Optimization of methods to assess levels of As, Bi, Sb and Se in airborne particulate matter by FI-HG-ICP OES

Autores
Savio, Marianela; Pacheco, Pablo Hugo; Martinez, Luis Dante; Smichowski, Patricia Nora; Gil, Raul Andres
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A study was undertaken to assess the level of selected trace elements namely, As, Bi, Sb and Se in airborne particulate matter collected on ash-free glass-fibre filters from urban and industrial areas of Argentina. For sample digestion, a simple acid treatment with HCl + HF is proposed with the aim to minimize contamination and reduce sample treatment steps. A flow injection-hydride generation system in combination with inductively coupled plasma optical emission spectrometry was used. While, Se and Bi could be determined directly from the digest, As and Sb needed a pre-reduction with KI, and H3BO3 to avoid the interference of F- ions that may cause losses via volatile compounds such as AsF3 and Sb(v) complexes. Limits of detection (3σ) of 0.3 ng m-3 for As; 0.09 ng m-3 for Bi, and 0.1 ng m-3 for Sb and Se were achieved. Precision resulted in better than 6.1% accuracy for all the elements determined. Accuracy test was assessed by means of the certified reference material, NIST 1648 (urban particulate matter).
Fil: Savio, Marianela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
Fil: Pacheco, Pablo Hugo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
Fil: Martinez, Luis Dante. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
Fil: Smichowski, Patricia Nora. Comisión Nacional de Energía Atómica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Gil, Raul Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
Materia
As, Bi, Se, Sb
airbone particulate matter
FI-HG-ICP OES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/188276
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Optimization of methods to assess levels of As, Bi, Sb and Se in airborne particulate matter by FI-HG-ICP OESSavio, MarianelaPacheco, Pablo HugoMartinez, Luis DanteSmichowski, Patricia NoraGil, Raul AndresAs, Bi, Se, Sbairbone particulate matterFI-HG-ICP OEShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A study was undertaken to assess the level of selected trace elements namely, As, Bi, Sb and Se in airborne particulate matter collected on ash-free glass-fibre filters from urban and industrial areas of Argentina. For sample digestion, a simple acid treatment with HCl + HF is proposed with the aim to minimize contamination and reduce sample treatment steps. A flow injection-hydride generation system in combination with inductively coupled plasma optical emission spectrometry was used. While, Se and Bi could be determined directly from the digest, As and Sb needed a pre-reduction with KI, and H3BO3 to avoid the interference of F- ions that may cause losses via volatile compounds such as AsF3 and Sb(v) complexes. Limits of detection (3σ) of 0.3 ng m-3 for As; 0.09 ng m-3 for Bi, and 0.1 ng m-3 for Sb and Se were achieved. Precision resulted in better than 6.1% accuracy for all the elements determined. Accuracy test was assessed by means of the certified reference material, NIST 1648 (urban particulate matter).Fil: Savio, Marianela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; ArgentinaFil: Pacheco, Pablo Hugo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; ArgentinaFil: Martinez, Luis Dante. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; ArgentinaFil: Smichowski, Patricia Nora. Comisión Nacional de Energía Atómica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Gil, Raul Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; ArgentinaRoyal Society of Chemistry2010-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/188276Savio, Marianela; Pacheco, Pablo Hugo; Martinez, Luis Dante; Smichowski, Patricia Nora; Gil, Raul Andres; Optimization of methods to assess levels of As, Bi, Sb and Se in airborne particulate matter by FI-HG-ICP OES; Royal Society of Chemistry; Journal of Analytical Atomic Spectrometry; 25; 8; 8-2010; 1343-13470267-9477CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2010/ja/c003864dinfo:eu-repo/semantics/altIdentifier/doi/10.1039/C003864Dinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:22:15Zoai:ri.conicet.gov.ar:11336/188276instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:22:15.442CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Optimization of methods to assess levels of As, Bi, Sb and Se in airborne particulate matter by FI-HG-ICP OES
title Optimization of methods to assess levels of As, Bi, Sb and Se in airborne particulate matter by FI-HG-ICP OES
spellingShingle Optimization of methods to assess levels of As, Bi, Sb and Se in airborne particulate matter by FI-HG-ICP OES
Savio, Marianela
As, Bi, Se, Sb
airbone particulate matter
FI-HG-ICP OES
title_short Optimization of methods to assess levels of As, Bi, Sb and Se in airborne particulate matter by FI-HG-ICP OES
title_full Optimization of methods to assess levels of As, Bi, Sb and Se in airborne particulate matter by FI-HG-ICP OES
title_fullStr Optimization of methods to assess levels of As, Bi, Sb and Se in airborne particulate matter by FI-HG-ICP OES
title_full_unstemmed Optimization of methods to assess levels of As, Bi, Sb and Se in airborne particulate matter by FI-HG-ICP OES
title_sort Optimization of methods to assess levels of As, Bi, Sb and Se in airborne particulate matter by FI-HG-ICP OES
dc.creator.none.fl_str_mv Savio, Marianela
Pacheco, Pablo Hugo
Martinez, Luis Dante
Smichowski, Patricia Nora
Gil, Raul Andres
author Savio, Marianela
author_facet Savio, Marianela
Pacheco, Pablo Hugo
Martinez, Luis Dante
Smichowski, Patricia Nora
Gil, Raul Andres
author_role author
author2 Pacheco, Pablo Hugo
Martinez, Luis Dante
Smichowski, Patricia Nora
Gil, Raul Andres
author2_role author
author
author
author
dc.subject.none.fl_str_mv As, Bi, Se, Sb
airbone particulate matter
FI-HG-ICP OES
topic As, Bi, Se, Sb
airbone particulate matter
FI-HG-ICP OES
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A study was undertaken to assess the level of selected trace elements namely, As, Bi, Sb and Se in airborne particulate matter collected on ash-free glass-fibre filters from urban and industrial areas of Argentina. For sample digestion, a simple acid treatment with HCl + HF is proposed with the aim to minimize contamination and reduce sample treatment steps. A flow injection-hydride generation system in combination with inductively coupled plasma optical emission spectrometry was used. While, Se and Bi could be determined directly from the digest, As and Sb needed a pre-reduction with KI, and H3BO3 to avoid the interference of F- ions that may cause losses via volatile compounds such as AsF3 and Sb(v) complexes. Limits of detection (3σ) of 0.3 ng m-3 for As; 0.09 ng m-3 for Bi, and 0.1 ng m-3 for Sb and Se were achieved. Precision resulted in better than 6.1% accuracy for all the elements determined. Accuracy test was assessed by means of the certified reference material, NIST 1648 (urban particulate matter).
Fil: Savio, Marianela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
Fil: Pacheco, Pablo Hugo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
Fil: Martinez, Luis Dante. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
Fil: Smichowski, Patricia Nora. Comisión Nacional de Energía Atómica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Gil, Raul Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina
description A study was undertaken to assess the level of selected trace elements namely, As, Bi, Sb and Se in airborne particulate matter collected on ash-free glass-fibre filters from urban and industrial areas of Argentina. For sample digestion, a simple acid treatment with HCl + HF is proposed with the aim to minimize contamination and reduce sample treatment steps. A flow injection-hydride generation system in combination with inductively coupled plasma optical emission spectrometry was used. While, Se and Bi could be determined directly from the digest, As and Sb needed a pre-reduction with KI, and H3BO3 to avoid the interference of F- ions that may cause losses via volatile compounds such as AsF3 and Sb(v) complexes. Limits of detection (3σ) of 0.3 ng m-3 for As; 0.09 ng m-3 for Bi, and 0.1 ng m-3 for Sb and Se were achieved. Precision resulted in better than 6.1% accuracy for all the elements determined. Accuracy test was assessed by means of the certified reference material, NIST 1648 (urban particulate matter).
publishDate 2010
dc.date.none.fl_str_mv 2010-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/188276
Savio, Marianela; Pacheco, Pablo Hugo; Martinez, Luis Dante; Smichowski, Patricia Nora; Gil, Raul Andres; Optimization of methods to assess levels of As, Bi, Sb and Se in airborne particulate matter by FI-HG-ICP OES; Royal Society of Chemistry; Journal of Analytical Atomic Spectrometry; 25; 8; 8-2010; 1343-1347
0267-9477
CONICET Digital
CONICET
url http://hdl.handle.net/11336/188276
identifier_str_mv Savio, Marianela; Pacheco, Pablo Hugo; Martinez, Luis Dante; Smichowski, Patricia Nora; Gil, Raul Andres; Optimization of methods to assess levels of As, Bi, Sb and Se in airborne particulate matter by FI-HG-ICP OES; Royal Society of Chemistry; Journal of Analytical Atomic Spectrometry; 25; 8; 8-2010; 1343-1347
0267-9477
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2010/ja/c003864d
info:eu-repo/semantics/altIdentifier/doi/10.1039/C003864D
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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