Recent advances in catalysts, palladium alloys and high temperature WGS membrane reactors: A review

Autores
Cornaglia, Laura Maria; Múnera Agudelo, John Fernando; Lombardo, Eduardo Agustin
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
There is an increasing demand for pure H2 (CO < 10 ppm) to be used in low temperature PEM fuel cells. This puts pressure on the development of alternative routes to purify the hydrogen that is produced in reformers using feedstocks such as natural gas and ethanol. A good option is the water gas shift reaction conducted in a membrane reactor to obtain ultrapure hydrogen. This contribution critically reviews the developments that took place in this decade concerning more efficient, selective, long-lasting catalysts that do not catalyze the formation of methane, graphitic and carbonaceous residues. The membranes, highly selective to hydrogen with high permeability and resistant to poisonous gases, particularly H2S, are also critically reviewed. Also included in this analysis are the different types of membrane reactors most commonly used.
Fil: Cornaglia, Laura Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Múnera Agudelo, John Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Lombardo, Eduardo Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Materia
Hydrogen Production
Pt Pd Rh
Co Inhibition
H2s Effect
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/34100
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Recent advances in catalysts, palladium alloys and high temperature WGS membrane reactors: A reviewCornaglia, Laura MariaMúnera Agudelo, John FernandoLombardo, Eduardo AgustinHydrogen ProductionPt Pd RhCo InhibitionH2s Effecthttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2There is an increasing demand for pure H2 (CO < 10 ppm) to be used in low temperature PEM fuel cells. This puts pressure on the development of alternative routes to purify the hydrogen that is produced in reformers using feedstocks such as natural gas and ethanol. A good option is the water gas shift reaction conducted in a membrane reactor to obtain ultrapure hydrogen. This contribution critically reviews the developments that took place in this decade concerning more efficient, selective, long-lasting catalysts that do not catalyze the formation of methane, graphitic and carbonaceous residues. The membranes, highly selective to hydrogen with high permeability and resistant to poisonous gases, particularly H2S, are also critically reviewed. Also included in this analysis are the different types of membrane reactors most commonly used.Fil: Cornaglia, Laura Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Múnera Agudelo, John Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Lombardo, Eduardo Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaElsevier2015-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/34100Cornaglia, Laura Maria; Múnera Agudelo, John Fernando; Lombardo, Eduardo Agustin; Recent advances in catalysts, palladium alloys and high temperature WGS membrane reactors: A review; Elsevier; International Journal of Hydrogen Energy; 40; 8; 3-2015; 3423-34370360-3199CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijhydene.2014.10.091info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0360319914029310?via%3Dihubinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:41:35Zoai:ri.conicet.gov.ar:11336/34100instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:41:35.672CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Recent advances in catalysts, palladium alloys and high temperature WGS membrane reactors: A review
title Recent advances in catalysts, palladium alloys and high temperature WGS membrane reactors: A review
spellingShingle Recent advances in catalysts, palladium alloys and high temperature WGS membrane reactors: A review
Cornaglia, Laura Maria
Hydrogen Production
Pt Pd Rh
Co Inhibition
H2s Effect
title_short Recent advances in catalysts, palladium alloys and high temperature WGS membrane reactors: A review
title_full Recent advances in catalysts, palladium alloys and high temperature WGS membrane reactors: A review
title_fullStr Recent advances in catalysts, palladium alloys and high temperature WGS membrane reactors: A review
title_full_unstemmed Recent advances in catalysts, palladium alloys and high temperature WGS membrane reactors: A review
title_sort Recent advances in catalysts, palladium alloys and high temperature WGS membrane reactors: A review
dc.creator.none.fl_str_mv Cornaglia, Laura Maria
Múnera Agudelo, John Fernando
Lombardo, Eduardo Agustin
author Cornaglia, Laura Maria
author_facet Cornaglia, Laura Maria
Múnera Agudelo, John Fernando
Lombardo, Eduardo Agustin
author_role author
author2 Múnera Agudelo, John Fernando
Lombardo, Eduardo Agustin
author2_role author
author
dc.subject.none.fl_str_mv Hydrogen Production
Pt Pd Rh
Co Inhibition
H2s Effect
topic Hydrogen Production
Pt Pd Rh
Co Inhibition
H2s Effect
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv There is an increasing demand for pure H2 (CO < 10 ppm) to be used in low temperature PEM fuel cells. This puts pressure on the development of alternative routes to purify the hydrogen that is produced in reformers using feedstocks such as natural gas and ethanol. A good option is the water gas shift reaction conducted in a membrane reactor to obtain ultrapure hydrogen. This contribution critically reviews the developments that took place in this decade concerning more efficient, selective, long-lasting catalysts that do not catalyze the formation of methane, graphitic and carbonaceous residues. The membranes, highly selective to hydrogen with high permeability and resistant to poisonous gases, particularly H2S, are also critically reviewed. Also included in this analysis are the different types of membrane reactors most commonly used.
Fil: Cornaglia, Laura Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Múnera Agudelo, John Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Lombardo, Eduardo Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
description There is an increasing demand for pure H2 (CO < 10 ppm) to be used in low temperature PEM fuel cells. This puts pressure on the development of alternative routes to purify the hydrogen that is produced in reformers using feedstocks such as natural gas and ethanol. A good option is the water gas shift reaction conducted in a membrane reactor to obtain ultrapure hydrogen. This contribution critically reviews the developments that took place in this decade concerning more efficient, selective, long-lasting catalysts that do not catalyze the formation of methane, graphitic and carbonaceous residues. The membranes, highly selective to hydrogen with high permeability and resistant to poisonous gases, particularly H2S, are also critically reviewed. Also included in this analysis are the different types of membrane reactors most commonly used.
publishDate 2015
dc.date.none.fl_str_mv 2015-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/34100
Cornaglia, Laura Maria; Múnera Agudelo, John Fernando; Lombardo, Eduardo Agustin; Recent advances in catalysts, palladium alloys and high temperature WGS membrane reactors: A review; Elsevier; International Journal of Hydrogen Energy; 40; 8; 3-2015; 3423-3437
0360-3199
CONICET Digital
CONICET
url http://hdl.handle.net/11336/34100
identifier_str_mv Cornaglia, Laura Maria; Múnera Agudelo, John Fernando; Lombardo, Eduardo Agustin; Recent advances in catalysts, palladium alloys and high temperature WGS membrane reactors: A review; Elsevier; International Journal of Hydrogen Energy; 40; 8; 3-2015; 3423-3437
0360-3199
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijhydene.2014.10.091
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0360319914029310?via%3Dihub
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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