Solvatochromic Dipolarity Micro-Sensor Behavior in Binary Solvent Sustems of the (Water + Ionic Liquid) Type. Application of Preferential Solvation Model And Linear Solvation Energ...
- Autores
- Adam, Claudia Guadalupe; Bravo, Maria Virginia; Mancini, Pedro Maximo Emilio; Fortunato, Graciela Guadalupe
- Año de publicación
- 2014
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The type of specific intermolecular and interionic interactions that are established when an ionic liquid is dissolved in water was here analysed. The study of the solvatochromic response of dipolarity micro-sensors based on Reichardt ET(30) and Kamlet?Abboud?Taft solvent scales and the application of the solvent exchangemodel confirmed the formation of different intersolvent complexes in binary mixtures of (water + [C4mim] [BF4]/[Br]) type. These complexes provide H-bond or electron pairs to the polar network, respectively. Moreover, for 4-methoxybenzenesulfonyl chloride hydrolysis reaction in the (water + [C4mim] [BF4]) system, a higher inhibition (13 times) on the kobs values was observed. Multiple linear regression analysis that allows confirming the solvent effect upon the reactive system is due to the hydrogen-bond donor properties of intersolvent complex formed. Then, the correlation between two different solvent-dependent processes proved to be successful.
Fil: Adam, Claudia Guadalupe. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Bravo, Maria Virginia. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Mancini, Pedro Maximo Emilio. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Fortunato, Graciela Guadalupe. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Química. Cátedra de Química Organica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina - Materia
-
Ionic Liquid
Micro-Sensor
Binary Solvent Sistems
Linear Solvation Energy Relationships
Binary Solvent Mixtures
Empirical Parameters
Energy Relationships
Microscopic Properties
Solvatochromic Probe - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/31456
Ver los metadatos del registro completo
id |
CONICETDig_5bb220bb4cade99e25654bdf64ea3cfc |
---|---|
oai_identifier_str |
oai:ri.conicet.gov.ar:11336/31456 |
network_acronym_str |
CONICETDig |
repository_id_str |
3498 |
network_name_str |
CONICET Digital (CONICET) |
spelling |
Solvatochromic Dipolarity Micro-Sensor Behavior in Binary Solvent Sustems of the (Water + Ionic Liquid) Type. Application of Preferential Solvation Model And Linear Solvation Energy RelationshipsAdam, Claudia GuadalupeBravo, Maria VirginiaMancini, Pedro Maximo EmilioFortunato, Graciela GuadalupeIonic LiquidMicro-SensorBinary Solvent SistemsLinear Solvation Energy RelationshipsBinary Solvent MixturesEmpirical ParametersEnergy RelationshipsMicroscopic PropertiesSolvatochromic Probehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The type of specific intermolecular and interionic interactions that are established when an ionic liquid is dissolved in water was here analysed. The study of the solvatochromic response of dipolarity micro-sensors based on Reichardt ET(30) and Kamlet?Abboud?Taft solvent scales and the application of the solvent exchangemodel confirmed the formation of different intersolvent complexes in binary mixtures of (water + [C4mim] [BF4]/[Br]) type. These complexes provide H-bond or electron pairs to the polar network, respectively. Moreover, for 4-methoxybenzenesulfonyl chloride hydrolysis reaction in the (water + [C4mim] [BF4]) system, a higher inhibition (13 times) on the kobs values was observed. Multiple linear regression analysis that allows confirming the solvent effect upon the reactive system is due to the hydrogen-bond donor properties of intersolvent complex formed. Then, the correlation between two different solvent-dependent processes proved to be successful.Fil: Adam, Claudia Guadalupe. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; ArgentinaFil: Bravo, Maria Virginia. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; ArgentinaFil: Mancini, Pedro Maximo Emilio. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; ArgentinaFil: Fortunato, Graciela Guadalupe. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Química. Cátedra de Química Organica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; ArgentinaWiley2014-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/31456Bravo, Maria Virginia; Adam, Claudia Guadalupe; Fortunato, Graciela Guadalupe; Mancini, Pedro Maximo Emilio; Solvatochromic Dipolarity Micro-Sensor Behavior in Binary Solvent Sustems of the (Water + Ionic Liquid) Type. Application of Preferential Solvation Model And Linear Solvation Energy Relationships; Wiley; Journal Of Physical Organic Chemistry; 27; 11; 8-2014; 841-8490894-3230CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/poc.3346/abstractinfo:eu-repo/semantics/altIdentifier/doi/10.1002/poc.3346info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:54:07Zoai:ri.conicet.gov.ar:11336/31456instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:54:08.201CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Solvatochromic Dipolarity Micro-Sensor Behavior in Binary Solvent Sustems of the (Water + Ionic Liquid) Type. Application of Preferential Solvation Model And Linear Solvation Energy Relationships |
title |
Solvatochromic Dipolarity Micro-Sensor Behavior in Binary Solvent Sustems of the (Water + Ionic Liquid) Type. Application of Preferential Solvation Model And Linear Solvation Energy Relationships |
spellingShingle |
Solvatochromic Dipolarity Micro-Sensor Behavior in Binary Solvent Sustems of the (Water + Ionic Liquid) Type. Application of Preferential Solvation Model And Linear Solvation Energy Relationships Adam, Claudia Guadalupe Ionic Liquid Micro-Sensor Binary Solvent Sistems Linear Solvation Energy Relationships Binary Solvent Mixtures Empirical Parameters Energy Relationships Microscopic Properties Solvatochromic Probe |
title_short |
Solvatochromic Dipolarity Micro-Sensor Behavior in Binary Solvent Sustems of the (Water + Ionic Liquid) Type. Application of Preferential Solvation Model And Linear Solvation Energy Relationships |
title_full |
Solvatochromic Dipolarity Micro-Sensor Behavior in Binary Solvent Sustems of the (Water + Ionic Liquid) Type. Application of Preferential Solvation Model And Linear Solvation Energy Relationships |
title_fullStr |
Solvatochromic Dipolarity Micro-Sensor Behavior in Binary Solvent Sustems of the (Water + Ionic Liquid) Type. Application of Preferential Solvation Model And Linear Solvation Energy Relationships |
title_full_unstemmed |
Solvatochromic Dipolarity Micro-Sensor Behavior in Binary Solvent Sustems of the (Water + Ionic Liquid) Type. Application of Preferential Solvation Model And Linear Solvation Energy Relationships |
title_sort |
Solvatochromic Dipolarity Micro-Sensor Behavior in Binary Solvent Sustems of the (Water + Ionic Liquid) Type. Application of Preferential Solvation Model And Linear Solvation Energy Relationships |
dc.creator.none.fl_str_mv |
Adam, Claudia Guadalupe Bravo, Maria Virginia Mancini, Pedro Maximo Emilio Fortunato, Graciela Guadalupe |
author |
Adam, Claudia Guadalupe |
author_facet |
Adam, Claudia Guadalupe Bravo, Maria Virginia Mancini, Pedro Maximo Emilio Fortunato, Graciela Guadalupe |
author_role |
author |
author2 |
Bravo, Maria Virginia Mancini, Pedro Maximo Emilio Fortunato, Graciela Guadalupe |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Ionic Liquid Micro-Sensor Binary Solvent Sistems Linear Solvation Energy Relationships Binary Solvent Mixtures Empirical Parameters Energy Relationships Microscopic Properties Solvatochromic Probe |
topic |
Ionic Liquid Micro-Sensor Binary Solvent Sistems Linear Solvation Energy Relationships Binary Solvent Mixtures Empirical Parameters Energy Relationships Microscopic Properties Solvatochromic Probe |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
The type of specific intermolecular and interionic interactions that are established when an ionic liquid is dissolved in water was here analysed. The study of the solvatochromic response of dipolarity micro-sensors based on Reichardt ET(30) and Kamlet?Abboud?Taft solvent scales and the application of the solvent exchangemodel confirmed the formation of different intersolvent complexes in binary mixtures of (water + [C4mim] [BF4]/[Br]) type. These complexes provide H-bond or electron pairs to the polar network, respectively. Moreover, for 4-methoxybenzenesulfonyl chloride hydrolysis reaction in the (water + [C4mim] [BF4]) system, a higher inhibition (13 times) on the kobs values was observed. Multiple linear regression analysis that allows confirming the solvent effect upon the reactive system is due to the hydrogen-bond donor properties of intersolvent complex formed. Then, the correlation between two different solvent-dependent processes proved to be successful. Fil: Adam, Claudia Guadalupe. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina Fil: Bravo, Maria Virginia. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina Fil: Mancini, Pedro Maximo Emilio. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina Fil: Fortunato, Graciela Guadalupe. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Química. Cátedra de Química Organica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina |
description |
The type of specific intermolecular and interionic interactions that are established when an ionic liquid is dissolved in water was here analysed. The study of the solvatochromic response of dipolarity micro-sensors based on Reichardt ET(30) and Kamlet?Abboud?Taft solvent scales and the application of the solvent exchangemodel confirmed the formation of different intersolvent complexes in binary mixtures of (water + [C4mim] [BF4]/[Br]) type. These complexes provide H-bond or electron pairs to the polar network, respectively. Moreover, for 4-methoxybenzenesulfonyl chloride hydrolysis reaction in the (water + [C4mim] [BF4]) system, a higher inhibition (13 times) on the kobs values was observed. Multiple linear regression analysis that allows confirming the solvent effect upon the reactive system is due to the hydrogen-bond donor properties of intersolvent complex formed. Then, the correlation between two different solvent-dependent processes proved to be successful. |
publishDate |
2014 |
dc.date.none.fl_str_mv |
2014-08 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/31456 Bravo, Maria Virginia; Adam, Claudia Guadalupe; Fortunato, Graciela Guadalupe; Mancini, Pedro Maximo Emilio; Solvatochromic Dipolarity Micro-Sensor Behavior in Binary Solvent Sustems of the (Water + Ionic Liquid) Type. Application of Preferential Solvation Model And Linear Solvation Energy Relationships; Wiley; Journal Of Physical Organic Chemistry; 27; 11; 8-2014; 841-849 0894-3230 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/31456 |
identifier_str_mv |
Bravo, Maria Virginia; Adam, Claudia Guadalupe; Fortunato, Graciela Guadalupe; Mancini, Pedro Maximo Emilio; Solvatochromic Dipolarity Micro-Sensor Behavior in Binary Solvent Sustems of the (Water + Ionic Liquid) Type. Application of Preferential Solvation Model And Linear Solvation Energy Relationships; Wiley; Journal Of Physical Organic Chemistry; 27; 11; 8-2014; 841-849 0894-3230 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/poc.3346/abstract info:eu-repo/semantics/altIdentifier/doi/10.1002/poc.3346 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Wiley |
publisher.none.fl_str_mv |
Wiley |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1844613646229962752 |
score |
13.070432 |