials. Here we focus on amorphous polymeric materials and introduce a new way to determine the nanoscale mechanical response of polymeric thin films in the GHz range, using ultrafast optical means. Coupling of the films to plasmonic nanoantennas excited at their vibrational eigenfrequencies allows the extraction of the values of the mechanical moduli as well as the estimation of the glass transition temperature via time-domain measurements, here demonstrated for PMMA films. This nanoscale method can be extended to the determination of mechanical and elastic properties of a wide range of spatially strongly confined materials.
Fil: Boggiano, Hilario Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; Argentina
Fil: Berté, Rodrigo. Ludwig Maximilians Universitat; Alemania
Fil: Scarpettini, Alberto Franco. Universidad Tecnológica Nacional. Facultad Regional Delta; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Cortés, Emiliano. Ludwig Maximilians Universitat; Alemania
Fil: Maier, Stefan A.. Imperial College London; Reino Unido
Fil: Bragas, Andrea Veronica. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; Argentina
Materia
NANOANTENNAS
NANOMECHANICS
PLASMONICS
POLYMERS
ULTRAFAST OPTICS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/146209
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Determination of Nanoscale Mechanical Properties of Polymers via Plasmonic NanoantennasBoggiano, Hilario DanielBerté, RodrigoScarpettini, Alberto FrancoCortés, EmilianoMaier, Stefan A.Bragas, Andrea VeronicaNANOANTENNASNANOMECHANICSPLASMONICSPOLYMERSULTRAFAST OPTICShttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1Nanotechnology and the consequent emergence of miniaturized devices are driving the need to improve our understanding of the mechanical properties of a myriad of materials. Here we focus on amorphous polymeric materials and introduce a new way to determine the nanoscale mechanical response of polymeric thin films in the GHz range, using ultrafast optical means. Coupling of the films to plasmonic nanoantennas excited at their vibrational eigenfrequencies allows the extraction of the values of the mechanical moduli as well as the estimation of the glass transition temperature via time-domain measurements, here demonstrated for PMMA films. This nanoscale method can be extended to the determination of mechanical and elastic properties of a wide range of spatially strongly confined materials.Fil: Boggiano, Hilario Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; ArgentinaFil: Berté, Rodrigo. Ludwig Maximilians Universitat; AlemaniaFil: Scarpettini, Alberto Franco. Universidad Tecnológica Nacional. Facultad Regional Delta; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Cortés, Emiliano. Ludwig Maximilians Universitat; AlemaniaFil: Maier, Stefan A.. Imperial College London; Reino UnidoFil: Bragas, Andrea Veronica. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; ArgentinaAmerican Chemical Society2020-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/146209Boggiano, Hilario Daniel; Berté, Rodrigo; Scarpettini, Alberto Franco; Cortés, Emiliano; Maier, Stefan A.; et al.; Determination of Nanoscale Mechanical Properties of Polymers via Plasmonic Nanoantennas; American Chemical Society; ACS Photonics; 7; 6; 6-2020; 1403-14092330-4022CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acsphotonics.0c00631info:eu-repo/semantics/altIdentifier/doi/10.1021/acsphotonics.0c00631info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:52:27Zoai:ri.conicet.gov.ar:11336/146209instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:52:27.964CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Determination of Nanoscale Mechanical Properties of Polymers via Plasmonic Nanoantennas
title Determination of Nanoscale Mechanical Properties of Polymers via Plasmonic Nanoantennas
spellingShingle Determination of Nanoscale Mechanical Properties of Polymers via Plasmonic Nanoantennas
Boggiano, Hilario Daniel
NANOANTENNAS
NANOMECHANICS
PLASMONICS
POLYMERS
ULTRAFAST OPTICS
title_short Determination of Nanoscale Mechanical Properties of Polymers via Plasmonic Nanoantennas
title_full Determination of Nanoscale Mechanical Properties of Polymers via Plasmonic Nanoantennas
title_fullStr Determination of Nanoscale Mechanical Properties of Polymers via Plasmonic Nanoantennas
title_full_unstemmed Determination of Nanoscale Mechanical Properties of Polymers via Plasmonic Nanoantennas
title_sort Determination of Nanoscale Mechanical Properties of Polymers via Plasmonic Nanoantennas
dc.creator.none.fl_str_mv Boggiano, Hilario Daniel
Berté, Rodrigo
Scarpettini, Alberto Franco
Cortés, Emiliano
Maier, Stefan A.
Bragas, Andrea Veronica
author Boggiano, Hilario Daniel
author_facet Boggiano, Hilario Daniel
Berté, Rodrigo
Scarpettini, Alberto Franco
Cortés, Emiliano
Maier, Stefan A.
Bragas, Andrea Veronica
author_role author
author2 Berté, Rodrigo
Scarpettini, Alberto Franco
Cortés, Emiliano
Maier, Stefan A.
Bragas, Andrea Veronica
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv NANOANTENNAS
NANOMECHANICS
PLASMONICS
POLYMERS
ULTRAFAST OPTICS
topic NANOANTENNAS
NANOMECHANICS
PLASMONICS
POLYMERS
ULTRAFAST OPTICS
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Nanotechnology and the consequent emergence of miniaturized devices are driving the need to improve our understanding of the mechanical properties of a myriad of materials. Here we focus on amorphous polymeric materials and introduce a new way to determine the nanoscale mechanical response of polymeric thin films in the GHz range, using ultrafast optical means. Coupling of the films to plasmonic nanoantennas excited at their vibrational eigenfrequencies allows the extraction of the values of the mechanical moduli as well as the estimation of the glass transition temperature via time-domain measurements, here demonstrated for PMMA films. This nanoscale method can be extended to the determination of mechanical and elastic properties of a wide range of spatially strongly confined materials.
Fil: Boggiano, Hilario Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; Argentina
Fil: Berté, Rodrigo. Ludwig Maximilians Universitat; Alemania
Fil: Scarpettini, Alberto Franco. Universidad Tecnológica Nacional. Facultad Regional Delta; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Cortés, Emiliano. Ludwig Maximilians Universitat; Alemania
Fil: Maier, Stefan A.. Imperial College London; Reino Unido
Fil: Bragas, Andrea Veronica. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; Argentina
description Nanotechnology and the consequent emergence of miniaturized devices are driving the need to improve our understanding of the mechanical properties of a myriad of materials. Here we focus on amorphous polymeric materials and introduce a new way to determine the nanoscale mechanical response of polymeric thin films in the GHz range, using ultrafast optical means. Coupling of the films to plasmonic nanoantennas excited at their vibrational eigenfrequencies allows the extraction of the values of the mechanical moduli as well as the estimation of the glass transition temperature via time-domain measurements, here demonstrated for PMMA films. This nanoscale method can be extended to the determination of mechanical and elastic properties of a wide range of spatially strongly confined materials.
publishDate 2020
dc.date.none.fl_str_mv 2020-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/146209
Boggiano, Hilario Daniel; Berté, Rodrigo; Scarpettini, Alberto Franco; Cortés, Emiliano; Maier, Stefan A.; et al.; Determination of Nanoscale Mechanical Properties of Polymers via Plasmonic Nanoantennas; American Chemical Society; ACS Photonics; 7; 6; 6-2020; 1403-1409
2330-4022
CONICET Digital
CONICET
url http://hdl.handle.net/11336/146209
identifier_str_mv Boggiano, Hilario Daniel; Berté, Rodrigo; Scarpettini, Alberto Franco; Cortés, Emiliano; Maier, Stefan A.; et al.; Determination of Nanoscale Mechanical Properties of Polymers via Plasmonic Nanoantennas; American Chemical Society; ACS Photonics; 7; 6; 6-2020; 1403-1409
2330-4022
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acsphotonics.0c00631
info:eu-repo/semantics/altIdentifier/doi/10.1021/acsphotonics.0c00631
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846782215921336320
score 12.982451

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