Structure and physical properties of nickel manganite NiMn2O4 obtained from nickel permanganate precursor
- Autores
- Díez, Alejandra; Schmidt, Rainer; Sagua, Aurora Estela; Frechero, Marisa Alejandra; Matesanz, Emilio; Leon, Carlos; Morán Emilio, E.
- Año de publicación
- 2010
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- In this paper we present the structural, magnetic and dielectric properties of ceramic nickel manganite NiMn2O4+δ produced by using nickel permanganate Ni(MnO4)2xH2O as a precursor. We have characterized the NiMn2O4+δ stoichiometry using quantitative energy-dispersive analysis of X-rays and thermal gravimetry under reducing conditions. Increased oxygen and Mn4+ contents were detected. X-ray diffraction and Rietveld refinement of X-ray data were carried out. Temperature dependent magnetization measurements were performed and the ferri-magnetic transition was identified at ≈100K. The ferri-magnetic moment was found to be ≈1μB and hysteretic magnetization vs applied field curves were obtained. Dielectric properties were measured using impedance spectroscopy. Two dielectric relaxation processes were detected, which were associated with grain boundary and bulk contributions. The Arrhenius plots of resistivity and the temperature dependent dielectric permittivity were obtained for the two relaxations by means of an equivalent circuit model based on a series of two parallel RC elements. © 2010 Elsevier Ltd.
Fil: Díez, Alejandra. Universidad Nacional del Sur. Departamento de Química; Argentina
Fil: Schmidt, Rainer. Universidad Complutense de Madrid; España
Fil: Sagua, Aurora Estela. Universidad Nacional del Sur. Departamento de Química; Argentina
Fil: Frechero, Marisa Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Matesanz, Emilio. Universidad Complutense de Madrid; España
Fil: Leon, Carlos. Universidad Complutense de Madrid; España
Fil: Morán Emilio, E.. Universidad Complutense de Madrid; España - Materia
-
B. X-Ray Methods
C. Chemical Properties
C. Dielectric Properties. E. Thermistors
C. Magnetic Properties - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/64066
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Structure and physical properties of nickel manganite NiMn2O4 obtained from nickel permanganate precursorDíez, AlejandraSchmidt, RainerSagua, Aurora EstelaFrechero, Marisa AlejandraMatesanz, EmilioLeon, CarlosMorán Emilio, E.B. X-Ray MethodsC. Chemical PropertiesC. Dielectric Properties. E. ThermistorsC. Magnetic Propertieshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1In this paper we present the structural, magnetic and dielectric properties of ceramic nickel manganite NiMn2O4+δ produced by using nickel permanganate Ni(MnO4)2xH2O as a precursor. We have characterized the NiMn2O4+δ stoichiometry using quantitative energy-dispersive analysis of X-rays and thermal gravimetry under reducing conditions. Increased oxygen and Mn4+ contents were detected. X-ray diffraction and Rietveld refinement of X-ray data were carried out. Temperature dependent magnetization measurements were performed and the ferri-magnetic transition was identified at ≈100K. The ferri-magnetic moment was found to be ≈1μB and hysteretic magnetization vs applied field curves were obtained. Dielectric properties were measured using impedance spectroscopy. Two dielectric relaxation processes were detected, which were associated with grain boundary and bulk contributions. The Arrhenius plots of resistivity and the temperature dependent dielectric permittivity were obtained for the two relaxations by means of an equivalent circuit model based on a series of two parallel RC elements. © 2010 Elsevier Ltd.Fil: Díez, Alejandra. Universidad Nacional del Sur. Departamento de Química; ArgentinaFil: Schmidt, Rainer. Universidad Complutense de Madrid; EspañaFil: Sagua, Aurora Estela. Universidad Nacional del Sur. Departamento de Química; ArgentinaFil: Frechero, Marisa Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Matesanz, Emilio. Universidad Complutense de Madrid; EspañaFil: Leon, Carlos. Universidad Complutense de Madrid; EspañaFil: Morán Emilio, E.. Universidad Complutense de Madrid; EspañaElsevier2010-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/64066Díez, Alejandra; Schmidt, Rainer; Sagua, Aurora Estela; Frechero, Marisa Alejandra; Matesanz, Emilio; et al.; Structure and physical properties of nickel manganite NiMn2O4 obtained from nickel permanganate precursor; Elsevier; Journal of the European Ceramic Society; 30; 12; 9-2010; 2617-26240955-2219CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jeurceramsoc.2010.04.032info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0955221910002037info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:35:44Zoai:ri.conicet.gov.ar:11336/64066instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:35:44.833CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Structure and physical properties of nickel manganite NiMn2O4 obtained from nickel permanganate precursor |
title |
Structure and physical properties of nickel manganite NiMn2O4 obtained from nickel permanganate precursor |
spellingShingle |
Structure and physical properties of nickel manganite NiMn2O4 obtained from nickel permanganate precursor Díez, Alejandra B. X-Ray Methods C. Chemical Properties C. Dielectric Properties. E. Thermistors C. Magnetic Properties |
title_short |
Structure and physical properties of nickel manganite NiMn2O4 obtained from nickel permanganate precursor |
title_full |
Structure and physical properties of nickel manganite NiMn2O4 obtained from nickel permanganate precursor |
title_fullStr |
Structure and physical properties of nickel manganite NiMn2O4 obtained from nickel permanganate precursor |
title_full_unstemmed |
Structure and physical properties of nickel manganite NiMn2O4 obtained from nickel permanganate precursor |
title_sort |
Structure and physical properties of nickel manganite NiMn2O4 obtained from nickel permanganate precursor |
dc.creator.none.fl_str_mv |
Díez, Alejandra Schmidt, Rainer Sagua, Aurora Estela Frechero, Marisa Alejandra Matesanz, Emilio Leon, Carlos Morán Emilio, E. |
author |
Díez, Alejandra |
author_facet |
Díez, Alejandra Schmidt, Rainer Sagua, Aurora Estela Frechero, Marisa Alejandra Matesanz, Emilio Leon, Carlos Morán Emilio, E. |
author_role |
author |
author2 |
Schmidt, Rainer Sagua, Aurora Estela Frechero, Marisa Alejandra Matesanz, Emilio Leon, Carlos Morán Emilio, E. |
author2_role |
author author author author author author |
dc.subject.none.fl_str_mv |
B. X-Ray Methods C. Chemical Properties C. Dielectric Properties. E. Thermistors C. Magnetic Properties |
topic |
B. X-Ray Methods C. Chemical Properties C. Dielectric Properties. E. Thermistors C. Magnetic Properties |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
In this paper we present the structural, magnetic and dielectric properties of ceramic nickel manganite NiMn2O4+δ produced by using nickel permanganate Ni(MnO4)2xH2O as a precursor. We have characterized the NiMn2O4+δ stoichiometry using quantitative energy-dispersive analysis of X-rays and thermal gravimetry under reducing conditions. Increased oxygen and Mn4+ contents were detected. X-ray diffraction and Rietveld refinement of X-ray data were carried out. Temperature dependent magnetization measurements were performed and the ferri-magnetic transition was identified at ≈100K. The ferri-magnetic moment was found to be ≈1μB and hysteretic magnetization vs applied field curves were obtained. Dielectric properties were measured using impedance spectroscopy. Two dielectric relaxation processes were detected, which were associated with grain boundary and bulk contributions. The Arrhenius plots of resistivity and the temperature dependent dielectric permittivity were obtained for the two relaxations by means of an equivalent circuit model based on a series of two parallel RC elements. © 2010 Elsevier Ltd. Fil: Díez, Alejandra. Universidad Nacional del Sur. Departamento de Química; Argentina Fil: Schmidt, Rainer. Universidad Complutense de Madrid; España Fil: Sagua, Aurora Estela. Universidad Nacional del Sur. Departamento de Química; Argentina Fil: Frechero, Marisa Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina Fil: Matesanz, Emilio. Universidad Complutense de Madrid; España Fil: Leon, Carlos. Universidad Complutense de Madrid; España Fil: Morán Emilio, E.. Universidad Complutense de Madrid; España |
description |
In this paper we present the structural, magnetic and dielectric properties of ceramic nickel manganite NiMn2O4+δ produced by using nickel permanganate Ni(MnO4)2xH2O as a precursor. We have characterized the NiMn2O4+δ stoichiometry using quantitative energy-dispersive analysis of X-rays and thermal gravimetry under reducing conditions. Increased oxygen and Mn4+ contents were detected. X-ray diffraction and Rietveld refinement of X-ray data were carried out. Temperature dependent magnetization measurements were performed and the ferri-magnetic transition was identified at ≈100K. The ferri-magnetic moment was found to be ≈1μB and hysteretic magnetization vs applied field curves were obtained. Dielectric properties were measured using impedance spectroscopy. Two dielectric relaxation processes were detected, which were associated with grain boundary and bulk contributions. The Arrhenius plots of resistivity and the temperature dependent dielectric permittivity were obtained for the two relaxations by means of an equivalent circuit model based on a series of two parallel RC elements. © 2010 Elsevier Ltd. |
publishDate |
2010 |
dc.date.none.fl_str_mv |
2010-09 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/64066 Díez, Alejandra; Schmidt, Rainer; Sagua, Aurora Estela; Frechero, Marisa Alejandra; Matesanz, Emilio; et al.; Structure and physical properties of nickel manganite NiMn2O4 obtained from nickel permanganate precursor; Elsevier; Journal of the European Ceramic Society; 30; 12; 9-2010; 2617-2624 0955-2219 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/64066 |
identifier_str_mv |
Díez, Alejandra; Schmidt, Rainer; Sagua, Aurora Estela; Frechero, Marisa Alejandra; Matesanz, Emilio; et al.; Structure and physical properties of nickel manganite NiMn2O4 obtained from nickel permanganate precursor; Elsevier; Journal of the European Ceramic Society; 30; 12; 9-2010; 2617-2624 0955-2219 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jeurceramsoc.2010.04.032 info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0955221910002037 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) |
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CONICET Digital (CONICET) |
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Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613115541454848 |
score |
13.070432 |