Effects of adding nano-clay (montmorillonite) on performance of polyvinyl acetate (PVAc) and urea-formaldehyde (UF) adhesives in Carapa guianensis, a tropical species

Autores
Moya, Róger; Rodriguez-zuñiga, Ana; Vega-Baudrit, José; Alvarez, Vera Alejandra
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The aim of this study was to improve the bond strength resistance of polyvinyl acetate (PVAc) and urea-formaldehyde (UF) adhesives modified with nano-clay (montmorillonite) with a tropical species of wood known to exhibit adhesion related problems. These adhesives were evaluated with 1.0 and 1.5 wt% nano-clay concentrations with lap shear strength (SS), and the percentage of wood failure (PWF) in dry and wet conditions being evaluated. An additional aim of this study was to observe the presence of nano-clay within both adhesive types using Atomic Force Microscopy (AFM) and the Transmission Electron Microscopy (TEM). Color, viscosity and the thermostability of these adhesives with nano-clay were also evaluated. First, AFM and TEM studies showed adequate dispersion and impregnation of nano-clay. The viscosity of PVAc adhesive was not affected by the incorporation of nano-clay, whereas the UF adhesive was. With both PVAc and UF adhesives, the presence of nano-clay increased the L∗ and b∗ color parameters, especially when 1.5 wt% nano-clay was used. The incorporation of the nano-clay improved thermostability, as determined by thermogravimetric analysis (TGA). Finally, it was shown that the nano-clay incorporation improved SS and PWF. The highest values of SS were obtained when nano-clay was added at 1.5 wt% concentration in the PVAc adhesive under dry conditions. SS was not affected by nano-clay addition in the UF adhesive under dry conditions. However, under wet conditions, both 1.0 and 1.5 wt% loadings of nano-clay increased SS with both adhesive types. The addition of nano-clay in both proportions increased PWF by approximately 15% and between 20-30% in dry and wet conditions, respectively, for the PVAc adhesive. For the UF adhesive, PWF increased by approximately 10% under dry conditions and 25-50% in wet conditions.
Fil: Moya, Róger. Instituto Tecnológico de Costa Rica; Costa Rica
Fil: Rodriguez-zuñiga, Ana. Instituto Tecnológico de Costa Rica; Costa Rica
Fil: Vega-Baudrit, José. Centro Nacional de Alta Tecnologia; Costa Rica
Fil: Alvarez, Vera Alejandra. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina
Materia
NANO-CLAY
NANOTECHNOLOGY
THERMAL ANALYSIS
TROPICAL SPECIES
WOOD ADHESIVES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/2940

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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Effects of adding nano-clay (montmorillonite) on performance of polyvinyl acetate (PVAc) and urea-formaldehyde (UF) adhesives in Carapa guianensis, a tropical speciesMoya, RógerRodriguez-zuñiga, AnaVega-Baudrit, JoséAlvarez, Vera AlejandraNANO-CLAYNANOTECHNOLOGYTHERMAL ANALYSISTROPICAL SPECIESWOOD ADHESIVEShttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2The aim of this study was to improve the bond strength resistance of polyvinyl acetate (PVAc) and urea-formaldehyde (UF) adhesives modified with nano-clay (montmorillonite) with a tropical species of wood known to exhibit adhesion related problems. These adhesives were evaluated with 1.0 and 1.5 wt% nano-clay concentrations with lap shear strength (SS), and the percentage of wood failure (PWF) in dry and wet conditions being evaluated. An additional aim of this study was to observe the presence of nano-clay within both adhesive types using Atomic Force Microscopy (AFM) and the Transmission Electron Microscopy (TEM). Color, viscosity and the thermostability of these adhesives with nano-clay were also evaluated. First, AFM and TEM studies showed adequate dispersion and impregnation of nano-clay. The viscosity of PVAc adhesive was not affected by the incorporation of nano-clay, whereas the UF adhesive was. With both PVAc and UF adhesives, the presence of nano-clay increased the L∗ and b∗ color parameters, especially when 1.5 wt% nano-clay was used. The incorporation of the nano-clay improved thermostability, as determined by thermogravimetric analysis (TGA). Finally, it was shown that the nano-clay incorporation improved SS and PWF. The highest values of SS were obtained when nano-clay was added at 1.5 wt% concentration in the PVAc adhesive under dry conditions. SS was not affected by nano-clay addition in the UF adhesive under dry conditions. However, under wet conditions, both 1.0 and 1.5 wt% loadings of nano-clay increased SS with both adhesive types. The addition of nano-clay in both proportions increased PWF by approximately 15% and between 20-30% in dry and wet conditions, respectively, for the PVAc adhesive. For the UF adhesive, PWF increased by approximately 10% under dry conditions and 25-50% in wet conditions.Fil: Moya, Róger. Instituto Tecnológico de Costa Rica; Costa RicaFil: Rodriguez-zuñiga, Ana. Instituto Tecnológico de Costa Rica; Costa RicaFil: Vega-Baudrit, José. Centro Nacional de Alta Tecnologia; Costa RicaFil: Alvarez, Vera Alejandra. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); ArgentinaElsevier2015-02-17info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/2940Moya, Róger; Rodriguez-zuñiga, Ana; Vega-Baudrit, José; Alvarez, Vera Alejandra; Effects of adding nano-clay (montmorillonite) on performance of polyvinyl acetate (PVAc) and urea-formaldehyde (UF) adhesives in Carapa guianensis, a tropical species; Elsevier; International Journal Of Adhesion And Adhesives; 59; 17-2-2015; 62-700143-7496enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0143749615000299info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijadhadh.2015.02.004info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:34:12Zoai:ri.conicet.gov.ar:11336/2940instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:34:12.523CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Effects of adding nano-clay (montmorillonite) on performance of polyvinyl acetate (PVAc) and urea-formaldehyde (UF) adhesives in Carapa guianensis, a tropical species
title Effects of adding nano-clay (montmorillonite) on performance of polyvinyl acetate (PVAc) and urea-formaldehyde (UF) adhesives in Carapa guianensis, a tropical species
spellingShingle Effects of adding nano-clay (montmorillonite) on performance of polyvinyl acetate (PVAc) and urea-formaldehyde (UF) adhesives in Carapa guianensis, a tropical species
Moya, Róger
NANO-CLAY
NANOTECHNOLOGY
THERMAL ANALYSIS
TROPICAL SPECIES
WOOD ADHESIVES
title_short Effects of adding nano-clay (montmorillonite) on performance of polyvinyl acetate (PVAc) and urea-formaldehyde (UF) adhesives in Carapa guianensis, a tropical species
title_full Effects of adding nano-clay (montmorillonite) on performance of polyvinyl acetate (PVAc) and urea-formaldehyde (UF) adhesives in Carapa guianensis, a tropical species
title_fullStr Effects of adding nano-clay (montmorillonite) on performance of polyvinyl acetate (PVAc) and urea-formaldehyde (UF) adhesives in Carapa guianensis, a tropical species
title_full_unstemmed Effects of adding nano-clay (montmorillonite) on performance of polyvinyl acetate (PVAc) and urea-formaldehyde (UF) adhesives in Carapa guianensis, a tropical species
title_sort Effects of adding nano-clay (montmorillonite) on performance of polyvinyl acetate (PVAc) and urea-formaldehyde (UF) adhesives in Carapa guianensis, a tropical species
dc.creator.none.fl_str_mv Moya, Róger
Rodriguez-zuñiga, Ana
Vega-Baudrit, José
Alvarez, Vera Alejandra
author Moya, Róger
author_facet Moya, Róger
Rodriguez-zuñiga, Ana
Vega-Baudrit, José
Alvarez, Vera Alejandra
author_role author
author2 Rodriguez-zuñiga, Ana
Vega-Baudrit, José
Alvarez, Vera Alejandra
author2_role author
author
author
dc.subject.none.fl_str_mv NANO-CLAY
NANOTECHNOLOGY
THERMAL ANALYSIS
TROPICAL SPECIES
WOOD ADHESIVES
topic NANO-CLAY
NANOTECHNOLOGY
THERMAL ANALYSIS
TROPICAL SPECIES
WOOD ADHESIVES
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The aim of this study was to improve the bond strength resistance of polyvinyl acetate (PVAc) and urea-formaldehyde (UF) adhesives modified with nano-clay (montmorillonite) with a tropical species of wood known to exhibit adhesion related problems. These adhesives were evaluated with 1.0 and 1.5 wt% nano-clay concentrations with lap shear strength (SS), and the percentage of wood failure (PWF) in dry and wet conditions being evaluated. An additional aim of this study was to observe the presence of nano-clay within both adhesive types using Atomic Force Microscopy (AFM) and the Transmission Electron Microscopy (TEM). Color, viscosity and the thermostability of these adhesives with nano-clay were also evaluated. First, AFM and TEM studies showed adequate dispersion and impregnation of nano-clay. The viscosity of PVAc adhesive was not affected by the incorporation of nano-clay, whereas the UF adhesive was. With both PVAc and UF adhesives, the presence of nano-clay increased the L∗ and b∗ color parameters, especially when 1.5 wt% nano-clay was used. The incorporation of the nano-clay improved thermostability, as determined by thermogravimetric analysis (TGA). Finally, it was shown that the nano-clay incorporation improved SS and PWF. The highest values of SS were obtained when nano-clay was added at 1.5 wt% concentration in the PVAc adhesive under dry conditions. SS was not affected by nano-clay addition in the UF adhesive under dry conditions. However, under wet conditions, both 1.0 and 1.5 wt% loadings of nano-clay increased SS with both adhesive types. The addition of nano-clay in both proportions increased PWF by approximately 15% and between 20-30% in dry and wet conditions, respectively, for the PVAc adhesive. For the UF adhesive, PWF increased by approximately 10% under dry conditions and 25-50% in wet conditions.
Fil: Moya, Róger. Instituto Tecnológico de Costa Rica; Costa Rica
Fil: Rodriguez-zuñiga, Ana. Instituto Tecnológico de Costa Rica; Costa Rica
Fil: Vega-Baudrit, José. Centro Nacional de Alta Tecnologia; Costa Rica
Fil: Alvarez, Vera Alejandra. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina
description The aim of this study was to improve the bond strength resistance of polyvinyl acetate (PVAc) and urea-formaldehyde (UF) adhesives modified with nano-clay (montmorillonite) with a tropical species of wood known to exhibit adhesion related problems. These adhesives were evaluated with 1.0 and 1.5 wt% nano-clay concentrations with lap shear strength (SS), and the percentage of wood failure (PWF) in dry and wet conditions being evaluated. An additional aim of this study was to observe the presence of nano-clay within both adhesive types using Atomic Force Microscopy (AFM) and the Transmission Electron Microscopy (TEM). Color, viscosity and the thermostability of these adhesives with nano-clay were also evaluated. First, AFM and TEM studies showed adequate dispersion and impregnation of nano-clay. The viscosity of PVAc adhesive was not affected by the incorporation of nano-clay, whereas the UF adhesive was. With both PVAc and UF adhesives, the presence of nano-clay increased the L∗ and b∗ color parameters, especially when 1.5 wt% nano-clay was used. The incorporation of the nano-clay improved thermostability, as determined by thermogravimetric analysis (TGA). Finally, it was shown that the nano-clay incorporation improved SS and PWF. The highest values of SS were obtained when nano-clay was added at 1.5 wt% concentration in the PVAc adhesive under dry conditions. SS was not affected by nano-clay addition in the UF adhesive under dry conditions. However, under wet conditions, both 1.0 and 1.5 wt% loadings of nano-clay increased SS with both adhesive types. The addition of nano-clay in both proportions increased PWF by approximately 15% and between 20-30% in dry and wet conditions, respectively, for the PVAc adhesive. For the UF adhesive, PWF increased by approximately 10% under dry conditions and 25-50% in wet conditions.
publishDate 2015
dc.date.none.fl_str_mv 2015-02-17
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/2940
Moya, Róger; Rodriguez-zuñiga, Ana; Vega-Baudrit, José; Alvarez, Vera Alejandra; Effects of adding nano-clay (montmorillonite) on performance of polyvinyl acetate (PVAc) and urea-formaldehyde (UF) adhesives in Carapa guianensis, a tropical species; Elsevier; International Journal Of Adhesion And Adhesives; 59; 17-2-2015; 62-70
0143-7496
url http://hdl.handle.net/11336/2940
identifier_str_mv Moya, Róger; Rodriguez-zuñiga, Ana; Vega-Baudrit, José; Alvarez, Vera Alejandra; Effects of adding nano-clay (montmorillonite) on performance of polyvinyl acetate (PVAc) and urea-formaldehyde (UF) adhesives in Carapa guianensis, a tropical species; Elsevier; International Journal Of Adhesion And Adhesives; 59; 17-2-2015; 62-70
0143-7496
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0143749615000299
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijadhadh.2015.02.004
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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