Equilibrium and dynamic surface properties of trisiloxane aqueous solutions. Part 2. Theory and comparison with experiment
- Autores
- Ritacco, Hernán Alejandro; Fainerman, Valentin B.; Ortega, Francisco; Rubio, Ramon G.; Ivanova, Natalia; Starov, Victor M.
- Año de publicación
- 2010
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- In the first part of this paper we presented experimental results, which shows the presence of surface aggregates in aqueous solutions of trisiloxane surfactants (Ritacco et al. [1]). Formation of those aggregates has been found for those trisiloxanes (T6, T7, T8, and T9), which show superspreading behaviour at room temperature. However, the formation of surface aggregates has not been detected for trisiloxanes (T4 and T5), which do not show superspreading behaviour at room temperature. It is shown that experimental results on equilibrium and dynamic interfacial tension agree well with a combined theoretical model, which is based on reorientation (or two states) and aggregation models. According to the reorientation model there are two states of trisiloxane molecules on the surface layer: molecules in those two states occupy different surface areas. The aggregation model was modified to account for specific properties of trisiloxane molecules. According to that model molecules occupying the lowest area on the interface can form two-dimensional aggregates. It was assumed that trisiloxane molecules include two kinetically independent trimethylsilyl [-O-Si(CH3)3] groups. This assumption allowed us to agree the aggregation theoretical model and experimental data on ellipsometric measurement of adsorption. © 2010 Elsevier B.V.
Fil: Ritacco, Hernán Alejandro. Universidad Complutense de Madrid; España
Fil: Fainerman, Valentin B.. Donetsk Medical University; Ucrania
Fil: Ortega, Francisco. Universidad Complutense de Madrid; España
Fil: Rubio, Ramon G.. Universidad Complutense de Madrid; España
Fil: Ivanova, Natalia. Loughborough University; Reino Unido
Fil: Starov, Victor M.. Loughborough University; Reino Unido - Materia
-
Aggregation
Equilibrium And Dynamic Surface Tension - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/67381
Ver los metadatos del registro completo
id |
CONICETDig_5c39a8463577039cb81effcb1e37fe21 |
---|---|
oai_identifier_str |
oai:ri.conicet.gov.ar:11336/67381 |
network_acronym_str |
CONICETDig |
repository_id_str |
3498 |
network_name_str |
CONICET Digital (CONICET) |
spelling |
Equilibrium and dynamic surface properties of trisiloxane aqueous solutions. Part 2. Theory and comparison with experimentRitacco, Hernán AlejandroFainerman, Valentin B.Ortega, FranciscoRubio, Ramon G.Ivanova, NataliaStarov, Victor M.AggregationEquilibrium And Dynamic Surface Tensionhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1In the first part of this paper we presented experimental results, which shows the presence of surface aggregates in aqueous solutions of trisiloxane surfactants (Ritacco et al. [1]). Formation of those aggregates has been found for those trisiloxanes (T6, T7, T8, and T9), which show superspreading behaviour at room temperature. However, the formation of surface aggregates has not been detected for trisiloxanes (T4 and T5), which do not show superspreading behaviour at room temperature. It is shown that experimental results on equilibrium and dynamic interfacial tension agree well with a combined theoretical model, which is based on reorientation (or two states) and aggregation models. According to the reorientation model there are two states of trisiloxane molecules on the surface layer: molecules in those two states occupy different surface areas. The aggregation model was modified to account for specific properties of trisiloxane molecules. According to that model molecules occupying the lowest area on the interface can form two-dimensional aggregates. It was assumed that trisiloxane molecules include two kinetically independent trimethylsilyl [-O-Si(CH3)3] groups. This assumption allowed us to agree the aggregation theoretical model and experimental data on ellipsometric measurement of adsorption. © 2010 Elsevier B.V.Fil: Ritacco, Hernán Alejandro. Universidad Complutense de Madrid; EspañaFil: Fainerman, Valentin B.. Donetsk Medical University; UcraniaFil: Ortega, Francisco. Universidad Complutense de Madrid; EspañaFil: Rubio, Ramon G.. Universidad Complutense de Madrid; EspañaFil: Ivanova, Natalia. Loughborough University; Reino UnidoFil: Starov, Victor M.. Loughborough University; Reino UnidoElsevier Science2010-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/67381Ritacco, Hernán Alejandro; Fainerman, Valentin B.; Ortega, Francisco; Rubio, Ramon G.; Ivanova, Natalia; et al.; Equilibrium and dynamic surface properties of trisiloxane aqueous solutions. Part 2. Theory and comparison with experiment; Elsevier Science; Colloids and Surfaces A: Physicochemical and Engineering Aspects; 365; 1-3; 12-2010; 204-2090927-7757CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0927775710000762info:eu-repo/semantics/altIdentifier/doi/10.1016/j.colsurfa.2010.01.052info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:05:45Zoai:ri.conicet.gov.ar:11336/67381instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:05:46.254CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Equilibrium and dynamic surface properties of trisiloxane aqueous solutions. Part 2. Theory and comparison with experiment |
title |
Equilibrium and dynamic surface properties of trisiloxane aqueous solutions. Part 2. Theory and comparison with experiment |
spellingShingle |
Equilibrium and dynamic surface properties of trisiloxane aqueous solutions. Part 2. Theory and comparison with experiment Ritacco, Hernán Alejandro Aggregation Equilibrium And Dynamic Surface Tension |
title_short |
Equilibrium and dynamic surface properties of trisiloxane aqueous solutions. Part 2. Theory and comparison with experiment |
title_full |
Equilibrium and dynamic surface properties of trisiloxane aqueous solutions. Part 2. Theory and comparison with experiment |
title_fullStr |
Equilibrium and dynamic surface properties of trisiloxane aqueous solutions. Part 2. Theory and comparison with experiment |
title_full_unstemmed |
Equilibrium and dynamic surface properties of trisiloxane aqueous solutions. Part 2. Theory and comparison with experiment |
title_sort |
Equilibrium and dynamic surface properties of trisiloxane aqueous solutions. Part 2. Theory and comparison with experiment |
dc.creator.none.fl_str_mv |
Ritacco, Hernán Alejandro Fainerman, Valentin B. Ortega, Francisco Rubio, Ramon G. Ivanova, Natalia Starov, Victor M. |
author |
Ritacco, Hernán Alejandro |
author_facet |
Ritacco, Hernán Alejandro Fainerman, Valentin B. Ortega, Francisco Rubio, Ramon G. Ivanova, Natalia Starov, Victor M. |
author_role |
author |
author2 |
Fainerman, Valentin B. Ortega, Francisco Rubio, Ramon G. Ivanova, Natalia Starov, Victor M. |
author2_role |
author author author author author |
dc.subject.none.fl_str_mv |
Aggregation Equilibrium And Dynamic Surface Tension |
topic |
Aggregation Equilibrium And Dynamic Surface Tension |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
In the first part of this paper we presented experimental results, which shows the presence of surface aggregates in aqueous solutions of trisiloxane surfactants (Ritacco et al. [1]). Formation of those aggregates has been found for those trisiloxanes (T6, T7, T8, and T9), which show superspreading behaviour at room temperature. However, the formation of surface aggregates has not been detected for trisiloxanes (T4 and T5), which do not show superspreading behaviour at room temperature. It is shown that experimental results on equilibrium and dynamic interfacial tension agree well with a combined theoretical model, which is based on reorientation (or two states) and aggregation models. According to the reorientation model there are two states of trisiloxane molecules on the surface layer: molecules in those two states occupy different surface areas. The aggregation model was modified to account for specific properties of trisiloxane molecules. According to that model molecules occupying the lowest area on the interface can form two-dimensional aggregates. It was assumed that trisiloxane molecules include two kinetically independent trimethylsilyl [-O-Si(CH3)3] groups. This assumption allowed us to agree the aggregation theoretical model and experimental data on ellipsometric measurement of adsorption. © 2010 Elsevier B.V. Fil: Ritacco, Hernán Alejandro. Universidad Complutense de Madrid; España Fil: Fainerman, Valentin B.. Donetsk Medical University; Ucrania Fil: Ortega, Francisco. Universidad Complutense de Madrid; España Fil: Rubio, Ramon G.. Universidad Complutense de Madrid; España Fil: Ivanova, Natalia. Loughborough University; Reino Unido Fil: Starov, Victor M.. Loughborough University; Reino Unido |
description |
In the first part of this paper we presented experimental results, which shows the presence of surface aggregates in aqueous solutions of trisiloxane surfactants (Ritacco et al. [1]). Formation of those aggregates has been found for those trisiloxanes (T6, T7, T8, and T9), which show superspreading behaviour at room temperature. However, the formation of surface aggregates has not been detected for trisiloxanes (T4 and T5), which do not show superspreading behaviour at room temperature. It is shown that experimental results on equilibrium and dynamic interfacial tension agree well with a combined theoretical model, which is based on reorientation (or two states) and aggregation models. According to the reorientation model there are two states of trisiloxane molecules on the surface layer: molecules in those two states occupy different surface areas. The aggregation model was modified to account for specific properties of trisiloxane molecules. According to that model molecules occupying the lowest area on the interface can form two-dimensional aggregates. It was assumed that trisiloxane molecules include two kinetically independent trimethylsilyl [-O-Si(CH3)3] groups. This assumption allowed us to agree the aggregation theoretical model and experimental data on ellipsometric measurement of adsorption. © 2010 Elsevier B.V. |
publishDate |
2010 |
dc.date.none.fl_str_mv |
2010-12 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/67381 Ritacco, Hernán Alejandro; Fainerman, Valentin B.; Ortega, Francisco; Rubio, Ramon G.; Ivanova, Natalia; et al.; Equilibrium and dynamic surface properties of trisiloxane aqueous solutions. Part 2. Theory and comparison with experiment; Elsevier Science; Colloids and Surfaces A: Physicochemical and Engineering Aspects; 365; 1-3; 12-2010; 204-209 0927-7757 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/67381 |
identifier_str_mv |
Ritacco, Hernán Alejandro; Fainerman, Valentin B.; Ortega, Francisco; Rubio, Ramon G.; Ivanova, Natalia; et al.; Equilibrium and dynamic surface properties of trisiloxane aqueous solutions. Part 2. Theory and comparison with experiment; Elsevier Science; Colloids and Surfaces A: Physicochemical and Engineering Aspects; 365; 1-3; 12-2010; 204-209 0927-7757 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0927775710000762 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.colsurfa.2010.01.052 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1844613897964748800 |
score |
13.070432 |