Infrared spectroscopy studies on stability of dimethyl sulfoxide for application in a LI-air battery

Autores
Mozhzhukhina, Nataliia; Méndez de Leo, Lucila Paula; Calvo, Ernesto Julio
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In situ infrared subtractive normalized Fourier transform infrared spectroscopy (SNIFTIRS) experiments performed simultaneously with the electroreduction of oxygen on gold and platinum cathodes in LiPF6 dimethyl sulfoxide (DMSO) electrolyte have shown that the solvent is stable with respect to nucleophilic attack by the electrogenerated superoxide radical anion. However, long-term experiments with KO2 solutions in DMSO have shown a slow formation of dimethyl sulfone. Evidence of dimethyl sulfone formation by anodic oxidation of DMSO above 4.2 V (Li/Li+) in the presence of trace water has been obtained on gold. On platinum, this unwanted reaction in the charging cycle of a lithium−air battery takes place at lower potentials, i.e., 3.5 V.
Fil: Mozhzhukhina, Nataliia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina. Universidad de Buenos Aires; Argentina
Fil: Méndez de Leo, Lucila Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina. Universidad de Buenos Aires; Argentina
Fil: Calvo, Ernesto Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina. Universidad de Buenos Aires; Argentina
Materia
Lithium
Dimethyl Sulfoxide
Oxygen
Dimethyl Sulfone
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/8281
Acceder
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spelling Infrared spectroscopy studies on stability of dimethyl sulfoxide for application in a LI-air batteryMozhzhukhina, NataliiaMéndez de Leo, Lucila PaulaCalvo, Ernesto JulioLithiumDimethyl SulfoxideOxygenDimethyl Sulfonehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1In situ infrared subtractive normalized Fourier transform infrared spectroscopy (SNIFTIRS) experiments performed simultaneously with the electroreduction of oxygen on gold and platinum cathodes in LiPF6 dimethyl sulfoxide (DMSO) electrolyte have shown that the solvent is stable with respect to nucleophilic attack by the electrogenerated superoxide radical anion. However, long-term experiments with KO2 solutions in DMSO have shown a slow formation of dimethyl sulfone. Evidence of dimethyl sulfone formation by anodic oxidation of DMSO above 4.2 V (Li/Li+) in the presence of trace water has been obtained on gold. On platinum, this unwanted reaction in the charging cycle of a lithium−air battery takes place at lower potentials, i.e., 3.5 V.Fil: Mozhzhukhina, Nataliia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina. Universidad de Buenos Aires; ArgentinaFil: Méndez de Leo, Lucila Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina. Universidad de Buenos Aires; ArgentinaFil: Calvo, Ernesto Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina. Universidad de Buenos Aires; ArgentinaAmerican Chemical Society2013-08-21info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/8281Mozhzhukhina, Nataliia; Méndez de Leo, Lucila Paula; Calvo, Ernesto Julio; Infrared spectroscopy studies on stability of dimethyl sulfoxide for application in a LI-air battery; American Chemical Society; Journal Of Physical Chemistry C; 117; 36; 21-8-2013; 18375-183801932-7447enginfo:eu-repo/semantics/altIdentifier/doi/10.1021/jp407221cinfo:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/jp407221cinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:55:45Zoai:ri.conicet.gov.ar:11336/8281instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:55:46.015CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Infrared spectroscopy studies on stability of dimethyl sulfoxide for application in a LI-air battery
title Infrared spectroscopy studies on stability of dimethyl sulfoxide for application in a LI-air battery
spellingShingle Infrared spectroscopy studies on stability of dimethyl sulfoxide for application in a LI-air battery
Mozhzhukhina, Nataliia
Lithium
Dimethyl Sulfoxide
Oxygen
Dimethyl Sulfone
title_short Infrared spectroscopy studies on stability of dimethyl sulfoxide for application in a LI-air battery
title_full Infrared spectroscopy studies on stability of dimethyl sulfoxide for application in a LI-air battery
title_fullStr Infrared spectroscopy studies on stability of dimethyl sulfoxide for application in a LI-air battery
title_full_unstemmed Infrared spectroscopy studies on stability of dimethyl sulfoxide for application in a LI-air battery
title_sort Infrared spectroscopy studies on stability of dimethyl sulfoxide for application in a LI-air battery
dc.creator.none.fl_str_mv Mozhzhukhina, Nataliia
Méndez de Leo, Lucila Paula
Calvo, Ernesto Julio
author Mozhzhukhina, Nataliia
author_facet Mozhzhukhina, Nataliia
Méndez de Leo, Lucila Paula
Calvo, Ernesto Julio
author_role author
author2 Méndez de Leo, Lucila Paula
Calvo, Ernesto Julio
author2_role author
author
dc.subject.none.fl_str_mv Lithium
Dimethyl Sulfoxide
Oxygen
Dimethyl Sulfone
topic Lithium
Dimethyl Sulfoxide
Oxygen
Dimethyl Sulfone
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv In situ infrared subtractive normalized Fourier transform infrared spectroscopy (SNIFTIRS) experiments performed simultaneously with the electroreduction of oxygen on gold and platinum cathodes in LiPF6 dimethyl sulfoxide (DMSO) electrolyte have shown that the solvent is stable with respect to nucleophilic attack by the electrogenerated superoxide radical anion. However, long-term experiments with KO2 solutions in DMSO have shown a slow formation of dimethyl sulfone. Evidence of dimethyl sulfone formation by anodic oxidation of DMSO above 4.2 V (Li/Li+) in the presence of trace water has been obtained on gold. On platinum, this unwanted reaction in the charging cycle of a lithium−air battery takes place at lower potentials, i.e., 3.5 V.
Fil: Mozhzhukhina, Nataliia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina. Universidad de Buenos Aires; Argentina
Fil: Méndez de Leo, Lucila Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina. Universidad de Buenos Aires; Argentina
Fil: Calvo, Ernesto Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina. Universidad de Buenos Aires; Argentina
description In situ infrared subtractive normalized Fourier transform infrared spectroscopy (SNIFTIRS) experiments performed simultaneously with the electroreduction of oxygen on gold and platinum cathodes in LiPF6 dimethyl sulfoxide (DMSO) electrolyte have shown that the solvent is stable with respect to nucleophilic attack by the electrogenerated superoxide radical anion. However, long-term experiments with KO2 solutions in DMSO have shown a slow formation of dimethyl sulfone. Evidence of dimethyl sulfone formation by anodic oxidation of DMSO above 4.2 V (Li/Li+) in the presence of trace water has been obtained on gold. On platinum, this unwanted reaction in the charging cycle of a lithium−air battery takes place at lower potentials, i.e., 3.5 V.
publishDate 2013
dc.date.none.fl_str_mv 2013-08-21
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/8281
Mozhzhukhina, Nataliia; Méndez de Leo, Lucila Paula; Calvo, Ernesto Julio; Infrared spectroscopy studies on stability of dimethyl sulfoxide for application in a LI-air battery; American Chemical Society; Journal Of Physical Chemistry C; 117; 36; 21-8-2013; 18375-18380
1932-7447
url http://hdl.handle.net/11336/8281
identifier_str_mv Mozhzhukhina, Nataliia; Méndez de Leo, Lucila Paula; Calvo, Ernesto Julio; Infrared spectroscopy studies on stability of dimethyl sulfoxide for application in a LI-air battery; American Chemical Society; Journal Of Physical Chemistry C; 117; 36; 21-8-2013; 18375-18380
1932-7447
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/jp407221c
info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/jp407221c
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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