Synthesis and Physicochemical Characterization of Branched Poly (monomethyl itaconate)

Autores
Calderon, Marcelo; Leiva, Angel; Martinelli, Marisa; Gargallo, Ligia; Radic, Deodato; Strumia, Miriam Cristina
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The synthesis and characterization of branched polymers derived from poly (monomethyl itaconate) (PMMI) are reported. Important changes in the properties of the functionalized products were found with respect to the base polymer, establishing a close relationship with the hydrophobic/hydrophilic balance of the products. The intrinsic viscosity of the branched PMMI showed an increment in its hydrodynamic volume due to the insertion of branched molecules, which correspond to a first generation of dendrons. Their incorporation into the polymer chain caused a change in the surface energy values of the sample films and enabled the products to form stable monolayers at the air-water interface.
Fil: Calderon, Marcelo. Universidad Nacional de Cordoba. Facultad de Ciencias Quimicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Leiva, Angel. Pontificia Universidad Católica de Chile. Facultad de Química. Departamento de Química Física. Facultad de Química; Chile
Fil: Martinelli, Marisa. Universidad Nacional de Cordoba. Facultad de Ciencias Quimicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Gargallo, Ligia. Pontificia Universidad Católica de Chile. Facultad de Química. Departamento de Química Física. Facultad de Química; Chile
Fil: Radic, Deodato. Pontificia Universidad Católica de Chile. Facultad de Química. Departamento de Química Física. Facultad de Química; Chile
Fil: Strumia, Miriam Cristina. Universidad Nacional de Cordoba. Facultad de Ciencias Quimicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Materia
Branched Polymer
Branched Molecuoles
Monolayer
Poly(Monomethyl Itaconate)
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/15767
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/15767
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Synthesis and Physicochemical Characterization of Branched Poly (monomethyl itaconate)Calderon, MarceloLeiva, AngelMartinelli, MarisaGargallo, LigiaRadic, DeodatoStrumia, Miriam CristinaBranched PolymerBranched MolecuolesMonolayerPoly(Monomethyl Itaconate)https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The synthesis and characterization of branched polymers derived from poly (monomethyl itaconate) (PMMI) are reported. Important changes in the properties of the functionalized products were found with respect to the base polymer, establishing a close relationship with the hydrophobic/hydrophilic balance of the products. The intrinsic viscosity of the branched PMMI showed an increment in its hydrodynamic volume due to the insertion of branched molecules, which correspond to a first generation of dendrons. Their incorporation into the polymer chain caused a change in the surface energy values of the sample films and enabled the products to form stable monolayers at the air-water interface.Fil: Calderon, Marcelo. Universidad Nacional de Cordoba. Facultad de Ciencias Quimicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Leiva, Angel. Pontificia Universidad Católica de Chile. Facultad de Química. Departamento de Química Física. Facultad de Química; ChileFil: Martinelli, Marisa. Universidad Nacional de Cordoba. Facultad de Ciencias Quimicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Gargallo, Ligia. Pontificia Universidad Católica de Chile. Facultad de Química. Departamento de Química Física. Facultad de Química; ChileFil: Radic, Deodato. Pontificia Universidad Católica de Chile. Facultad de Química. Departamento de Química Física. Facultad de Química; ChileFil: Strumia, Miriam Cristina. Universidad Nacional de Cordoba. Facultad de Ciencias Quimicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaDe Gruyter2010-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/15767Calderon, Marcelo; Leiva, Angel; Martinelli, Marisa; Gargallo, Ligia; Radic, Deodato; et al.; Synthesis and Physicochemical Characterization of Branched Poly (monomethyl itaconate); De Gruyter; E-polymers; 10; 1; 8-2010; 2197-45862197-45861618-7229enginfo:eu-repo/semantics/altIdentifier/url/https://www.degruyter.com/view/j/epoly.2010.10.issue-1/epoly.2010.10.1.1022/epoly.2010.10.1.1022.xml?format=INTinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:34:30Zoai:ri.conicet.gov.ar:11336/15767instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:34:30.443CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synthesis and Physicochemical Characterization of Branched Poly (monomethyl itaconate)
title Synthesis and Physicochemical Characterization of Branched Poly (monomethyl itaconate)
spellingShingle Synthesis and Physicochemical Characterization of Branched Poly (monomethyl itaconate)
Calderon, Marcelo
Branched Polymer
Branched Molecuoles
Monolayer
Poly(Monomethyl Itaconate)
title_short Synthesis and Physicochemical Characterization of Branched Poly (monomethyl itaconate)
title_full Synthesis and Physicochemical Characterization of Branched Poly (monomethyl itaconate)
title_fullStr Synthesis and Physicochemical Characterization of Branched Poly (monomethyl itaconate)
title_full_unstemmed Synthesis and Physicochemical Characterization of Branched Poly (monomethyl itaconate)
title_sort Synthesis and Physicochemical Characterization of Branched Poly (monomethyl itaconate)
dc.creator.none.fl_str_mv Calderon, Marcelo
Leiva, Angel
Martinelli, Marisa
Gargallo, Ligia
Radic, Deodato
Strumia, Miriam Cristina
author Calderon, Marcelo
author_facet Calderon, Marcelo
Leiva, Angel
Martinelli, Marisa
Gargallo, Ligia
Radic, Deodato
Strumia, Miriam Cristina
author_role author
author2 Leiva, Angel
Martinelli, Marisa
Gargallo, Ligia
Radic, Deodato
Strumia, Miriam Cristina
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Branched Polymer
Branched Molecuoles
Monolayer
Poly(Monomethyl Itaconate)
topic Branched Polymer
Branched Molecuoles
Monolayer
Poly(Monomethyl Itaconate)
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The synthesis and characterization of branched polymers derived from poly (monomethyl itaconate) (PMMI) are reported. Important changes in the properties of the functionalized products were found with respect to the base polymer, establishing a close relationship with the hydrophobic/hydrophilic balance of the products. The intrinsic viscosity of the branched PMMI showed an increment in its hydrodynamic volume due to the insertion of branched molecules, which correspond to a first generation of dendrons. Their incorporation into the polymer chain caused a change in the surface energy values of the sample films and enabled the products to form stable monolayers at the air-water interface.
Fil: Calderon, Marcelo. Universidad Nacional de Cordoba. Facultad de Ciencias Quimicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Leiva, Angel. Pontificia Universidad Católica de Chile. Facultad de Química. Departamento de Química Física. Facultad de Química; Chile
Fil: Martinelli, Marisa. Universidad Nacional de Cordoba. Facultad de Ciencias Quimicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Gargallo, Ligia. Pontificia Universidad Católica de Chile. Facultad de Química. Departamento de Química Física. Facultad de Química; Chile
Fil: Radic, Deodato. Pontificia Universidad Católica de Chile. Facultad de Química. Departamento de Química Física. Facultad de Química; Chile
Fil: Strumia, Miriam Cristina. Universidad Nacional de Cordoba. Facultad de Ciencias Quimicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
description The synthesis and characterization of branched polymers derived from poly (monomethyl itaconate) (PMMI) are reported. Important changes in the properties of the functionalized products were found with respect to the base polymer, establishing a close relationship with the hydrophobic/hydrophilic balance of the products. The intrinsic viscosity of the branched PMMI showed an increment in its hydrodynamic volume due to the insertion of branched molecules, which correspond to a first generation of dendrons. Their incorporation into the polymer chain caused a change in the surface energy values of the sample films and enabled the products to form stable monolayers at the air-water interface.
publishDate 2010
dc.date.none.fl_str_mv 2010-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/15767
Calderon, Marcelo; Leiva, Angel; Martinelli, Marisa; Gargallo, Ligia; Radic, Deodato; et al.; Synthesis and Physicochemical Characterization of Branched Poly (monomethyl itaconate); De Gruyter; E-polymers; 10; 1; 8-2010; 2197-4586
2197-4586
1618-7229
url http://hdl.handle.net/11336/15767
identifier_str_mv Calderon, Marcelo; Leiva, Angel; Martinelli, Marisa; Gargallo, Ligia; Radic, Deodato; et al.; Synthesis and Physicochemical Characterization of Branched Poly (monomethyl itaconate); De Gruyter; E-polymers; 10; 1; 8-2010; 2197-4586
2197-4586
1618-7229
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.degruyter.com/view/j/epoly.2010.10.issue-1/epoly.2010.10.1.1022/epoly.2010.10.1.1022.xml?format=INT
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv De Gruyter
publisher.none.fl_str_mv De Gruyter
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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