Structure and physical properties of nickel manganite NiMn2O4 obtained from nickel permanganate precursor

Autores
Díez, Alejandra; Schmidt, Rainer; Sagua, Aurora Estela; Frechero, Marisa Alejandra; Matesanz, Emilio; Leon, Carlos; Morán Emilio, E.
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this paper we present the structural, magnetic and dielectric properties of ceramic nickel manganite NiMn2O4+δ produced by using nickel permanganate Ni(MnO4)2xH2O as a precursor. We have characterized the NiMn2O4+δ stoichiometry using quantitative energy-dispersive analysis of X-rays and thermal gravimetry under reducing conditions. Increased oxygen and Mn4+ contents were detected. X-ray diffraction and Rietveld refinement of X-ray data were carried out. Temperature dependent magnetization measurements were performed and the ferri-magnetic transition was identified at ≈100K. The ferri-magnetic moment was found to be ≈1μB and hysteretic magnetization vs applied field curves were obtained. Dielectric properties were measured using impedance spectroscopy. Two dielectric relaxation processes were detected, which were associated with grain boundary and bulk contributions. The Arrhenius plots of resistivity and the temperature dependent dielectric permittivity were obtained for the two relaxations by means of an equivalent circuit model based on a series of two parallel RC elements. © 2010 Elsevier Ltd.
Fil: Díez, Alejandra. Universidad Nacional del Sur. Departamento de Química; Argentina
Fil: Schmidt, Rainer. Universidad Complutense de Madrid; España
Fil: Sagua, Aurora Estela. Universidad Nacional del Sur. Departamento de Química; Argentina
Fil: Frechero, Marisa Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Matesanz, Emilio. Universidad Complutense de Madrid; España
Fil: Leon, Carlos. Universidad Complutense de Madrid; España
Fil: Morán Emilio, E.. Universidad Complutense de Madrid; España
Materia
B. X-Ray Methods
C. Chemical Properties
C. Dielectric Properties. E. Thermistors
C. Magnetic Properties
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/64066
Acceder
id CONICETDig_4af285b6abac347ced9dc972f8e808c8
oai_identifier_str oai:ri.conicet.gov.ar:11336/64066
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Structure and physical properties of nickel manganite NiMn2O4 obtained from nickel permanganate precursorDíez, AlejandraSchmidt, RainerSagua, Aurora EstelaFrechero, Marisa AlejandraMatesanz, EmilioLeon, CarlosMorán Emilio, E.B. X-Ray MethodsC. Chemical PropertiesC. Dielectric Properties. E. ThermistorsC. Magnetic Propertieshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1In this paper we present the structural, magnetic and dielectric properties of ceramic nickel manganite NiMn2O4+δ produced by using nickel permanganate Ni(MnO4)2xH2O as a precursor. We have characterized the NiMn2O4+δ stoichiometry using quantitative energy-dispersive analysis of X-rays and thermal gravimetry under reducing conditions. Increased oxygen and Mn4+ contents were detected. X-ray diffraction and Rietveld refinement of X-ray data were carried out. Temperature dependent magnetization measurements were performed and the ferri-magnetic transition was identified at ≈100K. The ferri-magnetic moment was found to be ≈1μB and hysteretic magnetization vs applied field curves were obtained. Dielectric properties were measured using impedance spectroscopy. Two dielectric relaxation processes were detected, which were associated with grain boundary and bulk contributions. The Arrhenius plots of resistivity and the temperature dependent dielectric permittivity were obtained for the two relaxations by means of an equivalent circuit model based on a series of two parallel RC elements. © 2010 Elsevier Ltd.Fil: Díez, Alejandra. Universidad Nacional del Sur. Departamento de Química; ArgentinaFil: Schmidt, Rainer. Universidad Complutense de Madrid; EspañaFil: Sagua, Aurora Estela. Universidad Nacional del Sur. Departamento de Química; ArgentinaFil: Frechero, Marisa Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; ArgentinaFil: Matesanz, Emilio. Universidad Complutense de Madrid; EspañaFil: Leon, Carlos. Universidad Complutense de Madrid; EspañaFil: Morán Emilio, E.. Universidad Complutense de Madrid; EspañaElsevier2010-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/64066Díez, Alejandra; Schmidt, Rainer; Sagua, Aurora Estela; Frechero, Marisa Alejandra; Matesanz, Emilio; et al.; Structure and physical properties of nickel manganite NiMn2O4 obtained from nickel permanganate precursor; Elsevier; Journal of the European Ceramic Society; 30; 12; 9-2010; 2617-26240955-2219CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jeurceramsoc.2010.04.032info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0955221910002037info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:03:49Zoai:ri.conicet.gov.ar:11336/64066instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:03:49.63CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Structure and physical properties of nickel manganite NiMn2O4 obtained from nickel permanganate precursor
title Structure and physical properties of nickel manganite NiMn2O4 obtained from nickel permanganate precursor
spellingShingle Structure and physical properties of nickel manganite NiMn2O4 obtained from nickel permanganate precursor
Díez, Alejandra
B. X-Ray Methods
C. Chemical Properties
C. Dielectric Properties. E. Thermistors
C. Magnetic Properties
title_short Structure and physical properties of nickel manganite NiMn2O4 obtained from nickel permanganate precursor
title_full Structure and physical properties of nickel manganite NiMn2O4 obtained from nickel permanganate precursor
title_fullStr Structure and physical properties of nickel manganite NiMn2O4 obtained from nickel permanganate precursor
title_full_unstemmed Structure and physical properties of nickel manganite NiMn2O4 obtained from nickel permanganate precursor
title_sort Structure and physical properties of nickel manganite NiMn2O4 obtained from nickel permanganate precursor
dc.creator.none.fl_str_mv Díez, Alejandra
Schmidt, Rainer
Sagua, Aurora Estela
Frechero, Marisa Alejandra
Matesanz, Emilio
Leon, Carlos
Morán Emilio, E.
author Díez, Alejandra
author_facet Díez, Alejandra
Schmidt, Rainer
Sagua, Aurora Estela
Frechero, Marisa Alejandra
Matesanz, Emilio
Leon, Carlos
Morán Emilio, E.
author_role author
author2 Schmidt, Rainer
Sagua, Aurora Estela
Frechero, Marisa Alejandra
Matesanz, Emilio
Leon, Carlos
Morán Emilio, E.
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv B. X-Ray Methods
C. Chemical Properties
C. Dielectric Properties. E. Thermistors
C. Magnetic Properties
topic B. X-Ray Methods
C. Chemical Properties
C. Dielectric Properties. E. Thermistors
C. Magnetic Properties
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv In this paper we present the structural, magnetic and dielectric properties of ceramic nickel manganite NiMn2O4+δ produced by using nickel permanganate Ni(MnO4)2xH2O as a precursor. We have characterized the NiMn2O4+δ stoichiometry using quantitative energy-dispersive analysis of X-rays and thermal gravimetry under reducing conditions. Increased oxygen and Mn4+ contents were detected. X-ray diffraction and Rietveld refinement of X-ray data were carried out. Temperature dependent magnetization measurements were performed and the ferri-magnetic transition was identified at ≈100K. The ferri-magnetic moment was found to be ≈1μB and hysteretic magnetization vs applied field curves were obtained. Dielectric properties were measured using impedance spectroscopy. Two dielectric relaxation processes were detected, which were associated with grain boundary and bulk contributions. The Arrhenius plots of resistivity and the temperature dependent dielectric permittivity were obtained for the two relaxations by means of an equivalent circuit model based on a series of two parallel RC elements. © 2010 Elsevier Ltd.
Fil: Díez, Alejandra. Universidad Nacional del Sur. Departamento de Química; Argentina
Fil: Schmidt, Rainer. Universidad Complutense de Madrid; España
Fil: Sagua, Aurora Estela. Universidad Nacional del Sur. Departamento de Química; Argentina
Fil: Frechero, Marisa Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
Fil: Matesanz, Emilio. Universidad Complutense de Madrid; España
Fil: Leon, Carlos. Universidad Complutense de Madrid; España
Fil: Morán Emilio, E.. Universidad Complutense de Madrid; España
description In this paper we present the structural, magnetic and dielectric properties of ceramic nickel manganite NiMn2O4+δ produced by using nickel permanganate Ni(MnO4)2xH2O as a precursor. We have characterized the NiMn2O4+δ stoichiometry using quantitative energy-dispersive analysis of X-rays and thermal gravimetry under reducing conditions. Increased oxygen and Mn4+ contents were detected. X-ray diffraction and Rietveld refinement of X-ray data were carried out. Temperature dependent magnetization measurements were performed and the ferri-magnetic transition was identified at ≈100K. The ferri-magnetic moment was found to be ≈1μB and hysteretic magnetization vs applied field curves were obtained. Dielectric properties were measured using impedance spectroscopy. Two dielectric relaxation processes were detected, which were associated with grain boundary and bulk contributions. The Arrhenius plots of resistivity and the temperature dependent dielectric permittivity were obtained for the two relaxations by means of an equivalent circuit model based on a series of two parallel RC elements. © 2010 Elsevier Ltd.
publishDate 2010
dc.date.none.fl_str_mv 2010-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/64066
Díez, Alejandra; Schmidt, Rainer; Sagua, Aurora Estela; Frechero, Marisa Alejandra; Matesanz, Emilio; et al.; Structure and physical properties of nickel manganite NiMn2O4 obtained from nickel permanganate precursor; Elsevier; Journal of the European Ceramic Society; 30; 12; 9-2010; 2617-2624
0955-2219
CONICET Digital
CONICET
url http://hdl.handle.net/11336/64066
identifier_str_mv Díez, Alejandra; Schmidt, Rainer; Sagua, Aurora Estela; Frechero, Marisa Alejandra; Matesanz, Emilio; et al.; Structure and physical properties of nickel manganite NiMn2O4 obtained from nickel permanganate precursor; Elsevier; Journal of the European Ceramic Society; 30; 12; 9-2010; 2617-2624
0955-2219
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jeurceramsoc.2010.04.032
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0955221910002037
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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