Carboxylated, Fe-Filled Multiwalled Carbon Nanotubes as Versatile Catalysts for O2 Reduction and H2 Evolution Reactions at Physiological pH

Autores
Bracamonte, Maria Victoria; Melchionna, Michele; Stopin, Antoine; Giulani, Angela; Tavagnacco, Claudio; Garcia, Yann; Fornasiero, Paolo; Bonifazi, Davide; Prato, Maurizio
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The development of new electrocatalysts for the oxygen reduction reaction (ORR) and hydrogen evolution reaction (HER) at physiological pH is critical for several fields, including fuel cells and biological applications. Herein, the assembly of an electrode based on carboxyl-functionalised hydrophilic multiwalled carbon nanotubes (MWCNTs) filled with Fe phases and their excellent performance as electrocatalysts for ORR and HER at physiological pH are reported. The encapsulated Fe dramatically enhances the catalytic activity, and the graphitic shells play a double role of efficiently mediating the electron transfer to O2 and H2O reactants and providing a cocoon that prevents uncontrolled Fe oxidation or leaching.
Fil: Bracamonte, Maria Victoria. Università degli Studi di Trieste; Italia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
Fil: Melchionna, Michele. Università degli Studi di Trieste; Italia
Fil: Stopin, Antoine. University Of Namur; Bélgica
Fil: Giulani, Angela. Università degli Studi di Trieste; Italia
Fil: Tavagnacco, Claudio. Università degli Studi di Trieste; Italia
Fil: Garcia, Yann. Université Catholique de Louvain; Bélgica
Fil: Fornasiero, Paolo. Università degli Studi di Trieste; Italia
Fil: Bonifazi, Davide. Università degli Studi di Trieste; Italia. University Of Namur; Bélgica
Fil: Prato, Maurizio. Università degli Studi di Trieste; Italia
Materia
ELECTROCHEMISTRY
HYDROGEN EVOLUTION REACTION
IRON
NANOTUBES
OXYGEN REDUCTION REACTION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/186232
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Carboxylated, Fe-Filled Multiwalled Carbon Nanotubes as Versatile Catalysts for O2 Reduction and H2 Evolution Reactions at Physiological pHBracamonte, Maria VictoriaMelchionna, MicheleStopin, AntoineGiulani, AngelaTavagnacco, ClaudioGarcia, YannFornasiero, PaoloBonifazi, DavidePrato, MaurizioELECTROCHEMISTRYHYDROGEN EVOLUTION REACTIONIRONNANOTUBESOXYGEN REDUCTION REACTIONhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The development of new electrocatalysts for the oxygen reduction reaction (ORR) and hydrogen evolution reaction (HER) at physiological pH is critical for several fields, including fuel cells and biological applications. Herein, the assembly of an electrode based on carboxyl-functionalised hydrophilic multiwalled carbon nanotubes (MWCNTs) filled with Fe phases and their excellent performance as electrocatalysts for ORR and HER at physiological pH are reported. The encapsulated Fe dramatically enhances the catalytic activity, and the graphitic shells play a double role of efficiently mediating the electron transfer to O2 and H2O reactants and providing a cocoon that prevents uncontrolled Fe oxidation or leaching.Fil: Bracamonte, Maria Victoria. Università degli Studi di Trieste; Italia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; ArgentinaFil: Melchionna, Michele. Università degli Studi di Trieste; ItaliaFil: Stopin, Antoine. University Of Namur; BélgicaFil: Giulani, Angela. Università degli Studi di Trieste; ItaliaFil: Tavagnacco, Claudio. Università degli Studi di Trieste; ItaliaFil: Garcia, Yann. Université Catholique de Louvain; BélgicaFil: Fornasiero, Paolo. Università degli Studi di Trieste; ItaliaFil: Bonifazi, Davide. Università degli Studi di Trieste; Italia. University Of Namur; BélgicaFil: Prato, Maurizio. Università degli Studi di Trieste; ItaliaWiley VCH Verlag2015-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/186232Bracamonte, Maria Victoria; Melchionna, Michele; Stopin, Antoine; Giulani, Angela; Tavagnacco, Claudio; et al.; Carboxylated, Fe-Filled Multiwalled Carbon Nanotubes as Versatile Catalysts for O2 Reduction and H2 Evolution Reactions at Physiological pH; Wiley VCH Verlag; Chemistry- A European Journal; 21; 36; 9-2015; 12769-127770947-6539CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/chem.201501144info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:36:38Zoai:ri.conicet.gov.ar:11336/186232instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:36:38.581CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Carboxylated, Fe-Filled Multiwalled Carbon Nanotubes as Versatile Catalysts for O2 Reduction and H2 Evolution Reactions at Physiological pH
title Carboxylated, Fe-Filled Multiwalled Carbon Nanotubes as Versatile Catalysts for O2 Reduction and H2 Evolution Reactions at Physiological pH
spellingShingle Carboxylated, Fe-Filled Multiwalled Carbon Nanotubes as Versatile Catalysts for O2 Reduction and H2 Evolution Reactions at Physiological pH
Bracamonte, Maria Victoria
ELECTROCHEMISTRY
HYDROGEN EVOLUTION REACTION
IRON
NANOTUBES
OXYGEN REDUCTION REACTION
title_short Carboxylated, Fe-Filled Multiwalled Carbon Nanotubes as Versatile Catalysts for O2 Reduction and H2 Evolution Reactions at Physiological pH
title_full Carboxylated, Fe-Filled Multiwalled Carbon Nanotubes as Versatile Catalysts for O2 Reduction and H2 Evolution Reactions at Physiological pH
title_fullStr Carboxylated, Fe-Filled Multiwalled Carbon Nanotubes as Versatile Catalysts for O2 Reduction and H2 Evolution Reactions at Physiological pH
title_full_unstemmed Carboxylated, Fe-Filled Multiwalled Carbon Nanotubes as Versatile Catalysts for O2 Reduction and H2 Evolution Reactions at Physiological pH
title_sort Carboxylated, Fe-Filled Multiwalled Carbon Nanotubes as Versatile Catalysts for O2 Reduction and H2 Evolution Reactions at Physiological pH
dc.creator.none.fl_str_mv Bracamonte, Maria Victoria
Melchionna, Michele
Stopin, Antoine
Giulani, Angela
Tavagnacco, Claudio
Garcia, Yann
Fornasiero, Paolo
Bonifazi, Davide
Prato, Maurizio
author Bracamonte, Maria Victoria
author_facet Bracamonte, Maria Victoria
Melchionna, Michele
Stopin, Antoine
Giulani, Angela
Tavagnacco, Claudio
Garcia, Yann
Fornasiero, Paolo
Bonifazi, Davide
Prato, Maurizio
author_role author
author2 Melchionna, Michele
Stopin, Antoine
Giulani, Angela
Tavagnacco, Claudio
Garcia, Yann
Fornasiero, Paolo
Bonifazi, Davide
Prato, Maurizio
author2_role author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv ELECTROCHEMISTRY
HYDROGEN EVOLUTION REACTION
IRON
NANOTUBES
OXYGEN REDUCTION REACTION
topic ELECTROCHEMISTRY
HYDROGEN EVOLUTION REACTION
IRON
NANOTUBES
OXYGEN REDUCTION REACTION
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The development of new electrocatalysts for the oxygen reduction reaction (ORR) and hydrogen evolution reaction (HER) at physiological pH is critical for several fields, including fuel cells and biological applications. Herein, the assembly of an electrode based on carboxyl-functionalised hydrophilic multiwalled carbon nanotubes (MWCNTs) filled with Fe phases and their excellent performance as electrocatalysts for ORR and HER at physiological pH are reported. The encapsulated Fe dramatically enhances the catalytic activity, and the graphitic shells play a double role of efficiently mediating the electron transfer to O2 and H2O reactants and providing a cocoon that prevents uncontrolled Fe oxidation or leaching.
Fil: Bracamonte, Maria Victoria. Università degli Studi di Trieste; Italia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina
Fil: Melchionna, Michele. Università degli Studi di Trieste; Italia
Fil: Stopin, Antoine. University Of Namur; Bélgica
Fil: Giulani, Angela. Università degli Studi di Trieste; Italia
Fil: Tavagnacco, Claudio. Università degli Studi di Trieste; Italia
Fil: Garcia, Yann. Université Catholique de Louvain; Bélgica
Fil: Fornasiero, Paolo. Università degli Studi di Trieste; Italia
Fil: Bonifazi, Davide. Università degli Studi di Trieste; Italia. University Of Namur; Bélgica
Fil: Prato, Maurizio. Università degli Studi di Trieste; Italia
description The development of new electrocatalysts for the oxygen reduction reaction (ORR) and hydrogen evolution reaction (HER) at physiological pH is critical for several fields, including fuel cells and biological applications. Herein, the assembly of an electrode based on carboxyl-functionalised hydrophilic multiwalled carbon nanotubes (MWCNTs) filled with Fe phases and their excellent performance as electrocatalysts for ORR and HER at physiological pH are reported. The encapsulated Fe dramatically enhances the catalytic activity, and the graphitic shells play a double role of efficiently mediating the electron transfer to O2 and H2O reactants and providing a cocoon that prevents uncontrolled Fe oxidation or leaching.
publishDate 2015
dc.date.none.fl_str_mv 2015-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/186232
Bracamonte, Maria Victoria; Melchionna, Michele; Stopin, Antoine; Giulani, Angela; Tavagnacco, Claudio; et al.; Carboxylated, Fe-Filled Multiwalled Carbon Nanotubes as Versatile Catalysts for O2 Reduction and H2 Evolution Reactions at Physiological pH; Wiley VCH Verlag; Chemistry- A European Journal; 21; 36; 9-2015; 12769-12777
0947-6539
CONICET Digital
CONICET
url http://hdl.handle.net/11336/186232
identifier_str_mv Bracamonte, Maria Victoria; Melchionna, Michele; Stopin, Antoine; Giulani, Angela; Tavagnacco, Claudio; et al.; Carboxylated, Fe-Filled Multiwalled Carbon Nanotubes as Versatile Catalysts for O2 Reduction and H2 Evolution Reactions at Physiological pH; Wiley VCH Verlag; Chemistry- A European Journal; 21; 36; 9-2015; 12769-12777
0947-6539
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/chem.201501144
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley VCH Verlag
publisher.none.fl_str_mv Wiley VCH Verlag
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613150896291840
score 13.070432

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