Hydrodechlorination of dichloromethane with mono- and bimetallic Pd-Pt on sulfated and tungstated zirconia catalysts

Autores
Bedía, J.; Gómez Sainero, L.M.; Grau, Javier Mario; Busto, Mariana; Martín Martinez, M.; Rodriguez Jimenez, J.J.
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Monometallic (Pt or Pd) and bimetallic (Pt–Pd) catalysts supported on zirconia promoted with sulfate (SZ) or tungsten oxide (WZ) were prepared and tested in the gas-phase hydrodechlorination of dichloromethane. The catalysts showed a high selectivity to non-chlorinated products (between 80% and 90% at 250 C) being methane the main reaction product. As a general trend, the WZ catalysts yielded significantly higher dichloromethane conversion than the SZ ones, yielding all the catalysts initial conversions higher than 80% at a reaction temperature of 250 C. However, the former showed a very poor stability regardless of the metallic active phase. On the other hand, the presence of palladium in the sulfated zirconia catalyst avoids deactivation as proved in long-term experiments (80-h time on stream). XPS and elemental analyses of the used catalysts suggest that adsorption of organochlorinated species is a cause of deactivation by blocking the active sites. In the monometallic SZ Pt catalyst, deactivation occurs also by poisoning of the Pt sites by the H2S resulting from sulfate reduction under the hydrogen-rich gas atmosphere. The metal particle size appears to be a critical point with regard to stability of the catalysts. The one with the highest dispersion showed the highest stability with no signs of deactivation after more than 80 h on stream.
Fil: Bedía, J.. Universidad Autónoma de Madrid. Facultad de Ciencias; España
Fil: Gómez Sainero, L.M.. Universidad Autónoma de Madrid. Facultad de Ciencias; España
Fil: Grau, Javier Mario. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Busto, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Martín Martinez, M.. Universidad Autónoma de Madrid. Facultad de Ciencias; España
Fil: Rodriguez Jimenez, J.J.. Universidad Autónoma de Madrid. Facultad de Ciencias; España
Materia
Sulfated Zirconia
Tungstated Zirconia
Hydrodechlorination
Dichloromethane
Palladium
Platinum
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/52362
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/52362
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Hydrodechlorination of dichloromethane with mono- and bimetallic Pd-Pt on sulfated and tungstated zirconia catalystsBedía, J.Gómez Sainero, L.M.Grau, Javier MarioBusto, MarianaMartín Martinez, M.Rodriguez Jimenez, J.J.Sulfated ZirconiaTungstated ZirconiaHydrodechlorinationDichloromethanePalladiumPlatinumhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Monometallic (Pt or Pd) and bimetallic (Pt–Pd) catalysts supported on zirconia promoted with sulfate (SZ) or tungsten oxide (WZ) were prepared and tested in the gas-phase hydrodechlorination of dichloromethane. The catalysts showed a high selectivity to non-chlorinated products (between 80% and 90% at 250 C) being methane the main reaction product. As a general trend, the WZ catalysts yielded significantly higher dichloromethane conversion than the SZ ones, yielding all the catalysts initial conversions higher than 80% at a reaction temperature of 250 C. However, the former showed a very poor stability regardless of the metallic active phase. On the other hand, the presence of palladium in the sulfated zirconia catalyst avoids deactivation as proved in long-term experiments (80-h time on stream). XPS and elemental analyses of the used catalysts suggest that adsorption of organochlorinated species is a cause of deactivation by blocking the active sites. In the monometallic SZ Pt catalyst, deactivation occurs also by poisoning of the Pt sites by the H2S resulting from sulfate reduction under the hydrogen-rich gas atmosphere. The metal particle size appears to be a critical point with regard to stability of the catalysts. The one with the highest dispersion showed the highest stability with no signs of deactivation after more than 80 h on stream.Fil: Bedía, J.. Universidad Autónoma de Madrid. Facultad de Ciencias; EspañaFil: Gómez Sainero, L.M.. Universidad Autónoma de Madrid. Facultad de Ciencias; EspañaFil: Grau, Javier Mario. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Busto, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Martín Martinez, M.. Universidad Autónoma de Madrid. Facultad de Ciencias; EspañaFil: Rodriguez Jimenez, J.J.. Universidad Autónoma de Madrid. Facultad de Ciencias; EspañaAcademic Press Inc Elsevier Science2012-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/52362Bedía, J.; Gómez Sainero, L.M.; Grau, Javier Mario; Busto, Mariana; Martín Martinez, M.; et al.; Hydrodechlorination of dichloromethane with mono- and bimetallic Pd-Pt on sulfated and tungstated zirconia catalysts; Academic Press Inc Elsevier Science; Journal of Catalysis; 294; 7-2012; 207-2150021-9517CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S002195171200228Xinfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jcat.2012.07.023info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:53:11Zoai:ri.conicet.gov.ar:11336/52362instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:53:12.162CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Hydrodechlorination of dichloromethane with mono- and bimetallic Pd-Pt on sulfated and tungstated zirconia catalysts
title Hydrodechlorination of dichloromethane with mono- and bimetallic Pd-Pt on sulfated and tungstated zirconia catalysts
spellingShingle Hydrodechlorination of dichloromethane with mono- and bimetallic Pd-Pt on sulfated and tungstated zirconia catalysts
Bedía, J.
Sulfated Zirconia
Tungstated Zirconia
Hydrodechlorination
Dichloromethane
Palladium
Platinum
title_short Hydrodechlorination of dichloromethane with mono- and bimetallic Pd-Pt on sulfated and tungstated zirconia catalysts
title_full Hydrodechlorination of dichloromethane with mono- and bimetallic Pd-Pt on sulfated and tungstated zirconia catalysts
title_fullStr Hydrodechlorination of dichloromethane with mono- and bimetallic Pd-Pt on sulfated and tungstated zirconia catalysts
title_full_unstemmed Hydrodechlorination of dichloromethane with mono- and bimetallic Pd-Pt on sulfated and tungstated zirconia catalysts
title_sort Hydrodechlorination of dichloromethane with mono- and bimetallic Pd-Pt on sulfated and tungstated zirconia catalysts
dc.creator.none.fl_str_mv Bedía, J.
Gómez Sainero, L.M.
Grau, Javier Mario
Busto, Mariana
Martín Martinez, M.
Rodriguez Jimenez, J.J.
author Bedía, J.
author_facet Bedía, J.
Gómez Sainero, L.M.
Grau, Javier Mario
Busto, Mariana
Martín Martinez, M.
Rodriguez Jimenez, J.J.
author_role author
author2 Gómez Sainero, L.M.
Grau, Javier Mario
Busto, Mariana
Martín Martinez, M.
Rodriguez Jimenez, J.J.
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Sulfated Zirconia
Tungstated Zirconia
Hydrodechlorination
Dichloromethane
Palladium
Platinum
topic Sulfated Zirconia
Tungstated Zirconia
Hydrodechlorination
Dichloromethane
Palladium
Platinum
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Monometallic (Pt or Pd) and bimetallic (Pt–Pd) catalysts supported on zirconia promoted with sulfate (SZ) or tungsten oxide (WZ) were prepared and tested in the gas-phase hydrodechlorination of dichloromethane. The catalysts showed a high selectivity to non-chlorinated products (between 80% and 90% at 250 C) being methane the main reaction product. As a general trend, the WZ catalysts yielded significantly higher dichloromethane conversion than the SZ ones, yielding all the catalysts initial conversions higher than 80% at a reaction temperature of 250 C. However, the former showed a very poor stability regardless of the metallic active phase. On the other hand, the presence of palladium in the sulfated zirconia catalyst avoids deactivation as proved in long-term experiments (80-h time on stream). XPS and elemental analyses of the used catalysts suggest that adsorption of organochlorinated species is a cause of deactivation by blocking the active sites. In the monometallic SZ Pt catalyst, deactivation occurs also by poisoning of the Pt sites by the H2S resulting from sulfate reduction under the hydrogen-rich gas atmosphere. The metal particle size appears to be a critical point with regard to stability of the catalysts. The one with the highest dispersion showed the highest stability with no signs of deactivation after more than 80 h on stream.
Fil: Bedía, J.. Universidad Autónoma de Madrid. Facultad de Ciencias; España
Fil: Gómez Sainero, L.M.. Universidad Autónoma de Madrid. Facultad de Ciencias; España
Fil: Grau, Javier Mario. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Busto, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Martín Martinez, M.. Universidad Autónoma de Madrid. Facultad de Ciencias; España
Fil: Rodriguez Jimenez, J.J.. Universidad Autónoma de Madrid. Facultad de Ciencias; España
description Monometallic (Pt or Pd) and bimetallic (Pt–Pd) catalysts supported on zirconia promoted with sulfate (SZ) or tungsten oxide (WZ) were prepared and tested in the gas-phase hydrodechlorination of dichloromethane. The catalysts showed a high selectivity to non-chlorinated products (between 80% and 90% at 250 C) being methane the main reaction product. As a general trend, the WZ catalysts yielded significantly higher dichloromethane conversion than the SZ ones, yielding all the catalysts initial conversions higher than 80% at a reaction temperature of 250 C. However, the former showed a very poor stability regardless of the metallic active phase. On the other hand, the presence of palladium in the sulfated zirconia catalyst avoids deactivation as proved in long-term experiments (80-h time on stream). XPS and elemental analyses of the used catalysts suggest that adsorption of organochlorinated species is a cause of deactivation by blocking the active sites. In the monometallic SZ Pt catalyst, deactivation occurs also by poisoning of the Pt sites by the H2S resulting from sulfate reduction under the hydrogen-rich gas atmosphere. The metal particle size appears to be a critical point with regard to stability of the catalysts. The one with the highest dispersion showed the highest stability with no signs of deactivation after more than 80 h on stream.
publishDate 2012
dc.date.none.fl_str_mv 2012-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/52362
Bedía, J.; Gómez Sainero, L.M.; Grau, Javier Mario; Busto, Mariana; Martín Martinez, M.; et al.; Hydrodechlorination of dichloromethane with mono- and bimetallic Pd-Pt on sulfated and tungstated zirconia catalysts; Academic Press Inc Elsevier Science; Journal of Catalysis; 294; 7-2012; 207-215
0021-9517
CONICET Digital
CONICET
url http://hdl.handle.net/11336/52362
identifier_str_mv Bedía, J.; Gómez Sainero, L.M.; Grau, Javier Mario; Busto, Mariana; Martín Martinez, M.; et al.; Hydrodechlorination of dichloromethane with mono- and bimetallic Pd-Pt on sulfated and tungstated zirconia catalysts; Academic Press Inc Elsevier Science; Journal of Catalysis; 294; 7-2012; 207-215
0021-9517
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S002195171200228X
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jcat.2012.07.023
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Academic Press Inc Elsevier Science
publisher.none.fl_str_mv Academic Press Inc Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842269207697293312
score 13.13397

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