Advances in novel activation methods to perform green organic synthesis using recyclable heteropolyacid catalysis

Autores
Ruiz, Diego Manuel; Pasquale, Gustavo Antonio; Martínez, José J.; Romanelli, Gustavo Pablo
Año de publicación
2022
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Highly functionalized, high value added bioactive molecules are generally obtained by synthetic procedures that are highly selective, economical, with high atom economy, and environmentally friendly. Following these guidelines, the use of recoverable solid catalysts, nonpolluting substrates, or toxic organic solvent contributes greatly to these demands. In the last three decades, heteropolyacids (HPAs) and its derivatives have received great attention as recyclable solid catalysts, due to their strong Brönsted acidity, excellent oxidizing capacity under mild conditions, and various reuse cycles without appreciable loss of their catalytic activity. However, new activation methods should be investigated to improve the sustainability of a process using HPAs. In this review, we report the latest advances associated with the synthesis of potentially bioactive molecules using more energy efficient alternatives such as microwaves, ultrasound, mechanochemistry, and photochemistry to minimize the energy consumption associated with organic synthesis. The transformations studied include construction reaction, heterocycle synthesis, selective oxidation, and biomass recovery.
Fil: Ruiz, Diego Manuel. Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales. Departamento de Ciencias Exactas. Cátedra de Química Orgánica; Argentina. Universidad Nacional de la Plata. Facultad de Cs.agrarias y Forestales. Centro de Investigacion En Sanidad Vegetal.; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Pasquale, Gustavo Antonio. Universidad Nacional de la Plata. Facultad de Cs.agrarias y Forestales. Centro de Investigacion En Sanidad Vegetal.; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales. Departamento de Ciencias Exactas. Cátedra de Química Orgánica; Argentina
Fil: Martínez, José J.. Universidad Pedagógica y Tecnológica de Colombia; Colombia
Fil: Romanelli, Gustavo Pablo. Universidad Nacional de la Plata. Facultad de Cs.agrarias y Forestales. Centro de Investigacion En Sanidad Vegetal.; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales. Departamento de Ciencias Exactas. Cátedra de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Materia
GREEN CHEMISTRY
HETEROPOLYACIDS
NOVEL CHEMICAL ACTIVATION METHODS
ORGANIC TRANSFORMATIONS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/204797
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/204797
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Advances in novel activation methods to perform green organic synthesis using recyclable heteropolyacid catalysisRuiz, Diego ManuelPasquale, Gustavo AntonioMartínez, José J.Romanelli, Gustavo PabloGREEN CHEMISTRYHETEROPOLYACIDSNOVEL CHEMICAL ACTIVATION METHODSORGANIC TRANSFORMATIONShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1https://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Highly functionalized, high value added bioactive molecules are generally obtained by synthetic procedures that are highly selective, economical, with high atom economy, and environmentally friendly. Following these guidelines, the use of recoverable solid catalysts, nonpolluting substrates, or toxic organic solvent contributes greatly to these demands. In the last three decades, heteropolyacids (HPAs) and its derivatives have received great attention as recyclable solid catalysts, due to their strong Brönsted acidity, excellent oxidizing capacity under mild conditions, and various reuse cycles without appreciable loss of their catalytic activity. However, new activation methods should be investigated to improve the sustainability of a process using HPAs. In this review, we report the latest advances associated with the synthesis of potentially bioactive molecules using more energy efficient alternatives such as microwaves, ultrasound, mechanochemistry, and photochemistry to minimize the energy consumption associated with organic synthesis. The transformations studied include construction reaction, heterocycle synthesis, selective oxidation, and biomass recovery.Fil: Ruiz, Diego Manuel. Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales. Departamento de Ciencias Exactas. Cátedra de Química Orgánica; Argentina. Universidad Nacional de la Plata. Facultad de Cs.agrarias y Forestales. Centro de Investigacion En Sanidad Vegetal.; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Pasquale, Gustavo Antonio. Universidad Nacional de la Plata. Facultad de Cs.agrarias y Forestales. Centro de Investigacion En Sanidad Vegetal.; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales. Departamento de Ciencias Exactas. Cátedra de Química Orgánica; ArgentinaFil: Martínez, José J.. Universidad Pedagógica y Tecnológica de Colombia; ColombiaFil: Romanelli, Gustavo Pablo. Universidad Nacional de la Plata. Facultad de Cs.agrarias y Forestales. Centro de Investigacion En Sanidad Vegetal.; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales. Departamento de Ciencias Exactas. Cátedra de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaDe Gruyter2022-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/204797Ruiz, Diego Manuel; Pasquale, Gustavo Antonio; Martínez, José J.; Romanelli, Gustavo Pablo; Advances in novel activation methods to perform green organic synthesis using recyclable heteropolyacid catalysis; De Gruyter; Green Processing and Synthesis; 11; 1; 1-2022; 766-8092191-95422191-9550CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1515/gps-2022-0068info:eu-repo/semantics/altIdentifier/url/https://www.degruyter.com/document/doi/10.1515/gps-2022-0068/htmlinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:11:25Zoai:ri.conicet.gov.ar:11336/204797instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:11:25.702CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Advances in novel activation methods to perform green organic synthesis using recyclable heteropolyacid catalysis
title Advances in novel activation methods to perform green organic synthesis using recyclable heteropolyacid catalysis
spellingShingle Advances in novel activation methods to perform green organic synthesis using recyclable heteropolyacid catalysis
Ruiz, Diego Manuel
GREEN CHEMISTRY
HETEROPOLYACIDS
NOVEL CHEMICAL ACTIVATION METHODS
ORGANIC TRANSFORMATIONS
title_short Advances in novel activation methods to perform green organic synthesis using recyclable heteropolyacid catalysis
title_full Advances in novel activation methods to perform green organic synthesis using recyclable heteropolyacid catalysis
title_fullStr Advances in novel activation methods to perform green organic synthesis using recyclable heteropolyacid catalysis
title_full_unstemmed Advances in novel activation methods to perform green organic synthesis using recyclable heteropolyacid catalysis
title_sort Advances in novel activation methods to perform green organic synthesis using recyclable heteropolyacid catalysis
dc.creator.none.fl_str_mv Ruiz, Diego Manuel
Pasquale, Gustavo Antonio
Martínez, José J.
Romanelli, Gustavo Pablo
author Ruiz, Diego Manuel
author_facet Ruiz, Diego Manuel
Pasquale, Gustavo Antonio
Martínez, José J.
Romanelli, Gustavo Pablo
author_role author
author2 Pasquale, Gustavo Antonio
Martínez, José J.
Romanelli, Gustavo Pablo
author2_role author
author
author
dc.subject.none.fl_str_mv GREEN CHEMISTRY
HETEROPOLYACIDS
NOVEL CHEMICAL ACTIVATION METHODS
ORGANIC TRANSFORMATIONS
topic GREEN CHEMISTRY
HETEROPOLYACIDS
NOVEL CHEMICAL ACTIVATION METHODS
ORGANIC TRANSFORMATIONS
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Highly functionalized, high value added bioactive molecules are generally obtained by synthetic procedures that are highly selective, economical, with high atom economy, and environmentally friendly. Following these guidelines, the use of recoverable solid catalysts, nonpolluting substrates, or toxic organic solvent contributes greatly to these demands. In the last three decades, heteropolyacids (HPAs) and its derivatives have received great attention as recyclable solid catalysts, due to their strong Brönsted acidity, excellent oxidizing capacity under mild conditions, and various reuse cycles without appreciable loss of their catalytic activity. However, new activation methods should be investigated to improve the sustainability of a process using HPAs. In this review, we report the latest advances associated with the synthesis of potentially bioactive molecules using more energy efficient alternatives such as microwaves, ultrasound, mechanochemistry, and photochemistry to minimize the energy consumption associated with organic synthesis. The transformations studied include construction reaction, heterocycle synthesis, selective oxidation, and biomass recovery.
Fil: Ruiz, Diego Manuel. Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales. Departamento de Ciencias Exactas. Cátedra de Química Orgánica; Argentina. Universidad Nacional de la Plata. Facultad de Cs.agrarias y Forestales. Centro de Investigacion En Sanidad Vegetal.; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Pasquale, Gustavo Antonio. Universidad Nacional de la Plata. Facultad de Cs.agrarias y Forestales. Centro de Investigacion En Sanidad Vegetal.; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales. Departamento de Ciencias Exactas. Cátedra de Química Orgánica; Argentina
Fil: Martínez, José J.. Universidad Pedagógica y Tecnológica de Colombia; Colombia
Fil: Romanelli, Gustavo Pablo. Universidad Nacional de la Plata. Facultad de Cs.agrarias y Forestales. Centro de Investigacion En Sanidad Vegetal.; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales. Departamento de Ciencias Exactas. Cátedra de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
description Highly functionalized, high value added bioactive molecules are generally obtained by synthetic procedures that are highly selective, economical, with high atom economy, and environmentally friendly. Following these guidelines, the use of recoverable solid catalysts, nonpolluting substrates, or toxic organic solvent contributes greatly to these demands. In the last three decades, heteropolyacids (HPAs) and its derivatives have received great attention as recyclable solid catalysts, due to their strong Brönsted acidity, excellent oxidizing capacity under mild conditions, and various reuse cycles without appreciable loss of their catalytic activity. However, new activation methods should be investigated to improve the sustainability of a process using HPAs. In this review, we report the latest advances associated with the synthesis of potentially bioactive molecules using more energy efficient alternatives such as microwaves, ultrasound, mechanochemistry, and photochemistry to minimize the energy consumption associated with organic synthesis. The transformations studied include construction reaction, heterocycle synthesis, selective oxidation, and biomass recovery.
publishDate 2022
dc.date.none.fl_str_mv 2022-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/204797
Ruiz, Diego Manuel; Pasquale, Gustavo Antonio; Martínez, José J.; Romanelli, Gustavo Pablo; Advances in novel activation methods to perform green organic synthesis using recyclable heteropolyacid catalysis; De Gruyter; Green Processing and Synthesis; 11; 1; 1-2022; 766-809
2191-9542
2191-9550
CONICET Digital
CONICET
url http://hdl.handle.net/11336/204797
identifier_str_mv Ruiz, Diego Manuel; Pasquale, Gustavo Antonio; Martínez, José J.; Romanelli, Gustavo Pablo; Advances in novel activation methods to perform green organic synthesis using recyclable heteropolyacid catalysis; De Gruyter; Green Processing and Synthesis; 11; 1; 1-2022; 766-809
2191-9542
2191-9550
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1515/gps-2022-0068
info:eu-repo/semantics/altIdentifier/url/https://www.degruyter.com/document/doi/10.1515/gps-2022-0068/html
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv De Gruyter
publisher.none.fl_str_mv De Gruyter
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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