Carboxylate-Bridged Copper(II)-Lanthanide(III) Complexes [{Cu3Ln2(oda)6(H2O)6}.12H2O]n (Ln = Dy, Ho, Er, Y; oda = oxydiacetate

Autores
Rizzi, Alberto Claudio; Calvo, Rafael; Baggio, Ricardo Fortunato; Garland, María Teresa; Peña, Octavio; Perec, Mireille
Año de publicación
2002
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The hydrothermal reaction of Ln2O3 (Ln = Dy and Ho), Cu(OAc)2·2H2O, and oxydiacetic acid in the approximate mole ratio of 1:3:8 resulted in the formation of two new members of the isostructural series of polymers formulated as [{Cu3Ln2(oda)6(H2O)6}·12H2O]n, crystallizing in the hexagonal crystal system, space group P6/mcc (No. 192). Temperature-dependent magnetic susceptibilities and EPR spectra are reported for the heterometallic compounds Cu−Dy 1, Cu−Ho 2, Cu−Er 3, and Cu−Y 4. The results are discussed in terms of the structure of the compounds, the electronic properties of the lanthanide ions, and the exchange interactions between the magnetic ions.
Fil: Rizzi, Alberto Claudio. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas. Departamento de Física; Argentina
Fil: Calvo, Rafael. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica; Argentina
Fil: Garland, María Teresa. Universidad de Chile; Chile
Fil: Peña, Octavio. Universite de Rennes I; Francia
Fil: Perec, Mireille. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina
Materia
Epr
Cu(Ii)
Lanthanides
Complexes
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/30088
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/30088
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Carboxylate-Bridged Copper(II)-Lanthanide(III) Complexes [{Cu3Ln2(oda)6(H2O)6}.12H2O]n (Ln = Dy, Ho, Er, Y; oda = oxydiacetateRizzi, Alberto ClaudioCalvo, RafaelBaggio, Ricardo FortunatoGarland, María TeresaPeña, OctavioPerec, MireilleEprCu(Ii)LanthanidesComplexeshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The hydrothermal reaction of Ln2O3 (Ln = Dy and Ho), Cu(OAc)2·2H2O, and oxydiacetic acid in the approximate mole ratio of 1:3:8 resulted in the formation of two new members of the isostructural series of polymers formulated as [{Cu3Ln2(oda)6(H2O)6}·12H2O]n, crystallizing in the hexagonal crystal system, space group P6/mcc (No. 192). Temperature-dependent magnetic susceptibilities and EPR spectra are reported for the heterometallic compounds Cu−Dy 1, Cu−Ho 2, Cu−Er 3, and Cu−Y 4. The results are discussed in terms of the structure of the compounds, the electronic properties of the lanthanide ions, and the exchange interactions between the magnetic ions.Fil: Rizzi, Alberto Claudio. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas. Departamento de Física; ArgentinaFil: Calvo, Rafael. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica; ArgentinaFil: Garland, María Teresa. Universidad de Chile; ChileFil: Peña, Octavio. Universite de Rennes I; FranciaFil: Perec, Mireille. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; ArgentinaAmerican Chemical Society2002-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/30088Rizzi, Alberto Claudio; Calvo, Rafael; Baggio, Ricardo Fortunato; Garland, María Teresa; Peña, Octavio; et al.; Carboxylate-Bridged Copper(II)-Lanthanide(III) Complexes [{Cu3Ln2(oda)6(H2O)6}.12H2O]n (Ln = Dy, Ho, Er, Y; oda = oxydiacetate; American Chemical Society; Inorganic Chemistry; 41; 12-2002; 5609-56140020-1669CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/ic025754oinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:04:20Zoai:ri.conicet.gov.ar:11336/30088instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:04:20.488CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Carboxylate-Bridged Copper(II)-Lanthanide(III) Complexes [{Cu3Ln2(oda)6(H2O)6}.12H2O]n (Ln = Dy, Ho, Er, Y; oda = oxydiacetate
title Carboxylate-Bridged Copper(II)-Lanthanide(III) Complexes [{Cu3Ln2(oda)6(H2O)6}.12H2O]n (Ln = Dy, Ho, Er, Y; oda = oxydiacetate
spellingShingle Carboxylate-Bridged Copper(II)-Lanthanide(III) Complexes [{Cu3Ln2(oda)6(H2O)6}.12H2O]n (Ln = Dy, Ho, Er, Y; oda = oxydiacetate
Rizzi, Alberto Claudio
Epr
Cu(Ii)
Lanthanides
Complexes
title_short Carboxylate-Bridged Copper(II)-Lanthanide(III) Complexes [{Cu3Ln2(oda)6(H2O)6}.12H2O]n (Ln = Dy, Ho, Er, Y; oda = oxydiacetate
title_full Carboxylate-Bridged Copper(II)-Lanthanide(III) Complexes [{Cu3Ln2(oda)6(H2O)6}.12H2O]n (Ln = Dy, Ho, Er, Y; oda = oxydiacetate
title_fullStr Carboxylate-Bridged Copper(II)-Lanthanide(III) Complexes [{Cu3Ln2(oda)6(H2O)6}.12H2O]n (Ln = Dy, Ho, Er, Y; oda = oxydiacetate
title_full_unstemmed Carboxylate-Bridged Copper(II)-Lanthanide(III) Complexes [{Cu3Ln2(oda)6(H2O)6}.12H2O]n (Ln = Dy, Ho, Er, Y; oda = oxydiacetate
title_sort Carboxylate-Bridged Copper(II)-Lanthanide(III) Complexes [{Cu3Ln2(oda)6(H2O)6}.12H2O]n (Ln = Dy, Ho, Er, Y; oda = oxydiacetate
dc.creator.none.fl_str_mv Rizzi, Alberto Claudio
Calvo, Rafael
Baggio, Ricardo Fortunato
Garland, María Teresa
Peña, Octavio
Perec, Mireille
author Rizzi, Alberto Claudio
author_facet Rizzi, Alberto Claudio
Calvo, Rafael
Baggio, Ricardo Fortunato
Garland, María Teresa
Peña, Octavio
Perec, Mireille
author_role author
author2 Calvo, Rafael
Baggio, Ricardo Fortunato
Garland, María Teresa
Peña, Octavio
Perec, Mireille
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Epr
Cu(Ii)
Lanthanides
Complexes
topic Epr
Cu(Ii)
Lanthanides
Complexes
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The hydrothermal reaction of Ln2O3 (Ln = Dy and Ho), Cu(OAc)2·2H2O, and oxydiacetic acid in the approximate mole ratio of 1:3:8 resulted in the formation of two new members of the isostructural series of polymers formulated as [{Cu3Ln2(oda)6(H2O)6}·12H2O]n, crystallizing in the hexagonal crystal system, space group P6/mcc (No. 192). Temperature-dependent magnetic susceptibilities and EPR spectra are reported for the heterometallic compounds Cu−Dy 1, Cu−Ho 2, Cu−Er 3, and Cu−Y 4. The results are discussed in terms of the structure of the compounds, the electronic properties of the lanthanide ions, and the exchange interactions between the magnetic ions.
Fil: Rizzi, Alberto Claudio. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas. Departamento de Física; Argentina
Fil: Calvo, Rafael. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica; Argentina
Fil: Garland, María Teresa. Universidad de Chile; Chile
Fil: Peña, Octavio. Universite de Rennes I; Francia
Fil: Perec, Mireille. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina
description The hydrothermal reaction of Ln2O3 (Ln = Dy and Ho), Cu(OAc)2·2H2O, and oxydiacetic acid in the approximate mole ratio of 1:3:8 resulted in the formation of two new members of the isostructural series of polymers formulated as [{Cu3Ln2(oda)6(H2O)6}·12H2O]n, crystallizing in the hexagonal crystal system, space group P6/mcc (No. 192). Temperature-dependent magnetic susceptibilities and EPR spectra are reported for the heterometallic compounds Cu−Dy 1, Cu−Ho 2, Cu−Er 3, and Cu−Y 4. The results are discussed in terms of the structure of the compounds, the electronic properties of the lanthanide ions, and the exchange interactions between the magnetic ions.
publishDate 2002
dc.date.none.fl_str_mv 2002-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/30088
Rizzi, Alberto Claudio; Calvo, Rafael; Baggio, Ricardo Fortunato; Garland, María Teresa; Peña, Octavio; et al.; Carboxylate-Bridged Copper(II)-Lanthanide(III) Complexes [{Cu3Ln2(oda)6(H2O)6}.12H2O]n (Ln = Dy, Ho, Er, Y; oda = oxydiacetate; American Chemical Society; Inorganic Chemistry; 41; 12-2002; 5609-5614
0020-1669
CONICET Digital
CONICET
url http://hdl.handle.net/11336/30088
identifier_str_mv Rizzi, Alberto Claudio; Calvo, Rafael; Baggio, Ricardo Fortunato; Garland, María Teresa; Peña, Octavio; et al.; Carboxylate-Bridged Copper(II)-Lanthanide(III) Complexes [{Cu3Ln2(oda)6(H2O)6}.12H2O]n (Ln = Dy, Ho, Er, Y; oda = oxydiacetate; American Chemical Society; Inorganic Chemistry; 41; 12-2002; 5609-5614
0020-1669
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/ic025754o
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842269851763081216
score 13.13397

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