Synthesis and characterization of a Cu(II) complex of 2-benzylmercapto-5- methyl-1,3,4-thiadiazole (C10H10N2S 2)

Autores
Camí, Gerardo E.; González, Malva Liu; Ruiz, Francisco Sanz; De Arellano, Carmen Ramírez; Sanchez, Rodolfo Daniel; Pedregosa, Jose Carmelo
Año de publicación
2008
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A Cu(II) complex of 2-benzylmercapto-5-methyl-1,3,4-thiadiazole was synthesized and characterized. The crystal structure of the copper complex and the free ligand were determined by single-crystal X-ray diffraction at room temperature: {[Cu(C10H10N2S2) 2(Cl)2], P1 triclinic, a = 8.1450(2) Å, b = 8.1690(2) Å, c = 10.8180(3) Å, α = 97.4040(12)°, β = 101.6270(11)°, γ = 116.1431(14)°; C10H10N2S2 ligand, Pbca orthorhombic, a = 8.7938(7) Å, b = 9.6491(7) Å, c = 25.3552(18) Å}. The metal complex framework consists of discrete units that provide crystalline stability through a network of van der Waals contacts. The Cu(II) is coordinated by two chloride ions and two 2-benzylmercapto-5-methyl-1,3,4- thiadiazole monodentate ligands showing a distorted square planar configuration. Both thiadiazole ligands coordinate through the N atom bonded to the benzylthio substituted C atom. The FTIR spectroscopic data are consistent with this structural model. Analysis of the magnetic susceptibility from 5 K to room temperature indicates the presence of paramagnetic Cu(II), confirmed by the EPR spectrum.
Fil: Camí, Gerardo E.. Universidad Nacional de San Luis; Argentina
Fil: González, Malva Liu. Universidad de Valencia; España
Fil: Ruiz, Francisco Sanz. Universidad de Valencia; España
Fil: De Arellano, Carmen Ramírez. Universidad de Valencia; España
Fil: Sanchez, Rodolfo Daniel. Universidad Nacional de Cuyo; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Area de Investigación y Aplicaciones No Nucleares. Gerencia de Física (Centro Atómico Bariloche); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Pedregosa, Jose Carmelo. Universidad Nacional de San Luis; Argentina
Materia
2-Benzylmercapto-5-Methyl-1,3,4-Thiadiazole
Crystal Structure
Cu(Ii) Complexes
Magnetic Behavior
Spectroscopic Behavior
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/68579
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/68579
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Synthesis and characterization of a Cu(II) complex of 2-benzylmercapto-5- methyl-1,3,4-thiadiazole (C10H10N2S 2)Camí, Gerardo E.González, Malva LiuRuiz, Francisco SanzDe Arellano, Carmen RamírezSanchez, Rodolfo DanielPedregosa, Jose Carmelo2-Benzylmercapto-5-Methyl-1,3,4-ThiadiazoleCrystal StructureCu(Ii) ComplexesMagnetic BehaviorSpectroscopic Behaviorhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1A Cu(II) complex of 2-benzylmercapto-5-methyl-1,3,4-thiadiazole was synthesized and characterized. The crystal structure of the copper complex and the free ligand were determined by single-crystal X-ray diffraction at room temperature: {[Cu(C10H10N2S2) 2(Cl)2], P1 triclinic, a = 8.1450(2) Å, b = 8.1690(2) Å, c = 10.8180(3) Å, α = 97.4040(12)°, β = 101.6270(11)°, γ = 116.1431(14)°; C10H10N2S2 ligand, Pbca orthorhombic, a = 8.7938(7) Å, b = 9.6491(7) Å, c = 25.3552(18) Å}. The metal complex framework consists of discrete units that provide crystalline stability through a network of van der Waals contacts. The Cu(II) is coordinated by two chloride ions and two 2-benzylmercapto-5-methyl-1,3,4- thiadiazole monodentate ligands showing a distorted square planar configuration. Both thiadiazole ligands coordinate through the N atom bonded to the benzylthio substituted C atom. The FTIR spectroscopic data are consistent with this structural model. Analysis of the magnetic susceptibility from 5 K to room temperature indicates the presence of paramagnetic Cu(II), confirmed by the EPR spectrum.Fil: Camí, Gerardo E.. Universidad Nacional de San Luis; ArgentinaFil: González, Malva Liu. Universidad de Valencia; EspañaFil: Ruiz, Francisco Sanz. Universidad de Valencia; EspañaFil: De Arellano, Carmen Ramírez. Universidad de Valencia; EspañaFil: Sanchez, Rodolfo Daniel. Universidad Nacional de Cuyo; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Area de Investigación y Aplicaciones No Nucleares. Gerencia de Física (Centro Atómico Bariloche); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Pedregosa, Jose Carmelo. Universidad Nacional de San Luis; ArgentinaTaylor & Francis Ltd2008-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/68579Camí, Gerardo E.; González, Malva Liu; Ruiz, Francisco Sanz; De Arellano, Carmen Ramírez; Sanchez, Rodolfo Daniel; et al.; Synthesis and characterization of a Cu(II) complex of 2-benzylmercapto-5- methyl-1,3,4-thiadiazole (C10H10N2S 2); Taylor & Francis Ltd; Journal of Coordination Chemistry; 61; 19; 10-2008; 3122-31330095-8972CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1080/00958970802007910info:eu-repo/semantics/altIdentifier/url/https://www.tandfonline.com/doi/abs/10.1080/00958970802007910info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:53:47Zoai:ri.conicet.gov.ar:11336/68579instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:53:47.957CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synthesis and characterization of a Cu(II) complex of 2-benzylmercapto-5- methyl-1,3,4-thiadiazole (C10H10N2S 2)
title Synthesis and characterization of a Cu(II) complex of 2-benzylmercapto-5- methyl-1,3,4-thiadiazole (C10H10N2S 2)
spellingShingle Synthesis and characterization of a Cu(II) complex of 2-benzylmercapto-5- methyl-1,3,4-thiadiazole (C10H10N2S 2)
Camí, Gerardo E.
2-Benzylmercapto-5-Methyl-1,3,4-Thiadiazole
Crystal Structure
Cu(Ii) Complexes
Magnetic Behavior
Spectroscopic Behavior
title_short Synthesis and characterization of a Cu(II) complex of 2-benzylmercapto-5- methyl-1,3,4-thiadiazole (C10H10N2S 2)
title_full Synthesis and characterization of a Cu(II) complex of 2-benzylmercapto-5- methyl-1,3,4-thiadiazole (C10H10N2S 2)
title_fullStr Synthesis and characterization of a Cu(II) complex of 2-benzylmercapto-5- methyl-1,3,4-thiadiazole (C10H10N2S 2)
title_full_unstemmed Synthesis and characterization of a Cu(II) complex of 2-benzylmercapto-5- methyl-1,3,4-thiadiazole (C10H10N2S 2)
title_sort Synthesis and characterization of a Cu(II) complex of 2-benzylmercapto-5- methyl-1,3,4-thiadiazole (C10H10N2S 2)
dc.creator.none.fl_str_mv Camí, Gerardo E.
González, Malva Liu
Ruiz, Francisco Sanz
De Arellano, Carmen Ramírez
Sanchez, Rodolfo Daniel
Pedregosa, Jose Carmelo
author Camí, Gerardo E.
author_facet Camí, Gerardo E.
González, Malva Liu
Ruiz, Francisco Sanz
De Arellano, Carmen Ramírez
Sanchez, Rodolfo Daniel
Pedregosa, Jose Carmelo
author_role author
author2 González, Malva Liu
Ruiz, Francisco Sanz
De Arellano, Carmen Ramírez
Sanchez, Rodolfo Daniel
Pedregosa, Jose Carmelo
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv 2-Benzylmercapto-5-Methyl-1,3,4-Thiadiazole
Crystal Structure
Cu(Ii) Complexes
Magnetic Behavior
Spectroscopic Behavior
topic 2-Benzylmercapto-5-Methyl-1,3,4-Thiadiazole
Crystal Structure
Cu(Ii) Complexes
Magnetic Behavior
Spectroscopic Behavior
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A Cu(II) complex of 2-benzylmercapto-5-methyl-1,3,4-thiadiazole was synthesized and characterized. The crystal structure of the copper complex and the free ligand were determined by single-crystal X-ray diffraction at room temperature: {[Cu(C10H10N2S2) 2(Cl)2], P1 triclinic, a = 8.1450(2) Å, b = 8.1690(2) Å, c = 10.8180(3) Å, α = 97.4040(12)°, β = 101.6270(11)°, γ = 116.1431(14)°; C10H10N2S2 ligand, Pbca orthorhombic, a = 8.7938(7) Å, b = 9.6491(7) Å, c = 25.3552(18) Å}. The metal complex framework consists of discrete units that provide crystalline stability through a network of van der Waals contacts. The Cu(II) is coordinated by two chloride ions and two 2-benzylmercapto-5-methyl-1,3,4- thiadiazole monodentate ligands showing a distorted square planar configuration. Both thiadiazole ligands coordinate through the N atom bonded to the benzylthio substituted C atom. The FTIR spectroscopic data are consistent with this structural model. Analysis of the magnetic susceptibility from 5 K to room temperature indicates the presence of paramagnetic Cu(II), confirmed by the EPR spectrum.
Fil: Camí, Gerardo E.. Universidad Nacional de San Luis; Argentina
Fil: González, Malva Liu. Universidad de Valencia; España
Fil: Ruiz, Francisco Sanz. Universidad de Valencia; España
Fil: De Arellano, Carmen Ramírez. Universidad de Valencia; España
Fil: Sanchez, Rodolfo Daniel. Universidad Nacional de Cuyo; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Area de Investigación y Aplicaciones No Nucleares. Gerencia de Física (Centro Atómico Bariloche); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Pedregosa, Jose Carmelo. Universidad Nacional de San Luis; Argentina
description A Cu(II) complex of 2-benzylmercapto-5-methyl-1,3,4-thiadiazole was synthesized and characterized. The crystal structure of the copper complex and the free ligand were determined by single-crystal X-ray diffraction at room temperature: {[Cu(C10H10N2S2) 2(Cl)2], P1 triclinic, a = 8.1450(2) Å, b = 8.1690(2) Å, c = 10.8180(3) Å, α = 97.4040(12)°, β = 101.6270(11)°, γ = 116.1431(14)°; C10H10N2S2 ligand, Pbca orthorhombic, a = 8.7938(7) Å, b = 9.6491(7) Å, c = 25.3552(18) Å}. The metal complex framework consists of discrete units that provide crystalline stability through a network of van der Waals contacts. The Cu(II) is coordinated by two chloride ions and two 2-benzylmercapto-5-methyl-1,3,4- thiadiazole monodentate ligands showing a distorted square planar configuration. Both thiadiazole ligands coordinate through the N atom bonded to the benzylthio substituted C atom. The FTIR spectroscopic data are consistent with this structural model. Analysis of the magnetic susceptibility from 5 K to room temperature indicates the presence of paramagnetic Cu(II), confirmed by the EPR spectrum.
publishDate 2008
dc.date.none.fl_str_mv 2008-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/68579
Camí, Gerardo E.; González, Malva Liu; Ruiz, Francisco Sanz; De Arellano, Carmen Ramírez; Sanchez, Rodolfo Daniel; et al.; Synthesis and characterization of a Cu(II) complex of 2-benzylmercapto-5- methyl-1,3,4-thiadiazole (C10H10N2S 2); Taylor & Francis Ltd; Journal of Coordination Chemistry; 61; 19; 10-2008; 3122-3133
0095-8972
CONICET Digital
CONICET
url http://hdl.handle.net/11336/68579
identifier_str_mv Camí, Gerardo E.; González, Malva Liu; Ruiz, Francisco Sanz; De Arellano, Carmen Ramírez; Sanchez, Rodolfo Daniel; et al.; Synthesis and characterization of a Cu(II) complex of 2-benzylmercapto-5- methyl-1,3,4-thiadiazole (C10H10N2S 2); Taylor & Francis Ltd; Journal of Coordination Chemistry; 61; 19; 10-2008; 3122-3133
0095-8972
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1080/00958970802007910
info:eu-repo/semantics/altIdentifier/url/https://www.tandfonline.com/doi/abs/10.1080/00958970802007910
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Taylor & Francis Ltd
publisher.none.fl_str_mv Taylor & Francis Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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