Synergistic effect of bimetallic Au-Pd supported on ceria-zirconia mixed oxide catalysts for selective oxidation of glycerol

Autores
Olmos Carreno, Carol Maritza; Chinchilla, Lidia E.; Rodrigues, Elodie G.; Delgado, Juan J.; Hungría, Ana B.; Blanco, Ginesa; Pereira, Manuel F.R.; Órfão, José J.M.; Calvino, Jose J.; Chen, Xiaowei
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A series of bimetallic Au-Pd catalysts supported on Ce0.62Zr0.38O2mixed oxide has been synthesized usinga simultaneous deposition-precipitation method. Different Au:Pd ratios were obtained maintaining Auloadings constant and varying Pd content. Elemental analysis, X-ray diffraction, N2physisorption,X-rayphotoelectron spectroscopy, scanning transmission electron microscopy-high angle annular dark field(STEM-HAADF) and X-ray energy dispersive spectroscopy (XEDS) techniques have been employed tocharacterize these catalysts. The catalytic activities for selective oxidation of glycerol over these bimetalliccatalysts have been evaluated, a synergistic effect being observed. Thus, the bimetallic Au-Pd catalystwith the lowest Pd content was the one exhibiting the highest catalytic activity among all the preparedcatalysts. Oxidation at 700◦C of the bimetallic 2.2AuPd/Ce0.62Zr0.38O2catalyst led to an increase of thecatalytic activity for the selective oxidation of glycerol, which seemed to be due to the formation of alarger fraction of bimetallic Au-Pd alloy-type nanoparticles after oxidation at higher temperatures.
Fil: Olmos Carreno, Carol Maritza. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Cádiz; España
Fil: Chinchilla, Lidia E.. Universidad de Cádiz; España
Fil: Rodrigues, Elodie G.. Universidad de Porto; Portugal
Fil: Delgado, Juan J.. Universidad de Cádiz; España
Fil: Hungría, Ana B.. Universidad de Cádiz; España
Fil: Blanco, Ginesa. Universidad de Cádiz; España
Fil: Pereira, Manuel F.R.. Universidad de Porto; Portugal
Fil: Órfão, José J.M.. Universidad de Porto; Portugal
Fil: Calvino, Jose J.. Universidad de Cádiz; España
Fil: Chen, Xiaowei. Universidad de Cádiz; España
Materia
Glycerol Oxidation
Gold
Palladium
Bimetallic Catalyst
Ceria-Zirconia
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/46870
Acceder
id CONICETDig_65fd83376169fb5edf982f336b0b4d5f
oai_identifier_str oai:ri.conicet.gov.ar:11336/46870
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Synergistic effect of bimetallic Au-Pd supported on ceria-zirconia mixed oxide catalysts for selective oxidation of glycerolOlmos Carreno, Carol MaritzaChinchilla, Lidia E.Rodrigues, Elodie G.Delgado, Juan J.Hungría, Ana B.Blanco, GinesaPereira, Manuel F.R.Órfão, José J.M.Calvino, Jose J.Chen, XiaoweiGlycerol OxidationGoldPalladiumBimetallic CatalystCeria-Zirconiahttps://purl.org/becyt/ford/2.7https://purl.org/becyt/ford/2A series of bimetallic Au-Pd catalysts supported on Ce0.62Zr0.38O2mixed oxide has been synthesized usinga simultaneous deposition-precipitation method. Different Au:Pd ratios were obtained maintaining Auloadings constant and varying Pd content. Elemental analysis, X-ray diffraction, N2physisorption,X-rayphotoelectron spectroscopy, scanning transmission electron microscopy-high angle annular dark field(STEM-HAADF) and X-ray energy dispersive spectroscopy (XEDS) techniques have been employed tocharacterize these catalysts. The catalytic activities for selective oxidation of glycerol over these bimetalliccatalysts have been evaluated, a synergistic effect being observed. Thus, the bimetallic Au-Pd catalystwith the lowest Pd content was the one exhibiting the highest catalytic activity among all the preparedcatalysts. Oxidation at 700◦C of the bimetallic 2.2AuPd/Ce0.62Zr0.38O2catalyst led to an increase of thecatalytic activity for the selective oxidation of glycerol, which seemed to be due to the formation of alarger fraction of bimetallic Au-Pd alloy-type nanoparticles after oxidation at higher temperatures.Fil: Olmos Carreno, Carol Maritza. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Cádiz; EspañaFil: Chinchilla, Lidia E.. Universidad de Cádiz; EspañaFil: Rodrigues, Elodie G.. Universidad de Porto; PortugalFil: Delgado, Juan J.. Universidad de Cádiz; EspañaFil: Hungría, Ana B.. Universidad de Cádiz; EspañaFil: Blanco, Ginesa. Universidad de Cádiz; EspañaFil: Pereira, Manuel F.R.. Universidad de Porto; PortugalFil: Órfão, José J.M.. Universidad de Porto; PortugalFil: Calvino, Jose J.. Universidad de Cádiz; EspañaFil: Chen, Xiaowei. Universidad de Cádiz; EspañaElsevier Science2016-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/46870Olmos Carreno, Carol Maritza; Chinchilla, Lidia E.; Rodrigues, Elodie G.; Delgado, Juan J.; Hungría, Ana B.; et al.; Synergistic effect of bimetallic Au-Pd supported on ceria-zirconia mixed oxide catalysts for selective oxidation of glycerol; Elsevier Science; Applied Catalysis B: Environmental; 197; 11-2016; 222-2350926-3373CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcatb.2016.03.050info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S092633731630232info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:59:01Zoai:ri.conicet.gov.ar:11336/46870instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:59:01.696CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synergistic effect of bimetallic Au-Pd supported on ceria-zirconia mixed oxide catalysts for selective oxidation of glycerol
title Synergistic effect of bimetallic Au-Pd supported on ceria-zirconia mixed oxide catalysts for selective oxidation of glycerol
spellingShingle Synergistic effect of bimetallic Au-Pd supported on ceria-zirconia mixed oxide catalysts for selective oxidation of glycerol
Olmos Carreno, Carol Maritza
Glycerol Oxidation
Gold
Palladium
Bimetallic Catalyst
Ceria-Zirconia
title_short Synergistic effect of bimetallic Au-Pd supported on ceria-zirconia mixed oxide catalysts for selective oxidation of glycerol
title_full Synergistic effect of bimetallic Au-Pd supported on ceria-zirconia mixed oxide catalysts for selective oxidation of glycerol
title_fullStr Synergistic effect of bimetallic Au-Pd supported on ceria-zirconia mixed oxide catalysts for selective oxidation of glycerol
title_full_unstemmed Synergistic effect of bimetallic Au-Pd supported on ceria-zirconia mixed oxide catalysts for selective oxidation of glycerol
title_sort Synergistic effect of bimetallic Au-Pd supported on ceria-zirconia mixed oxide catalysts for selective oxidation of glycerol
dc.creator.none.fl_str_mv Olmos Carreno, Carol Maritza
Chinchilla, Lidia E.
Rodrigues, Elodie G.
Delgado, Juan J.
Hungría, Ana B.
Blanco, Ginesa
Pereira, Manuel F.R.
Órfão, José J.M.
Calvino, Jose J.
Chen, Xiaowei
author Olmos Carreno, Carol Maritza
author_facet Olmos Carreno, Carol Maritza
Chinchilla, Lidia E.
Rodrigues, Elodie G.
Delgado, Juan J.
Hungría, Ana B.
Blanco, Ginesa
Pereira, Manuel F.R.
Órfão, José J.M.
Calvino, Jose J.
Chen, Xiaowei
author_role author
author2 Chinchilla, Lidia E.
Rodrigues, Elodie G.
Delgado, Juan J.
Hungría, Ana B.
Blanco, Ginesa
Pereira, Manuel F.R.
Órfão, José J.M.
Calvino, Jose J.
Chen, Xiaowei
author2_role author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Glycerol Oxidation
Gold
Palladium
Bimetallic Catalyst
Ceria-Zirconia
topic Glycerol Oxidation
Gold
Palladium
Bimetallic Catalyst
Ceria-Zirconia
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.7
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv A series of bimetallic Au-Pd catalysts supported on Ce0.62Zr0.38O2mixed oxide has been synthesized usinga simultaneous deposition-precipitation method. Different Au:Pd ratios were obtained maintaining Auloadings constant and varying Pd content. Elemental analysis, X-ray diffraction, N2physisorption,X-rayphotoelectron spectroscopy, scanning transmission electron microscopy-high angle annular dark field(STEM-HAADF) and X-ray energy dispersive spectroscopy (XEDS) techniques have been employed tocharacterize these catalysts. The catalytic activities for selective oxidation of glycerol over these bimetalliccatalysts have been evaluated, a synergistic effect being observed. Thus, the bimetallic Au-Pd catalystwith the lowest Pd content was the one exhibiting the highest catalytic activity among all the preparedcatalysts. Oxidation at 700◦C of the bimetallic 2.2AuPd/Ce0.62Zr0.38O2catalyst led to an increase of thecatalytic activity for the selective oxidation of glycerol, which seemed to be due to the formation of alarger fraction of bimetallic Au-Pd alloy-type nanoparticles after oxidation at higher temperatures.
Fil: Olmos Carreno, Carol Maritza. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Cádiz; España
Fil: Chinchilla, Lidia E.. Universidad de Cádiz; España
Fil: Rodrigues, Elodie G.. Universidad de Porto; Portugal
Fil: Delgado, Juan J.. Universidad de Cádiz; España
Fil: Hungría, Ana B.. Universidad de Cádiz; España
Fil: Blanco, Ginesa. Universidad de Cádiz; España
Fil: Pereira, Manuel F.R.. Universidad de Porto; Portugal
Fil: Órfão, José J.M.. Universidad de Porto; Portugal
Fil: Calvino, Jose J.. Universidad de Cádiz; España
Fil: Chen, Xiaowei. Universidad de Cádiz; España
description A series of bimetallic Au-Pd catalysts supported on Ce0.62Zr0.38O2mixed oxide has been synthesized usinga simultaneous deposition-precipitation method. Different Au:Pd ratios were obtained maintaining Auloadings constant and varying Pd content. Elemental analysis, X-ray diffraction, N2physisorption,X-rayphotoelectron spectroscopy, scanning transmission electron microscopy-high angle annular dark field(STEM-HAADF) and X-ray energy dispersive spectroscopy (XEDS) techniques have been employed tocharacterize these catalysts. The catalytic activities for selective oxidation of glycerol over these bimetalliccatalysts have been evaluated, a synergistic effect being observed. Thus, the bimetallic Au-Pd catalystwith the lowest Pd content was the one exhibiting the highest catalytic activity among all the preparedcatalysts. Oxidation at 700◦C of the bimetallic 2.2AuPd/Ce0.62Zr0.38O2catalyst led to an increase of thecatalytic activity for the selective oxidation of glycerol, which seemed to be due to the formation of alarger fraction of bimetallic Au-Pd alloy-type nanoparticles after oxidation at higher temperatures.
publishDate 2016
dc.date.none.fl_str_mv 2016-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/46870
Olmos Carreno, Carol Maritza; Chinchilla, Lidia E.; Rodrigues, Elodie G.; Delgado, Juan J.; Hungría, Ana B.; et al.; Synergistic effect of bimetallic Au-Pd supported on ceria-zirconia mixed oxide catalysts for selective oxidation of glycerol; Elsevier Science; Applied Catalysis B: Environmental; 197; 11-2016; 222-235
0926-3373
CONICET Digital
CONICET
url http://hdl.handle.net/11336/46870
identifier_str_mv Olmos Carreno, Carol Maritza; Chinchilla, Lidia E.; Rodrigues, Elodie G.; Delgado, Juan J.; Hungría, Ana B.; et al.; Synergistic effect of bimetallic Au-Pd supported on ceria-zirconia mixed oxide catalysts for selective oxidation of glycerol; Elsevier Science; Applied Catalysis B: Environmental; 197; 11-2016; 222-235
0926-3373
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcatb.2016.03.050
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S092633731630232
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842269556326793216
score 13.13397

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