Glucose biosensing at carbon paste electrodes containing iron nanoparticles

Autores
Comba, Fausto Nahuel; Rubianes, María Dolores; Herrasti, Pilar; Rivas, Gustavo Adolfo
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This work reports the advantages of incorporating a metal as common as iron in a carbon paste electrode containing glucose oxidase to develop highly selective, stable and sensitive amperometric glucose biosensors. The excellent catalytic activity of iron nanoparticles towards the reduction of hydrogen peroxide has made possible the quantification of glucose at very low potentials (-0.100 V) avoiding, in this way, the interference of easily oxidizable compounds like ascorbic acid and uric acid without needing of redox mediators or permselective membranes. Linear relationship between current and glucose concentration was obtained up to 0.020 M (3.6 g/L), with a detection limit of 0.2 mM, no interference of AA and UA, and very good correlation with the spectrophotometric methods when determining glucose in human blood serum. © 2010 Elsevier B.V. All rights reserved.
Fil: Comba, Fausto Nahuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Rubianes, María Dolores. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Herrasti, Pilar. Universidad Autónoma de Madrid; España
Fil: Rivas, Gustavo Adolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Materia
Amperometric Glucose Biosensor
Carbon Paste Electrode
Glucose Oxidase
Hydrogen Peroxide
Iron
Nanoparticles
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/69835
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Glucose biosensing at carbon paste electrodes containing iron nanoparticlesComba, Fausto NahuelRubianes, María DoloresHerrasti, PilarRivas, Gustavo AdolfoAmperometric Glucose BiosensorCarbon Paste ElectrodeGlucose OxidaseHydrogen PeroxideIronNanoparticleshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1This work reports the advantages of incorporating a metal as common as iron in a carbon paste electrode containing glucose oxidase to develop highly selective, stable and sensitive amperometric glucose biosensors. The excellent catalytic activity of iron nanoparticles towards the reduction of hydrogen peroxide has made possible the quantification of glucose at very low potentials (-0.100 V) avoiding, in this way, the interference of easily oxidizable compounds like ascorbic acid and uric acid without needing of redox mediators or permselective membranes. Linear relationship between current and glucose concentration was obtained up to 0.020 M (3.6 g/L), with a detection limit of 0.2 mM, no interference of AA and UA, and very good correlation with the spectrophotometric methods when determining glucose in human blood serum. © 2010 Elsevier B.V. All rights reserved.Fil: Comba, Fausto Nahuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Rubianes, María Dolores. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Herrasti, Pilar. Universidad Autónoma de Madrid; EspañaFil: Rivas, Gustavo Adolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaElsevier Science Sa2010-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/69835Comba, Fausto Nahuel; Rubianes, María Dolores; Herrasti, Pilar; Rivas, Gustavo Adolfo; Glucose biosensing at carbon paste electrodes containing iron nanoparticles; Elsevier Science Sa; Sensors and Actuators B: Chemical; 149; 1; 8-2010; 306-3090925-4005CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0925400510004971info:eu-repo/semantics/altIdentifier/doi/10.1016/j.snb.2010.06.020info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:16:11Zoai:ri.conicet.gov.ar:11336/69835instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:16:11.848CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Glucose biosensing at carbon paste electrodes containing iron nanoparticles
title Glucose biosensing at carbon paste electrodes containing iron nanoparticles
spellingShingle Glucose biosensing at carbon paste electrodes containing iron nanoparticles
Comba, Fausto Nahuel
Amperometric Glucose Biosensor
Carbon Paste Electrode
Glucose Oxidase
Hydrogen Peroxide
Iron
Nanoparticles
title_short Glucose biosensing at carbon paste electrodes containing iron nanoparticles
title_full Glucose biosensing at carbon paste electrodes containing iron nanoparticles
title_fullStr Glucose biosensing at carbon paste electrodes containing iron nanoparticles
title_full_unstemmed Glucose biosensing at carbon paste electrodes containing iron nanoparticles
title_sort Glucose biosensing at carbon paste electrodes containing iron nanoparticles
dc.creator.none.fl_str_mv Comba, Fausto Nahuel
Rubianes, María Dolores
Herrasti, Pilar
Rivas, Gustavo Adolfo
author Comba, Fausto Nahuel
author_facet Comba, Fausto Nahuel
Rubianes, María Dolores
Herrasti, Pilar
Rivas, Gustavo Adolfo
author_role author
author2 Rubianes, María Dolores
Herrasti, Pilar
Rivas, Gustavo Adolfo
author2_role author
author
author
dc.subject.none.fl_str_mv Amperometric Glucose Biosensor
Carbon Paste Electrode
Glucose Oxidase
Hydrogen Peroxide
Iron
Nanoparticles
topic Amperometric Glucose Biosensor
Carbon Paste Electrode
Glucose Oxidase
Hydrogen Peroxide
Iron
Nanoparticles
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv This work reports the advantages of incorporating a metal as common as iron in a carbon paste electrode containing glucose oxidase to develop highly selective, stable and sensitive amperometric glucose biosensors. The excellent catalytic activity of iron nanoparticles towards the reduction of hydrogen peroxide has made possible the quantification of glucose at very low potentials (-0.100 V) avoiding, in this way, the interference of easily oxidizable compounds like ascorbic acid and uric acid without needing of redox mediators or permselective membranes. Linear relationship between current and glucose concentration was obtained up to 0.020 M (3.6 g/L), with a detection limit of 0.2 mM, no interference of AA and UA, and very good correlation with the spectrophotometric methods when determining glucose in human blood serum. © 2010 Elsevier B.V. All rights reserved.
Fil: Comba, Fausto Nahuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Rubianes, María Dolores. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Herrasti, Pilar. Universidad Autónoma de Madrid; España
Fil: Rivas, Gustavo Adolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
description This work reports the advantages of incorporating a metal as common as iron in a carbon paste electrode containing glucose oxidase to develop highly selective, stable and sensitive amperometric glucose biosensors. The excellent catalytic activity of iron nanoparticles towards the reduction of hydrogen peroxide has made possible the quantification of glucose at very low potentials (-0.100 V) avoiding, in this way, the interference of easily oxidizable compounds like ascorbic acid and uric acid without needing of redox mediators or permselective membranes. Linear relationship between current and glucose concentration was obtained up to 0.020 M (3.6 g/L), with a detection limit of 0.2 mM, no interference of AA and UA, and very good correlation with the spectrophotometric methods when determining glucose in human blood serum. © 2010 Elsevier B.V. All rights reserved.
publishDate 2010
dc.date.none.fl_str_mv 2010-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/69835
Comba, Fausto Nahuel; Rubianes, María Dolores; Herrasti, Pilar; Rivas, Gustavo Adolfo; Glucose biosensing at carbon paste electrodes containing iron nanoparticles; Elsevier Science Sa; Sensors and Actuators B: Chemical; 149; 1; 8-2010; 306-309
0925-4005
CONICET Digital
CONICET
url http://hdl.handle.net/11336/69835
identifier_str_mv Comba, Fausto Nahuel; Rubianes, María Dolores; Herrasti, Pilar; Rivas, Gustavo Adolfo; Glucose biosensing at carbon paste electrodes containing iron nanoparticles; Elsevier Science Sa; Sensors and Actuators B: Chemical; 149; 1; 8-2010; 306-309
0925-4005
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0925400510004971
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.snb.2010.06.020
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science Sa
publisher.none.fl_str_mv Elsevier Science Sa
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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