Effective Anisotropic Interactions in Spin Pairs Containing High-Spin Ions with Large Zero-Field Splitting

Autores
Neuman, Nicolás Ignacio
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Analytic and numeric derivations are made of the effective exchange and dipolar magnetic interactions between spin pairs containing S = 3/2 ions, such as high-spin Co(II), S = 5/2 ions, such as high-spin Fe(III) ions, experiencing zero-field splittings much larger than the interion interactions, or J = 15/2 ions such as Dy(III) with crystal-field splittings much larger than the interion interaction. These formulas allow for a simpler analysis of the magnetic properties of dimers containing high-spin ions.
Fil: Neuman, Nicolás Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Materia
Cobalt
Iron
High-Spin
Magnetic Interactions
Dysprosium
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/53939
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/53939
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Effective Anisotropic Interactions in Spin Pairs Containing High-Spin Ions with Large Zero-Field SplittingNeuman, Nicolás IgnacioCobaltIronHigh-SpinMagnetic InteractionsDysprosiumhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1Analytic and numeric derivations are made of the effective exchange and dipolar magnetic interactions between spin pairs containing S = 3/2 ions, such as high-spin Co(II), S = 5/2 ions, such as high-spin Fe(III) ions, experiencing zero-field splittings much larger than the interion interactions, or J = 15/2 ions such as Dy(III) with crystal-field splittings much larger than the interion interaction. These formulas allow for a simpler analysis of the magnetic properties of dimers containing high-spin ions.Fil: Neuman, Nicolás Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaAmerican Chemical Society2018-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/53939Neuman, Nicolás Ignacio; Effective Anisotropic Interactions in Spin Pairs Containing High-Spin Ions with Large Zero-Field Splitting; American Chemical Society; Journal of Physical Chemistry A; 122; 1; 1-2018; 234-2381089-5639CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/10.1021/acs.jpca.7b11908info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.jpca.7b11908info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-11-05T09:35:02Zoai:ri.conicet.gov.ar:11336/53939instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-11-05 09:35:03.208CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Effective Anisotropic Interactions in Spin Pairs Containing High-Spin Ions with Large Zero-Field Splitting
title Effective Anisotropic Interactions in Spin Pairs Containing High-Spin Ions with Large Zero-Field Splitting
spellingShingle Effective Anisotropic Interactions in Spin Pairs Containing High-Spin Ions with Large Zero-Field Splitting
Neuman, Nicolás Ignacio
Cobalt
Iron
High-Spin
Magnetic Interactions
Dysprosium
title_short Effective Anisotropic Interactions in Spin Pairs Containing High-Spin Ions with Large Zero-Field Splitting
title_full Effective Anisotropic Interactions in Spin Pairs Containing High-Spin Ions with Large Zero-Field Splitting
title_fullStr Effective Anisotropic Interactions in Spin Pairs Containing High-Spin Ions with Large Zero-Field Splitting
title_full_unstemmed Effective Anisotropic Interactions in Spin Pairs Containing High-Spin Ions with Large Zero-Field Splitting
title_sort Effective Anisotropic Interactions in Spin Pairs Containing High-Spin Ions with Large Zero-Field Splitting
dc.creator.none.fl_str_mv Neuman, Nicolás Ignacio
author Neuman, Nicolás Ignacio
author_facet Neuman, Nicolás Ignacio
author_role author
dc.subject.none.fl_str_mv Cobalt
Iron
High-Spin
Magnetic Interactions
Dysprosium
topic Cobalt
Iron
High-Spin
Magnetic Interactions
Dysprosium
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Analytic and numeric derivations are made of the effective exchange and dipolar magnetic interactions between spin pairs containing S = 3/2 ions, such as high-spin Co(II), S = 5/2 ions, such as high-spin Fe(III) ions, experiencing zero-field splittings much larger than the interion interactions, or J = 15/2 ions such as Dy(III) with crystal-field splittings much larger than the interion interaction. These formulas allow for a simpler analysis of the magnetic properties of dimers containing high-spin ions.
Fil: Neuman, Nicolás Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
description Analytic and numeric derivations are made of the effective exchange and dipolar magnetic interactions between spin pairs containing S = 3/2 ions, such as high-spin Co(II), S = 5/2 ions, such as high-spin Fe(III) ions, experiencing zero-field splittings much larger than the interion interactions, or J = 15/2 ions such as Dy(III) with crystal-field splittings much larger than the interion interaction. These formulas allow for a simpler analysis of the magnetic properties of dimers containing high-spin ions.
publishDate 2018
dc.date.none.fl_str_mv 2018-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/53939
Neuman, Nicolás Ignacio; Effective Anisotropic Interactions in Spin Pairs Containing High-Spin Ions with Large Zero-Field Splitting; American Chemical Society; Journal of Physical Chemistry A; 122; 1; 1-2018; 234-238
1089-5639
CONICET Digital
CONICET
url http://hdl.handle.net/11336/53939
identifier_str_mv Neuman, Nicolás Ignacio; Effective Anisotropic Interactions in Spin Pairs Containing High-Spin Ions with Large Zero-Field Splitting; American Chemical Society; Journal of Physical Chemistry A; 122; 1; 1-2018; 234-238
1089-5639
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/10.1021/acs.jpca.7b11908
info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.jpca.7b11908
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1847976767183126528
score 13.121305

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