Interaction of catechol and gallic acid with titanium dioxide in aqueous suspensions. 1. Equilibrium studies

Autores
Araujo, Paula Zulema; Morando, Pedro Juan; Blesa, Miguel Angel
Año de publicación
2005
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The adsorption isotherms of catechol (1,2-dihydroxybenzene) and gallic acid (3,4,5-trihydroxybenzoic acid) onto titanium dioxide (Degussa P-25) were measured at various pH values and room temperature using attenuated total reflection Fourier transform infrared (FTIR-ATR) data, processed by singular value decomposition. The affinity is largely pH independent, although the deprotonatation of the carboxylic group in gallic acid might produce a slight increase in the affinity. Catechol was shown to form two complexes, with Langmuir stability constants log K of 4.66 (strong mode) and 3.65 (weak mode). Both complexes have the same spectral signature, and mononuclear and binuclear chelate structures are proposed for them. Gallic acid chemisorbs by complexation through two -OH groups and forms one complex only, log K= 4.70. The third -OH and the pendant carboxylate do not influence much the stability of the surface complex. Comparison with literature data demonstrates that the affinity of 4-chlorocatechol is also similar, whereas 2,3-dihidroxynaphthalene and 4-nitrocatechol form more stable complexes, probably because of the solvation contribution to the overall Gibbs adsorption energy. All quoted constants refer to the surface complexation equilibria written as follows: (≡Ti-OH) 2 + H2L = (≡Ti)2-L + 2H2O, i.e., as electroneutral processes. The FTIR-ATR spectra of the surface complexes are also discussed. © 2005 American Chemical Society.
Fil: Araujo, Paula Zulema. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
Fil: Morando, Pedro Juan. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Universidad Nacional de San Martín. Instituto Sabato; Argentina
Fil: Blesa, Miguel Angel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Universidad Nacional de San Martín; Argentina
Materia
Catechol
Gallic Acid
Titanium Dioxide
Equilibrium
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/55492
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/55492
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Interaction of catechol and gallic acid with titanium dioxide in aqueous suspensions. 1. Equilibrium studiesAraujo, Paula ZulemaMorando, Pedro JuanBlesa, Miguel AngelCatecholGallic AcidTitanium DioxideEquilibriumhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The adsorption isotherms of catechol (1,2-dihydroxybenzene) and gallic acid (3,4,5-trihydroxybenzoic acid) onto titanium dioxide (Degussa P-25) were measured at various pH values and room temperature using attenuated total reflection Fourier transform infrared (FTIR-ATR) data, processed by singular value decomposition. The affinity is largely pH independent, although the deprotonatation of the carboxylic group in gallic acid might produce a slight increase in the affinity. Catechol was shown to form two complexes, with Langmuir stability constants log K of 4.66 (strong mode) and 3.65 (weak mode). Both complexes have the same spectral signature, and mononuclear and binuclear chelate structures are proposed for them. Gallic acid chemisorbs by complexation through two -OH groups and forms one complex only, log K= 4.70. The third -OH and the pendant carboxylate do not influence much the stability of the surface complex. Comparison with literature data demonstrates that the affinity of 4-chlorocatechol is also similar, whereas 2,3-dihidroxynaphthalene and 4-nitrocatechol form more stable complexes, probably because of the solvation contribution to the overall Gibbs adsorption energy. All quoted constants refer to the surface complexation equilibria written as follows: (≡Ti-OH) 2 + H2L = (≡Ti)2-L + 2H2O, i.e., as electroneutral processes. The FTIR-ATR spectra of the surface complexes are also discussed. © 2005 American Chemical Society.Fil: Araujo, Paula Zulema. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; ArgentinaFil: Morando, Pedro Juan. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Universidad Nacional de San Martín. Instituto Sabato; ArgentinaFil: Blesa, Miguel Angel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Universidad Nacional de San Martín; ArgentinaAmerican Chemical Society2005-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/55492Araujo, Paula Zulema; Morando, Pedro Juan; Blesa, Miguel Angel; Interaction of catechol and gallic acid with titanium dioxide in aqueous suspensions. 1. Equilibrium studies; American Chemical Society; Langmuir; 21; 8; 4-2005; 3470-34740743-7463CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/la0476985info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/abs/10.1021/la0476985info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-11-12T09:40:28Zoai:ri.conicet.gov.ar:11336/55492instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-11-12 09:40:28.978CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Interaction of catechol and gallic acid with titanium dioxide in aqueous suspensions. 1. Equilibrium studies
title Interaction of catechol and gallic acid with titanium dioxide in aqueous suspensions. 1. Equilibrium studies
spellingShingle Interaction of catechol and gallic acid with titanium dioxide in aqueous suspensions. 1. Equilibrium studies
Araujo, Paula Zulema
Catechol
Gallic Acid
Titanium Dioxide
Equilibrium
title_short Interaction of catechol and gallic acid with titanium dioxide in aqueous suspensions. 1. Equilibrium studies
title_full Interaction of catechol and gallic acid with titanium dioxide in aqueous suspensions. 1. Equilibrium studies
title_fullStr Interaction of catechol and gallic acid with titanium dioxide in aqueous suspensions. 1. Equilibrium studies
title_full_unstemmed Interaction of catechol and gallic acid with titanium dioxide in aqueous suspensions. 1. Equilibrium studies
title_sort Interaction of catechol and gallic acid with titanium dioxide in aqueous suspensions. 1. Equilibrium studies
dc.creator.none.fl_str_mv Araujo, Paula Zulema
Morando, Pedro Juan
Blesa, Miguel Angel
author Araujo, Paula Zulema
author_facet Araujo, Paula Zulema
Morando, Pedro Juan
Blesa, Miguel Angel
author_role author
author2 Morando, Pedro Juan
Blesa, Miguel Angel
author2_role author
author
dc.subject.none.fl_str_mv Catechol
Gallic Acid
Titanium Dioxide
Equilibrium
topic Catechol
Gallic Acid
Titanium Dioxide
Equilibrium
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The adsorption isotherms of catechol (1,2-dihydroxybenzene) and gallic acid (3,4,5-trihydroxybenzoic acid) onto titanium dioxide (Degussa P-25) were measured at various pH values and room temperature using attenuated total reflection Fourier transform infrared (FTIR-ATR) data, processed by singular value decomposition. The affinity is largely pH independent, although the deprotonatation of the carboxylic group in gallic acid might produce a slight increase in the affinity. Catechol was shown to form two complexes, with Langmuir stability constants log K of 4.66 (strong mode) and 3.65 (weak mode). Both complexes have the same spectral signature, and mononuclear and binuclear chelate structures are proposed for them. Gallic acid chemisorbs by complexation through two -OH groups and forms one complex only, log K= 4.70. The third -OH and the pendant carboxylate do not influence much the stability of the surface complex. Comparison with literature data demonstrates that the affinity of 4-chlorocatechol is also similar, whereas 2,3-dihidroxynaphthalene and 4-nitrocatechol form more stable complexes, probably because of the solvation contribution to the overall Gibbs adsorption energy. All quoted constants refer to the surface complexation equilibria written as follows: (≡Ti-OH) 2 + H2L = (≡Ti)2-L + 2H2O, i.e., as electroneutral processes. The FTIR-ATR spectra of the surface complexes are also discussed. © 2005 American Chemical Society.
Fil: Araujo, Paula Zulema. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
Fil: Morando, Pedro Juan. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Universidad Nacional de San Martín. Instituto Sabato; Argentina
Fil: Blesa, Miguel Angel. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Universidad Nacional de San Martín; Argentina
description The adsorption isotherms of catechol (1,2-dihydroxybenzene) and gallic acid (3,4,5-trihydroxybenzoic acid) onto titanium dioxide (Degussa P-25) were measured at various pH values and room temperature using attenuated total reflection Fourier transform infrared (FTIR-ATR) data, processed by singular value decomposition. The affinity is largely pH independent, although the deprotonatation of the carboxylic group in gallic acid might produce a slight increase in the affinity. Catechol was shown to form two complexes, with Langmuir stability constants log K of 4.66 (strong mode) and 3.65 (weak mode). Both complexes have the same spectral signature, and mononuclear and binuclear chelate structures are proposed for them. Gallic acid chemisorbs by complexation through two -OH groups and forms one complex only, log K= 4.70. The third -OH and the pendant carboxylate do not influence much the stability of the surface complex. Comparison with literature data demonstrates that the affinity of 4-chlorocatechol is also similar, whereas 2,3-dihidroxynaphthalene and 4-nitrocatechol form more stable complexes, probably because of the solvation contribution to the overall Gibbs adsorption energy. All quoted constants refer to the surface complexation equilibria written as follows: (≡Ti-OH) 2 + H2L = (≡Ti)2-L + 2H2O, i.e., as electroneutral processes. The FTIR-ATR spectra of the surface complexes are also discussed. © 2005 American Chemical Society.
publishDate 2005
dc.date.none.fl_str_mv 2005-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/55492
Araujo, Paula Zulema; Morando, Pedro Juan; Blesa, Miguel Angel; Interaction of catechol and gallic acid with titanium dioxide in aqueous suspensions. 1. Equilibrium studies; American Chemical Society; Langmuir; 21; 8; 4-2005; 3470-3474
0743-7463
CONICET Digital
CONICET
url http://hdl.handle.net/11336/55492
identifier_str_mv Araujo, Paula Zulema; Morando, Pedro Juan; Blesa, Miguel Angel; Interaction of catechol and gallic acid with titanium dioxide in aqueous suspensions. 1. Equilibrium studies; American Chemical Society; Langmuir; 21; 8; 4-2005; 3470-3474
0743-7463
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/la0476985
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/abs/10.1021/la0476985
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.976206

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